Crystallization Behavior and Dynamic Mechanical Properties of Poly(<italic style="font-style: italic">ε</italic>-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared <italic style="font-style: italic">via</italic> Different Methods

Si-Qi Teng; Zhi-Guo Jiang; Zhao-Bin Qiu

doi:10.1007/s10118-020-2338-5

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Crystallization Behavior and Dynamic Mechanical Properties of Poly(ε-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared via Different Methods

ARTICLE | Updated：2019-10-10

- Crystallization Behavior and Dynamic Mechanical Properties of Poly(ε-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared via Different Methods
- Crystallization Behavior and Dynamic Mechanical Properties of Poly(ε-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared via Different Methods
- Chinese Journal of Polymer Science 2020年38卷第2期页码：158-163
- Affiliations：
  
  State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  jiangzg@mail.buct.edu.cn (Z.G.J.)
  qiuzb@mail.buct.edu.cn (Z.B.Q.)
- Funds：
  
  Part of this research was financially supported by the National Natural Science Foundation of China (Nos. 51373020 and 51573016).
- DOI：10.1007/s10118-020-2338-5
  中图分类号：
- 收稿：2019-04-28，
  
  修回：2019-6-25，
  
  录用：2019-7-19，
  
  网络首发：2019-10-10，
  
  纸质出版：2020-02
- Accepted：
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Teng, S. Q.; Jiang, Z. G.; Qiu, Z. B. Crystallization behavior and dynamic mechanical properties of poly(ε-caprolactone)/octaisobutyl-polyhedral oligomeric silsesquioxanes composites prepared via different methods. Chinese J. Polym. Sci. 2020, 38, 158–163.

Si-Qi Teng, Zhi-Guo Jiang, Zhao-Bin Qiu. Crystallization Behavior and Dynamic Mechanical Properties of Poly(ε-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared via Different Methods[J]. Chinese Journal of Polymer Science, 2020, 38(2): 158-163. DOI: 10.1007/s10118-020-2338-5.
Teng, S. Q.; Jiang, Z. G.; Qiu, Z. B. Crystallization behavior and dynamic mechanical properties of poly(ε-caprolactone)/octaisobutyl-polyhedral oligomeric silsesquioxanes composites prepared via different methods. Chinese J. Polym. Sci. 2020, 38, 158–163. DOI： 10.1007/s10118-020-2338-5.

Si-Qi Teng, Zhi-Guo Jiang, Zhao-Bin Qiu. Crystallization Behavior and Dynamic Mechanical Properties of Poly(ε-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared via Different Methods[J]. Chinese Journal of Polymer Science, 2020, 38(2): 158-163. DOI: 10.1007/s10118-020-2338-5. DOI：

摘要

Abstract

Two octaisobutyl-polyhedral oligomeric silsesquioxanes (oib-POSS) reinforced biodegradable poly(

-caprolactone) (PCL) composites were prepared

via

two different methods

i.e.

melt compounding and solution casting

which were named as mPCL/oib-POSS and sPCL/oib-POSS

respectively

in this work. Oib-POSS dispersed finely in both composites; moreover

oib-POSS aggregates were larger in mPCL/oib-POSS than in sPCL/oib-POSS. Despite the different preparation methods

oib-POSS obviously promoted the crystallization of PCL

especially in sPCL/oib-POSS

but did not modify the crystal structure of PCL. The storage moduli of PCL were improved significantly in both composites. PCL/oib-POSS composites with enhanced crystallization behavior and improved dynamic mechanical properties were successfully prepared through both methods; moreover

the solution casting method was more effective than the melt compounding method.

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Keywords

references

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Crystallization Behavior and Dynamic Mechanical Properties of Poly(ε-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared via Different Methods

Crystallization Behavior and Dynamic Mechanical Properties of Poly(ε-caprolactone)/Octaisobutyl-Polyhedral Oligomeric Silsesquioxanes Composites Prepared via Different Methods

DOI：10.1007/s10118-020-2338-5

摘要

Abstract

关键词

Keywords

references