Hierarchically Crosslinked Gels Containing Hydrophobic Ionic Liquids towards Reliable Sensing Applications

Xia-Chao Chen; Pei-Ru Sun; Hong-Liang Liu

doi:10.1007/s10118-020-2357-2

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Hierarchically Crosslinked Gels Containing Hydrophobic Ionic Liquids towards Reliable Sensing Applications

ARTICLE | Updated：2019-11-15

- Hierarchically Crosslinked Gels Containing Hydrophobic Ionic Liquids towards Reliable Sensing Applications
- Hierarchically Crosslinked Gels Containing Hydrophobic Ionic Liquids towards Reliable Sensing Applications
- Chinese Journal of Polymer Science 2020年38卷第4期页码：332-341
- Affiliations：
  
  a.Laboratory of Bio-inspired Smart Interface Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  b.Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education and Beijing Advanced Innovation Center for Biomedical Engineering, Beihang University, Beijing 100191, China
  c.School of Metallurgy and Materials Engineering, Chongqing University of Science and Technology, Chongqing 401331, China
- Author bio：
  
  chenxiachao@buaa.edu.cn (X.C.C.)
  liuhl@mail.ipc.ac.cn (H.L.L.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21875268 and 51276009), National Research Fund for Fundamental Key Projects (Nos. 2013CB933000 and 2012CB933800), the Key Research Program of the Chinese Academy of Sciences (Nos. KJZD-EW-M01 and KJZD-EW-M03), the 111 project (No. B14009), Youth Innovation Promotion Association, CAS (No. 2016026), and the China Postdoctoral Science Foundation (No. 2019M650435).
- DOI：10.1007/s10118-020-2357-2
  中图分类号：
- 收稿：2019-08-08，
  
  修回：2019-9-12，
  
  录用：2019-9-16，
  
  网络首发：2019-11-15，
  
  纸质出版：2020-04
- Accepted：
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Chen, X. C.; Sun, P. R.; Liu, H. L. Hierarchically crosslinked gels containing hydrophobic ionic liquids towards reliable sensing applications. Chinese J. Polym. Sci. 2020, 38, 332–341

Xia-Chao Chen, Pei-Ru Sun, Hong-Liang Liu. Hierarchically Crosslinked Gels Containing Hydrophobic Ionic Liquids towards Reliable Sensing Applications[J]. Chinese Journal of Polymer Science, 2020, 38(4): 332-341.
Chen, X. C.; Sun, P. R.; Liu, H. L. Hierarchically crosslinked gels containing hydrophobic ionic liquids towards reliable sensing applications. Chinese J. Polym. Sci. 2020, 38, 332–341 DOI： 10.1007/s10118-020-2357-2.

Xia-Chao Chen, Pei-Ru Sun, Hong-Liang Liu. Hierarchically Crosslinked Gels Containing Hydrophobic Ionic Liquids towards Reliable Sensing Applications[J]. Chinese Journal of Polymer Science, 2020, 38(4): 332-341. DOI： 10.1007/s10118-020-2357-2.

摘要

Abstract

Human skin can function steadily regardless of surrounding circumstances (dry or wet)

while it is still a challenge for artificial ionic skins

which tend to release solvents in dry air and leach electrolytes in wetted state. Herein

a series of hierarchically crosslinked ionogels containing hydrophobic ionic liquids (ILs) is fabricated by combining a crystalline fluorinated copolymer with hydrophobic ILs. With a reasonable combination of nonvolatility

transparency

stretchablility

and sensitivity

such ionogels can work as reliable sensors for real-time monitoring human motions and operate steadily in complex environments as human skin does

which can contribute to the development of durable sensing devices with a simple design.

关键词

Keywords

references

Wang, J.; Lin, M. F.; Park, S.; Lee, P. S . Deformable conductors for human-machine interface . Mater. Today , 2018 . 21 508 - 526 . DOI: 10.1016/j.mattod.2017.12.006 http://doi.org/10.1016/j.mattod.2017.12.006 .

Qian, Y.; Zhang, X.; Xie, L.; Qi, D.; Chandran, B. K.; Chen, X.; Huang, W . Stretchable organic semiconductor devices . Adv. Mater. , 2016 . 28 9243 - 9265 . DOI: 10.1002/adma.201601278 http://doi.org/10.1002/adma.201601278 .

Oh, J. Y.; Kim, S.; Baik, H. K.; Jeong, U . Conducting polymer dough for deformable electronics . Adv. Mater. , 2016 . 28 4455 - 4461 . DOI: 10.1002/adma.201502947 http://doi.org/10.1002/adma.201502947 .

