Ring-opening Copolymerization of <italic style="font-style: italic">ε</italic>-Caprolactone and <italic style="font-style: italic">δ</italic>-Valerolactone Catalyzed by a 2,6-Bis(amino)phenol Zinc Complex

Qian Hu; Su-Yun Jie; Pierre Braunstein; Bo-Geng Li

doi:10.1007/s10118-020-2347-4

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Ring-opening Copolymerization of ε-Caprolactone and δ-Valerolactone Catalyzed by a 2,6-Bis(amino)phenol Zinc Complex

ARTICLE | Updated：2019-10-12

- Ring-opening Copolymerization of ε-Caprolactone and δ-Valerolactone Catalyzed by a 2,6-Bis(amino)phenol Zinc Complex
- Ring-opening Copolymerization of ε-Caprolactone and δ-Valerolactone Catalyzed by a 2,6-Bis(amino)phenol Zinc Complex
- Chinese Journal of Polymer Science 2020年38卷第3期页码：240-247
- Affiliations：
  
  a.State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
  b.Université de Strasbourg, CNRS, CHIMIE UMR 7177, Laboratoire de Chimie de Coordination, 4 rue Blaise Pascal, 67081 Strasbourg Cedex, France
- Author bio：
  
  jiesy@zju.edu.cn
- Funds：
  
  This work was financially supported by the National Key R&D Program of China (No. 2016YFC1100801) and the State Key Laboratory of Chemical Engineering (No. SKL-ChE-18D01).
- DOI：10.1007/s10118-020-2347-4
  中图分类号：
- 收稿：2019-05-28，
  
  修回：2019-8-6，
  
  录用：2019-8-29，
  
  网络首发：2019-10-12，
  
  纸质出版：2020-03
- Accepted：
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Hu, Q.; Jie, S. Y.; Braunstein, P.; Li, B. G. Ring-opening copolymerization of , ε,-caprolactone and , δ,-valerolactone catalyzed by a 2,6-bis(amino)phenol zinc complex. Chinese J. Polym. Sci. 2020, 38, 240–247.

Qian Hu, Su-Yun Jie, Pierre Braunstein, et al. Ring-opening Copolymerization of ε-Caprolactone and δ-Valerolactone Catalyzed by a 2,6-Bis(amino)phenol Zinc Complex[J]. Chinese Journal of Polymer Science, 2020, 38(3): 240-247. DOI: 10.1007/s10118-020-2347-4.
Hu, Q.; Jie, S. Y.; Braunstein, P.; Li, B. G. Ring-opening copolymerization of , ε,-caprolactone and , δ,-valerolactone catalyzed by a 2,6-bis(amino)phenol zinc complex. Chinese J. Polym. Sci. 2020, 38, 240–247. DOI： 10.1007/s10118-020-2347-4.

Qian Hu, Su-Yun Jie, Pierre Braunstein, et al. Ring-opening Copolymerization of ε-Caprolactone and δ-Valerolactone Catalyzed by a 2,6-Bis(amino)phenol Zinc Complex[J]. Chinese Journal of Polymer Science, 2020, 38(3): 240-247. DOI: 10.1007/s10118-020-2347-4. DOI：

摘要

Abstract

In combination with methyllithium

a 2

6-bis(amino)phenol zinc complex

was used in the ring-opening polymerization of

-valerolactone in the absence or presence of benzyl alcohol and showed high efficiency

mainly producing cyclic and linear polyvalerolactones

respectively. On the basis of homopolymerization

the ring-opening copolymerization of

-caprolactone and

-valerolactone was investigated. The P(CL-

-VL) random copolymers

PCL-

-PVL and PVL-

-PCL diblock copolymers

were prepared by varying the feeding strategy (premixing or sequential feeding). The copolymer composition was adjusted by varying the feeding ratio of two monomers. The structure and thermal properties of obtained polymers were characterized by GPC

H-NMR

C-NMR

MALDI-TOF mass spectroscopy

and DSC

respectively.

关键词

Keywords

references

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Ring-opening Copolymerization of ε-Caprolactone and δ-Valerolactone Catalyzed by a 2,6-Bis(amino)phenol Zinc Complex

DOI：10.1007/s10118-020-2347-4

摘要

Abstract

关键词

Keywords

references