Cross-linked Polyamides Prepared through Direct Bulk Michael Addition and Polycondensation from 1,6-Hexanediamine and Methyl Acrylate

Sheng-Qing Yang; Jin-Nan Zhao; Jing-Bo Zhao; Zhi-Yuan Zhang; Jun-Ying Zhang

doi:10.1007/s10118-019-2332-y

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Cross-linked Polyamides Prepared through Direct Bulk Michael Addition and Polycondensation from 1,6-Hexanediamine and Methyl Acrylate

ARTICLE | Updated：2019-10-12

- Cross-linked Polyamides Prepared through Direct Bulk Michael Addition and Polycondensation from 1,6-Hexanediamine and Methyl Acrylate
- Cross-linked Polyamides Prepared through Direct Bulk Michael Addition and Polycondensation from 1,6-Hexanediamine and Methyl Acrylate
- Chinese Journal of Polymer Science 2020年38卷第2期页码：143-150
- Affiliations：
  
  Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  zhaojb@mail.buct.edu.cn (J.B.Z.)
  zhangjy@mail.buct.edu.cn (J.Y.Z.)
- Funds：
  
  This work was financially supported by the Beijing Natural Science Foundation (No. 2182056) and the National Natural Science Foundation of China (No. 21244006).
- DOI：10.1007/s10118-019-2332-y
  中图分类号：
- 收稿：2019-04-22，
  
  修回：2019-7-5，
  
  录用：2019-7-19，
  
  网络首发：2019-10-12，
  
  纸质出版：2020-02
- Accepted：
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Citation: Yang, S. Q.; Zhao, J. N.; Zhao, J. B.; Zhang, Z. Y.; Zhang, J. Y. Cross-linked polyamides prepared through direct bulk Michael addition and polycondensation from 1,6-hexanediamine and methyl acrylate. Chinese J. Polym. Sci. 2020, 38, 143–150

Sheng-Qing Yang, Jin-Nan Zhao, Jing-Bo Zhao, et al. Cross-linked Polyamides Prepared through Direct Bulk Michael Addition and Polycondensation from 1,6-Hexanediamine and Methyl Acrylate[J]. Chinese Journal of Polymer Science, 2020, 38(2): 143-150.
Citation: Yang, S. Q.; Zhao, J. N.; Zhao, J. B.; Zhang, Z. Y.; Zhang, J. Y. Cross-linked polyamides prepared through direct bulk Michael addition and polycondensation from 1,6-hexanediamine and methyl acrylate. Chinese J. Polym. Sci. 2020, 38, 143–150 DOI： 10.1007/s10118-019-2332-y.

Sheng-Qing Yang, Jin-Nan Zhao, Jing-Bo Zhao, et al. Cross-linked Polyamides Prepared through Direct Bulk Michael Addition and Polycondensation from 1,6-Hexanediamine and Methyl Acrylate[J]. Chinese Journal of Polymer Science, 2020, 38(2): 143-150. DOI： 10.1007/s10118-019-2332-y.

摘要

Abstract

Cross-linked polyamides (cPAs) were prepared through direct bulk Michael addition and subsequent polycondensation. Several mixed hexanediamine multi-esters (HDAMEs) were generated through the Michael addition of 1

6-hexanediamine (HDA) and methyl acrylate (MA) at 50 °C with different HDA/MA molar ratios. Melt polycondensation of HDAMEs then proceeded at 150 or 170 °C in flasks to obtain viscous fluids

and curing was continued in tetrafluoroethylene molds to obtain cPA films. The Michael addition was monitored on the basis of FTIR and ESI-MS spectra. The cPA films were characterized by DSC

TGA

dynamic mechanical analysis

and tensile test. These directly prepared cPAs exhibited

of 1–39 °C

tensile strength of up to 45 MPa

and strain at break from 18% to 40%. The cPAs with high tensile strength and good toughness were successfully synthesized through the direct bulk Michael addition from HDA and MA followed with polycondensation.

关键词

Keywords

references

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