Keplinger, C.; Sun, J. Y.; Foo, C. C.; Rothemund, P.; Whitesides, G. M.; Suo, Z . Stretchable, transparent, ionic conductors . Science , 2013 . 341 984 - 987 . DOI: 10.1126/science.1240228 http://doi.org/10.1126/science.1240228 .

Larson, C.; Peele, B.; Li, S.; Robinson, S.; Totaro, M.; Beccai, L.; Mazzolai, B.; Shepherd, R . Highly stretchable electroluminescent skin for optical signaling and tactile sensing . Science , 2016 . 351 1071 - 1074 . DOI: 10.1126/science.aac5082 http://doi.org/10.1126/science.aac5082 .

Kim, C C.; Lee, H. H.; Oh, K. H.; Sun, J. Y . Highly stretchable, transparent ionic touch panel . Science , 2016 . 353 682 - 687 . DOI: 10.1126/science.aaf8810 http://doi.org/10.1126/science.aaf8810 .

Yang, C. H.; Chen, B.; Zhou, J.; Chen, Y. M.; Suo, Z . Electroluminescence of giant stretchability . Adv. Mater. , 2016 . 28 4480 - 4484 . DOI: 10.1002/adma.201504031 http://doi.org/10.1002/adma.201504031 .

Chen, L.; Yin, Y. A.; Liu, Y. X.; Lin, L.; Liu, M. J . Design and fabrication of functional hydrogels through interfacial engineering . Chinese J. Polym. Sci. , 2017 . 35 1181 - 1193 . DOI: 10.1007/s10118-017-1995-5 http://doi.org/10.1007/s10118-017-1995-5 .

Shi, F. K.; Zhong, M.; Zhang, L. Q.; Liu, X. Y.; Xie, X. M . Toughening mechanism of nanocomposite physical hydrogels fabricated by a single gel network with dual crosslinking—the roles of the dual crosslinking points . Chinese J. Polym. Sci. , 2017 . 35 25 - 35 . .

Lei, Z.; Wu, P . A Supramolecular biomimetic skin combining a wide spectrum of mechanical properties and multiple sensory capabilities . Nat. Commun. , 2018 . 9 1134 DOI: 10.1038/s41467-018-03456-w http://doi.org/10.1038/s41467-018-03456-w .

Lei, Z.; Wang, Q.; Sun, S.; Zhu, W.; Wu, P . A bioinspired mineral hydrogel as a self-healable, mechanically adaptable ionic skin for highly sensitive pressure sensing . Adv. Mater. , 2017 . 29 1700321 DOI: 10.1002/adma.201700321 http://doi.org/10.1002/adma.201700321 .

Lee, H. R.; Kim, C. C.; Sun, J. Y . Stretchable ionics—a promising candidate for upcoming wearable devices . Adv. Mater. , 2018 . 30 1704403 DOI: 10.1002/adma.201704403 http://doi.org/10.1002/adma.201704403 .

Bai, Y.; Chen, B.; Xiang, F.; Zhou, J.; Wang, H.; Suo, Z . Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt . Appl. Phys. Lett. , 2014 . 105 151903 DOI: 10.1063/1.4898189 http://doi.org/10.1063/1.4898189 .

Zhang, J. Z.; Xiao, C. S.; Wang, J. C.; Zhuang, X. L.; Chen, X. S . Photo cross-linked biodegradable hydrogels for enhanced vancomycin loading and sustained release . Chinese J. Polym. Sci. , 2013 . 31 1697 - 1705 . DOI: 10.1007/s10118-013-1358-9 http://doi.org/10.1007/s10118-013-1358-9 .

Zhao, Z. G.; Xu, Y. C.; Fang, R. C.; Liu, M. J . Bioinspired adaptive gel materials with synergistic heterostructures . Chinese J. Polym. Sci. , 2018 . 36 683 - 696 . DOI: 10.1007/s10118-018-2105-z http://doi.org/10.1007/s10118-018-2105-z .

Yuk, H.; Zhang, T.; Parada, G. A.; Liu, X.; Zhao, X . Skin-inspired hydrogel-elastomer hybrids with robust interfaces and functional microstructures . Nat. Commun. , 2016 . 7 12028 DOI: 10.1038/ncomms12028 http://doi.org/10.1038/ncomms12028 .

