Preparation of Polyaniline-coated Composite Aerogel of MnO<sub>2</sub> and Reduced Graphene Oxide for High-performance Zinc-ion Battery

Jing Mao; Fang-Fang Wu; Wen-Hui Shi; Wen-Xian Liu; Xi-Lian Xu; Gang-Feng Cai; Yi-Wen Li; Xie-Hong Cao

doi:10.1007/s10118-020-2353-6

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Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery

ARTICLE | Updated：2019-11-07

- Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery
- Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery
- Chinese Journal of Polymer Science 2020年38卷第5期页码：514-521
- Affiliations：
  
  a.College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China
  b.Center for Membrane Separation and Water Science & Technology, Ocean College, Zhejiang University of Technology, Hangzhou 310014, China
- Author bio：
  
  gcscaoxh@zjut.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51602284 and 51702286), Natural Science Foundation of Zhejiang Province, China (Nos. LQ17B030002 and LR19E020003), and General Scientific Research Project of the Department of Education of Zhejiang Province, China (No. Y201839638).
- DOI：10.1007/s10118-020-2353-6
  中图分类号：
- 收稿：2019-08-14，
  
  修回：2019-8-30，
  
  录用：2019-8-31，
  
  网络首发：2019-11-07，
  
  纸质出版：2020-05
- Accepted：
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Mao, J.; Wu, F. F.; Shi, W. H.; Liu, W. X.; Xu, X. L.; Cai, G. F.; Li, Y. W.; Cao, X. H. Preparation of polyaniline-coated composite aerogel of MnO₂ and reduced graphene oxide for high-performance zinc-ion battery. Chinese J. Polym. Sci. 2020, 38, 514–521 DOI: 10.1007/s10118-020-2353-6.

Jing Mao, Fang-Fang Wu, Wen-Hui Shi, et al. Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery[J]. Chinese Journal of Polymer Science, 2020, 38(5): 514-521. DOI: 10.1007/s10118-020-2353-6.
Mao, J.; Wu, F. F.; Shi, W. H.; Liu, W. X.; Xu, X. L.; Cai, G. F.; Li, Y. W.; Cao, X. H. Preparation of polyaniline-coated composite aerogel of MnO₂ and reduced graphene oxide for high-performance zinc-ion battery. Chinese J. Polym. Sci. 2020, 38, 514–521 DOI: 10.1007/s10118-020-2353-6. DOI：

Jing Mao, Fang-Fang Wu, Wen-Hui Shi, et al. Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery[J]. Chinese Journal of Polymer Science, 2020, 38(5): 514-521. DOI: 10.1007/s10118-020-2353-6. DOI：

摘要

Abstract

Aqueous zinc-ion batteries

especially Zn-MnO

battery

have attracted intensive attention owing to their unique features of high capacity

environmental friendliness

and safety. However

the problem of Mn dissolution hinders the development of zinc-ion batteries with long-term usage and high-rate performance. In this work

a novel preparation method for the polyaniline (PANI)-coated composite aerogel of MnO

and rGO (MnO

/rGO/PANI) electrode is reported. The obtained composite possesses high electrical conductivity

and also effectively suppresses the dissolution of Mn. The fabricated MnO

/rGO/PANI//Zn battery exhibits a high capacity of 241.1 mAh·g

−1

at 0.1 A·g

−1

and an excellent capacity retention of 82.7% after 600 charge/discharge cycles. In addition

the rapid diffusion coefficient of the MnO

/rGO/PANI electrode was further examined by galvanostatic intermittent titration technique. This work provides new insights into the development of high-performance Zn-MnO

battery with a better understanding of its diffusion kinetics.

关键词

Keywords

references

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Preparation of Polyaniline-coated Composite Aerogel of MnO2 and Reduced Graphene Oxide for High-performance Zinc-ion Battery

DOI：10.1007/s10118-020-2353-6

摘要

Abstract

关键词

Keywords

references

Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery

Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery