Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property

Shi-Xuan Yang; Zi-Yu Fan; Feng-Yu Zhang; Si-Hao Li; Yi-Xian Wu

doi:10.1007/s10118-019-2329-6

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Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property

ARTICLE | Updated：2021-02-18

- Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property
- Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property
- Chinese Journal of Polymer Science 2019年37卷第9期页码：919-929
- Affiliations：
  
  State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  wuyx@mail.buct.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21574007 and 51521062) and the Fundamental Research Funds for the Central Universities (No. XK1802-2).
- DOI：10.1007/s10118-019-2329-6
  中图分类号：
- 收稿：2019-06-17，
  
  修回：2019-1-1，
  
  录用：2019-7-9，
  
  网络首发：2019-07-24，
  
  纸质出版：2019-09
- Accepted：
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Citation: Yang, S. X.; Fan, Z. Y.; Zhang, F. Y.; Li, S. H.; Wu, Y. X. Functionalized copolymers of isobutylene with vinyl phenol: Synthesis, characterization, and property. Chinese J. Polym. Sci. 2019, 37, 919–929

Shi-Xuan Yang, Zi-Yu Fan, Feng-Yu Zhang, et al. Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property[J]. Chinese Journal of Polymer Science, 2019, 37(9): 919-929.
Citation: Yang, S. X.; Fan, Z. Y.; Zhang, F. Y.; Li, S. H.; Wu, Y. X. Functionalized copolymers of isobutylene with vinyl phenol: Synthesis, characterization, and property. Chinese J. Polym. Sci. 2019, 37, 919–929 DOI： 10.1007/s10118-019-2329-6.

Shi-Xuan Yang, Zi-Yu Fan, Feng-Yu Zhang, et al. Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property[J]. Chinese Journal of Polymer Science, 2019, 37(9): 919-929. DOI： 10.1007/s10118-019-2329-6.

摘要

Abstract

The random copolymers of isobutylene (IB) with polar comonomers of 4-acetoxystyrene (ACS) or 4-

tert

-butoxystyrene (TBO)

P(IB-

-ACS) and P(IB-

-TBO)

could be successfully synthesized

via

cationic copolymerization with FeCl

-based initiating system. The kinetics of the cationic copolymerization process was

in situ

investigated by inserting a diamond probe into the reaction system by ATR-FTIR spectroscopy. The chemical structure and incorporation content of polar comonomers in the copolymers were characterized by GPC with RI/UV dual detectors and

H-NMR spectroscopy. The corresponding functionalized random copolymers of IB with vinyl phenol P(IB-

-POH) carrying phenolic hydroxyl side groups could be further prepared

via

the complete hydrolysis of acetoxyl side groups in P(IB-

-ACS) or

tert

-butoxyl side groups in P(IB-

-TBO) copolymers. The functionalized P(IB-

-POH) copolymers became hydrophilic with water contact angle (WCA) of

. 80° for the self-assembly in hot water

compared to the hydrophobic polyisobutylene with WCA of

. 110°. The functionalized P(IB-

-POH) copolymers also displayed an excellent self-healing property due to the interaction of intermolecular hydrogen bonding and formation of three dimentional supramolecular networks from phenolic hydroxyl side groups. Furthermore

P(IB-

-POH) copolymers also provided a good matrix for the homogeneous dispersion for silica nanoparticles due to the formation of hydrogen bonding between copolymer chains and silica nanoparticles.

关键词

Keywords

references

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