Directed Self-assembly of Vertical PS-<italic style="font-style: italic">b</italic>-PMMA Nanodomains Grown on Multilayered Polyelectrolyte Films

Kai Liu; Chun-Ming Yang; Bo-Ming Yang; Lan Zhang; Wen-Chao Huang; Xiao-Ping Ouyang; Fu-Gang Qi; Nie Zhao; Feng-Gang Bian

doi:10.1007/s10118-019-2315-z

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Directed Self-assembly of Vertical PS-b-PMMA Nanodomains Grown on Multilayered Polyelectrolyte Films

ARTICLE | Updated：2019-09-19

- Directed Self-assembly of Vertical PS-b-PMMA Nanodomains Grown on Multilayered Polyelectrolyte Films
- Directed Self-assembly of Vertical PS-b-PMMA Nanodomains Grown on Multilayered Polyelectrolyte Films
- Chinese Journal of Polymer Science 2020年38卷第1期页码：92-99
- Affiliations：
  
  a.College of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, China
  b.Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201204, China
  c.Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China
- Author bio：
  
  zhaonie@xtu.edu.cn (N.Z.)
  bianfenggang@sinap.ac.cn (F.G.B.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 11605149, 11405259, U1932118, and U1732123), the Natural Science Foundation of Hunan Province (No. 2017JJ3309), the China Postdoctoral Science Foundation (No. 2017 M622595), the Zhejiang Public Service Technology Research Program/Analytical Test (No. LGC19F040001), the National Key R&D Program of China (No. 2017YFA0403000), and the Science and Technology Commission of Shanghai Municipality (No. 17JC1400802).
- DOI：10.1007/s10118-019-2315-z
  中图分类号：
- 收稿：2019-05-20，
  
  修回：2019-6-11，
  
  录用：2019-6-13，
  
  网络首发：2019-09-19，
  
  纸质出版：2020-01
- Accepted：
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Citation: Liu, K.; Yang, C. M.; Yang, B. M.; Zhang, L.; Huang, W. C.; Ouyang, X. P.; Qi, F. G.; Zhao, N.; Bian, F. G. Directed self-assembly of vertical PS-b-PMMA nanodomains grown on multilayered polyelectrolyte films. Chinese J. Polym. Sci. 2020, 38, 92–99

Kai Liu, Chun-Ming Yang, Bo-Ming Yang, et al. Directed Self-assembly of Vertical PS-b-PMMA Nanodomains Grown on Multilayered Polyelectrolyte Films[J]. Chinese Journal of Polymer Science, 2020, 38(1): 92-99. DOI: 10.1007/s10118-019-2315-z.
Citation: Liu, K.; Yang, C. M.; Yang, B. M.; Zhang, L.; Huang, W. C.; Ouyang, X. P.; Qi, F. G.; Zhao, N.; Bian, F. G. Directed self-assembly of vertical PS-b-PMMA nanodomains grown on multilayered polyelectrolyte films. Chinese J. Polym. Sci. 2020, 38, 92–99 DOI： 10.1007/s10118-019-2315-z.

Kai Liu, Chun-Ming Yang, Bo-Ming Yang, et al. Directed Self-assembly of Vertical PS-b-PMMA Nanodomains Grown on Multilayered Polyelectrolyte Films[J]. Chinese Journal of Polymer Science, 2020, 38(1): 92-99. DOI: 10.1007/s10118-019-2315-z. DOI：

摘要

Abstract

Layer-by-layer polyelectrolyte self-assembly

a common method for preparing high-quality ultra-thin films

was employed to direct the self-assembly behavior of polystyrene-block-poly(methyl methacrylate) (PS-

-PMMA) block copolymer for the first time. Differing from the previous neutral polymer brushes anchored to silicon substrates

via

chemical modification

polyelectrolyte multilayers (PEMs) were anchored by electrostatic interaction and provided a stable

smooth

and neutral interface. In the present study

PS-

-PMMA was deposited on poly(acrylamide hydrochloride)/poly(acrylic acid) (PAH/PAA) PEMs prepared by layer-by-layer self-assembly to successfully yield vertical nanodomains after thermal annealing. Seven layered PEMs revealed an excellent

smooth surface

with a low roughness of 0.6 nm. The periodic structure with interlamellar spacing of 47 nm was determined by grazing-incidence small-angle X-ray scattering (GISAXS). The morphology of the PS-

-PMMA nanodomains depended on the polyanion-to-polycation concentration ratio

which is related to the interaction between the block copolymer and the substrate. Our results demonstrate that layer-by-layer self-assembly is a helpful method for the phase separation of block polymers and the fabrication of vertical

ordered nanodomains.

关键词

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references

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Directed Self-assembly of Vertical PS-b-PMMA Nanodomains Grown on Multilayered Polyelectrolyte Films

Directed Self-assembly of Vertical PS-b-PMMA Nanodomains Grown on Multilayered Polyelectrolyte Films

DOI：10.1007/s10118-019-2315-z

摘要

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