Chen, S.; Liu, H.; Liu, S.; Wang, P.; Zeng, S.; Sun, L.; Liu, L . Transparent and waterproof ionic liquid-based fibers for highly durable multifunctional sensors and strain-insensitive stretchable conductors . ACS Appl. Mater. Interfaces , 2018 . 10 4305 - 4314 . DOI: 10.1021/acsami.7b17790 http://doi.org/10.1021/acsami.7b17790 .

Kamio, E.; Yasui, T.; Iida, Y.; Gong, J. P.; Matsuyama, H . Inorganic/organic double-network gels containing ionic liquids . Adv. Mater. , 2017 . 29 1704118 DOI: 10.1002/adma.201704118 http://doi.org/10.1002/adma.201704118 .

Ding, Y.; Zhang, J.; Chang, L.; Zhang, X.; Liu, H.; Jiang, L . Preparation of high-performance ionogels with excellent transparency, good mechanical strength, and high conductivity . Adv. Mater. , 2017 . 29 1704253 DOI: 10.1002/adma.201704253 http://doi.org/10.1002/adma.201704253 .

Chen, B.; Lu, J. J.; Yang, C. H.; Yang, J. H.; Zhou, J.; Chen, Y. M.; Suo, Z . Highly stretchable and transparent ionogels as nonvolatile conductors for dielectric elastomer transducers . ACS Appl. Mater. Interfaces , 2014 . 6 7840 - 7845 . DOI: 10.1021/am501130t http://doi.org/10.1021/am501130t .

Freire, M. G.; Carvalho, P. J.; Gardas, R. L.; Marrucho, I. M.; Santo, L. M. N. B. F.; Coutinho, J. A. P . Mutual solubilities of water and the [C n MIm][Tf 2 n] hydrophobic ionic liquids . J. Phys. Chem. B , 2008 . 112 1604 - 1610 . .

Yee, P.; Shah, J. K.; Maginn, E. J . State of hydrophobic and hydrophilic ionic liquids in aqueous solutions: are the ions fully dissociated? . J. Phys. Chem. B , 2013 . 117 12556 - 12566 . DOI: 10.1021/jp405341m http://doi.org/10.1021/jp405341m .

Thomas, M. L.; Oda, Y.; Tatara, R.; Kwon, H. M.; Ueno, K.; Dokko, K.; Watanabe, M . Suppression of water absorption by molecular design of ionic liquid electrolyte for Li-Air battery . Adv. Energy Mater. , 2017 . 7 1601753 DOI: 10.1002/aenm.201601753 http://doi.org/10.1002/aenm.201601753 .

Ameduri, B . From vinylidene fluoride (Vdf) to the applications of Vdf-containing polymers and copolymers: recent developments and future trends . Chem. Rev. , 2009 . 109 6632 - 6686 . DOI: 10.1021/cr800187m http://doi.org/10.1021/cr800187m .

Lin, D. J.; Lin, C. L.; Guo, S. Y . Network nano-porous poly(vinylidene fluoride- co -hexafluoropropene) membranes by nano-gelation assisted phase separation of poly(vinylidene fluoride- co -hexafluoropropene)/poly(methyl methacrylate) blend precursor in toluene . Macromolecules , 2012 . 45 8824 - 8832 . DOI: 10.1021/ma301075e http://doi.org/10.1021/ma301075e .

Ueki, T.; Watanabe, M . Macromolecules in ionic liquids: progress, challenges, and opportunities . Macromolecules , 2008 . 41 3739 - 3749 . DOI: 10.1021/ma800171k http://doi.org/10.1021/ma800171k .

Fujii, K.; Asai, H.; Ueki, T.; Sakai, T.; Imaizumi, S.; Chung, U. I.; Watanabe, M.; Shibayama, M . High-performance ion gel with tetra-PEG network . Soft Matter , 2012 . 8 1756 - 1759 . DOI: 10.1039/C2SM07119C http://doi.org/10.1039/C2SM07119C .

Xing, C.; Zhao, M.; Zhao, L.; You, J.; Cao, X.; Li, Y . Ionic liquid modified poly(vinylidene fluoride): crystalline structures, miscibility, and physical properties . Polym. Chem. , 2013 . 4 5726 - 5734 . DOI: 10.1039/c3py00466j http://doi.org/10.1039/c3py00466j .

Cao, Y.; Morrissey, T. G.; Acome, E.; Allec, S. I.; Wong, B. M.; Keplinger, C.; Wang, C . A Transparent, self-healing, highly stretchable ionic conductor . Adv. Mater. , 2017 . 29 1605099 DOI: 10.1002/adma.201605099 http://doi.org/10.1002/adma.201605099 .

