Melt Crystallization of Poly(butylene 2,6-naphthalate)

Qian Ding; Michelina Soccio; Nadia Lotti; Dario Cavallo; René Androsch

doi:10.1007/s10118-020-2354-5

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Melt Crystallization of Poly(butylene 2,6-naphthalate)

REVIEW | Updated：2019-11-15

- Melt Crystallization of Poly(butylene 2,6-naphthalate)
- Melt Crystallization of Poly(butylene 2,6-naphthalate)
- Chinese Journal of Polymer Science 2020年38卷第4期页码：311-322
- Affiliations：
  
  a.School of Packaging Design and Art, Hunan University of Technology, Zhuzhou 412007, China
  b.Department of Civil, Chemical, Environmental and Materials Engineering, University of Bologna, Via Terracini 28, Bologna 40131, Italy
  c.Department of Chemistry and Industrial Chemistry, University of Genova, Via Dodecaneso 31, Genova 16146, Italy
  d.Interdisciplinary Center for Transfer-oriented Research in Natural Sciences (IWE TFN), Martin Luther University Halle-Wittenberg, Halle/Saale 06099, Germany
- Author bio：
  
  dario.cavallo@unige.it (D.C.)
  rene.androsch@iw.uni-halle.de (R.A.)
- Funds：
  
  Q. D. acknowledges financial support from the China Scholarship Council (CSC), for performing research at the Martin Luther University Halle-Wittenberg (Germany). R. A. and Q. D. acknowledge financial support from Sino-German Center for Research Promotion (GZ 1514).
- DOI：10.1007/s10118-020-2354-5
  中图分类号：
- 收稿：2019-07-14，
  
  修回：2019-9-3，
  
  录用：2019-9-4，
  
  网络首发：2019-11-15，
  
  纸质出版：2020-04
- Accepted：
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Ding, Q.; Soccio, M.; Lotti, N.; Cavallo, D.; Androsch, R. Melt crystallization of poly(butylene 2,6-naphthalate). Chinese J. Polym. Sci. 2020, 38, 311–322

Qian Ding, Michelina Soccio, Nadia Lotti, et al. Melt Crystallization of Poly(butylene 2,6-naphthalate)[J]. Chinese Journal of Polymer Science, 2020, 38(4): 311-322.
Ding, Q.; Soccio, M.; Lotti, N.; Cavallo, D.; Androsch, R. Melt crystallization of poly(butylene 2,6-naphthalate). Chinese J. Polym. Sci. 2020, 38, 311–322 DOI： 10.1007/s10118-020-2354-5.

Qian Ding, Michelina Soccio, Nadia Lotti, et al. Melt Crystallization of Poly(butylene 2,6-naphthalate)[J]. Chinese Journal of Polymer Science, 2020, 38(4): 311-322. DOI： 10.1007/s10118-020-2354-5.

摘要

Abstract

Poly(butylene 2

6-naphthalate) (PBN) is a crystallizable linear polyester containing a rigid naphthalene unit and flexible methylene spacer in the chemical repeat unit. Polymeric materials made of PBN exhibit excellent anti-abrasion and low friction properties

superior chemical resistance

and outstanding gas barrier characteristics. Many of the properties rely on the presence of crystals and the formation of a semicrystalline morphology. To develop specific crystal structures and morphologies during cooling the melt

precise information about the melt-crystallization process is required. This review article summarizes the current knowledge about the temperature-controlled crystal polymorphism of PBN. At rather low supercooling of the melt

with decreasing crystallization temperature

′- and

-crystals grow directly from the melt and organize in largely different spherulitic superstructures. Formation of

-crystals at high supercooling may also proceed

via

intermediate formation of a transient monotropic liquid crystalline structure

then yielding a non-spherulitic semicrystalline morphology. Crystallization of PBN is rather fast since its suppression requires cooling the melt at a rate higher than 6000 K·s

−1

. For this reason

investigation of the two-step crystallization process at low temperatures requires application of sophisticated experimental tools. These include temperature-resolved X-ray scattering techniques using fast detectors and synchrotron-based X-rays and fast scanning chip calorimetry. Fast scanning chip calorimetry allows freezing the transient liquid-crystalline structure before its conversion into

-crystals

by fast cooling to below its glass transition temperature. Subsequent analysis using polarized-light optical microscopy reveals its texture and X-ray scattering confirms the smectic arrangement of the mesogens. The combination of a large variety of experimental techniques allows obtaining a complete picture about crystallization of PBN in the entire range of melt-supercoolings down to the glass transition

including quantitative data about the crystallization kinetics

semicrystalline morphologies at the micrometer length scale

as well as nanoscale X-ray structure information.

关键词

Keywords

references

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