Liang, C. L.; Mai, Z. H.; Xie, Q.; Bao, R. Y.; Yang, W.; Xie, B. H.; Yang, M. B . Induced formation of dominating polar phases of poly(vinylidene fluoride): positive ion-CF 2 dipole or negative ion-CH 2 dipole interaction . J. Phys. Chem. B , 2014 . 118 9104 - 9111 . DOI: 10.1021/jp504938f http://doi.org/10.1021/jp504938f .

Sun, J. Y.; Keplinger, C.; Whitesides, G. M.; Suo, Z . Ionic skin . Adv. Mater. , 2014 . 26 7608 - 7614 . DOI: 10.1002/adma.201403441 http://doi.org/10.1002/adma.201403441 .

Jin, M. L.; Park, S.; Kim, J. S.; Kwon, S. H.; Zhang, S.; Yoo, M. S.; Jang, S.; Koh, H. J.; Cho, S. Y.; Kim, S. Y.; Ahn, C. W.; Cho, K.; Lee, S. G.; Kim, D. H.; Jung, H. T . An ultrastable ionic chemiresistor skin with an intrinsically stretchable polymer electrolyte . Adv. Mater. , 2018 . 30 1706851 DOI: 10.1002/adma.201706851 http://doi.org/10.1002/adma.201706851 .

Sousa, R. E.; Nunes-Pereira, J.; Ferreira, J. C. C.; Costa, C. M.; Machado, A. V.; Silva, M. M.; Lanceros-Mendez, S . Microstructural variations of poly(vinylidene fluoride- co -hexafluoropropylene) and their influence on the thermal, dielectric and piezoelectric properties . Polym. Test. , 2014 . 40 245 - 255 . DOI: 10.1016/j.polymertesting.2014.09.012 http://doi.org/10.1016/j.polymertesting.2014.09.012 .

Ding, Y.; Zhang, J.; Zhang, X.; Zhou, Y.; Wang, S.; Liu, H.; Jiang, L . Ionic-liquid-gel surfaces showing easy-sliding and ultradurable features . Adv. Mater. Interfaces , 2015 . 2 1500177 DOI: 10.1002/admi.201500177 http://doi.org/10.1002/admi.201500177 .

Kofu, M.; Someya, T.; Tatsumi, S.; Ueno, K.; Ueki, T.; Watanabe, M.; Matsunaga, T.; Shibayama, M.; Sakai, V. G.; Tyagi, M.; Yamamuro, O . Microscopic insights into ion gel dynamics using neutron spectroscopy . Soft Matter , 2012 . 8 7888 - 7897 . DOI: 10.1039/c2sm25348h http://doi.org/10.1039/c2sm25348h .

Ahmad, A. L.; Farooqui, U. R.; Hamid, N. A . Effect of graphene oxide (GO) on poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) polymer electrolyte membrane . Polymer , 2018 . 142 330 - 336 . DOI: 10.1016/j.polymer.2018.03.052 http://doi.org/10.1016/j.polymer.2018.03.052 .

Trung, T. Q.; Lee, N. E . Flexible and stretchable physical sensor integrated platforms for wearable human-activity monitoring and personal healthcare . Adv. Mater. , 2016 . 28 4338 - 4372 . DOI: 10.1002/adma.201504244 http://doi.org/10.1002/adma.201504244 .

Li, L.; Bai, Y.; Li, L.; Wang, S.; Zhang, T . A superhydrophobic smart coating for flexible and wearable sensing electronics . Adv. Mater. , 2017 . 29 1702517 DOI: 10.1002/adma.201702517 http://doi.org/10.1002/adma.201702517 .

Yang, S.; Lu, N . Gauge factor and stretchability of silicon-on-polymer strain gauges . Sensors , 2013 . 13 8577 - 8594 . DOI: 10.3390/s130708577 http://doi.org/10.3390/s130708577 .

Liu, T.; Liu, M.; Dou, S.; Sun, J.; Cong, Z.; Jiang, C.; Du, C.; Pu, X.; Hu, W.; Wang, Z. L . Triboelectric-nanogenerator-based soft energy-harvesting skin enabled by toughly bonded elastomer/hydrogel hybrids . ACS Nano , 2018 . 12 2818 - 2826 . DOI: 10.1021/acsnano.8b00108 http://doi.org/10.1021/acsnano.8b00108 .

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