Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales

Wei Zhao; Tian-Pin Wang; Jia-Li Wu; Ru-Ping Pan; Xiang-Yang Liu; Xi-Kui Liu

doi:10.1007/s10118-019-2313-1

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Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales

RAPID COMMUNICATION | Updated：2021-02-18

- Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales
- Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales
- Chinese Journal of Polymer Science 2019年37卷第11期页码：1045-1052
- Affiliations：
  
  College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  xkliu@scu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21674068 and 51633004).
- DOI：10.1007/s10118-019-2313-1
  中图分类号： M
- 收稿：2019-04-15，
  
  修回：2019-5-30，
  
  录用：2019-6-8，
  
  网络首发：2019-09-12，
  
  纸质出版：2019-11
- Accepted：
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Zhao, W.; Wang, T. P.; Wu, J. L.; Pan, R. P.; Liu, X. Y.; Liu, X. K. Monolithic covalent organic framework aerogels through framework crystallization induced self-assembly: Heading towards framework materials synthesis over all length scales. Chinese J. Polym. Sci. 2019, 37, 1045–1052.

Wei Zhao, Tian-Pin Wang, Jia-Li Wu, et al. Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1045-1052.
Zhao, W.; Wang, T. P.; Wu, J. L.; Pan, R. P.; Liu, X. Y.; Liu, X. K. Monolithic covalent organic framework aerogels through framework crystallization induced self-assembly: Heading towards framework materials synthesis over all length scales. Chinese J. Polym. Sci. 2019, 37, 1045–1052. DOI： 10.1007/s10118-019-2313-1.

Wei Zhao, Tian-Pin Wang, Jia-Li Wu, et al. Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1045-1052. DOI： 10.1007/s10118-019-2313-1.

摘要

Abstract

Here

through the synergism between kinetic dynamic imine-exchange control and thermodynamic control

rarely observed compressible

porous

crystalline covalent organic framework (COF) aerogels were synthesized

the mechanism behind which is a framework crystallization induced self-assembly (FCISA) process. The prepared COF aerogel possessed extremely high BET surface over 2000 m

·g

−1

and high maximum equilibrium adsorption capacity toward bisphenol-A of 699 mg·g

−1

in aqueous solution.

关键词

Keywords

references

Côté, A. P.; Benin, A. I.; Ockwig, N. W.; O'Keeffe, M.; Matzger, A. J.; Yaghi, O. M . Porous, crystalline, covalent organic frameworks . Science , 2005 . 310 1166 - 1170 . DOI: 10.1126/science.1120411 http://doi.org/10.1126/science.1120411 .

Oh, H.; Kalidindi, S. B.; Um, Y.; Bureekaew, S.; Schmid, R . A cryogenically flexible covalent organic framework for efficient hydrogen isotope separation by quantum sieving . Angew. Chem. Int. Ed. , 2013 . 52 13219 - 13222 . DOI: 10.1002/anie.201307443 http://doi.org/10.1002/anie.201307443 .

Ding, S. Y.; Wang, W . Covalent organic frameworks (COFs): From design to applications . Chem. Soc. Rev. , 2013 . 42 548 - 568 . DOI: 10.1039/C2CS35072F http://doi.org/10.1039/C2CS35072F .

Qian, H. L.; Yang, C. X.; Yan, X. P . Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation . Nat. Commun. , 2016 . 7 12104 - 12111 . DOI: 10.1038/ncomms12104 http://doi.org/10.1038/ncomms12104 .

Xu, H.; Chen, X.; Gao, J.; Lin, J. B.; Addicoat, M.; Irle, S.; Jiang, D. L . Catalytic covalent organic frameworks via pore surface engineering . Chem. Commun. , 2014 . 50 1292 - 1294 . DOI: 10.1039/C3CC48813F http://doi.org/10.1039/C3CC48813F .

Furukawa, H.; Yaghi, O. M . Storage of hydrogen, methane, and carbon dioxide in highly porous covalent organic frameworks for clean energy applications . J. Am. Chem. Soc. , 2009 . 131 8875 - 8883 . DOI: 10.1021/ja9015765 http://doi.org/10.1021/ja9015765 .

Deblase, C. R.; Silberstein, K. E.; Truong, T. T.; A, H. A.; Dichtel, W. R. Β . β -Ketoenamine-linked covalent organic frameworks capable of pseudocapacitive energy storage . J. Am. Chem. Soc. , 2013 . 135 16821 - 16824 . DOI: 10.1021/ja409421d http://doi.org/10.1021/ja409421d .

Peng, Y.; Zhao, M.; Chen, B.; Zhang, Z.; Huang, Y.; Dai, F.; Lai, Z.; Cui, X.; Tan, C.; Zhang, H . Hybridization of MOFs and COFs: A new strategy for construction of MOF@COF core-shell hybrid materials . Adv. Mater. , 2018 . 30 1705454 DOI: 10.1002/adma.v30.3 http://doi.org/10.1002/adma.v30.3 .

Gole, B.; Stepanenko, V.; Rager, S.; Grgne, M.; Medina, D. D.; Bein, T.; Wgrthner, F.; Beuerle, F . Microtubular self-assembly of covalent organic frameworks . Angew. Chem. Int. Ed. , 2018 . 57 846 - 850 . DOI: 10.1002/anie.201708526 http://doi.org/10.1002/anie.201708526 .

Halder, A.; Kandambeth, S.; Biswal, B. P.; Kaur, G.; Roy, N. C.; Addicoat, M.; Salunke, J. K.; Banerjee, S.; Vanka, K.; Heine, T.; Verma, S.; Banerjee, R . Decoding the morphological diversity in two dimensional crystalline porous polymers by core planarity modulation . Angew. Chem. Int. Ed. , 2016 . 55 7806 - 7810 . DOI: 10.1002/anie.201600087 http://doi.org/10.1002/anie.201600087 .

Kandambeth, S.; Venkatesh, V.; Shinde, D. B.; Kumari, S.; Halder, A.; Verma, S.; Banerjee, R . Self-templated chemically stable hollow spherical covalent organic framework . Nat. Commun. , 2015 . 16 6768 DOI: 10.1038/ncomms7786 http://doi.org/10.1038/ncomms7786 .

Tan, J.; Namuangruk, S.; Kong, W.; Kungwan, N.; Guo, J.; Wang, C . Manipulation of amorphous-to-crystalline transformation: Towards the construction of covalent organic framework hybrid microspheres with NIR photothermal conversion ability . Angew. Chem. Int. Ed. , 2016 . 55 13979 - 13984 . DOI: 10.1002/anie.v55.45 http://doi.org/10.1002/anie.v55.45 .

Sun, B.; Liu, J.; Cao, A.; Song, W.; Wang, D . Interfacial synthesis of ordered and stable covalent organic frameworks on amino-functionalized carbon nanotubes with enhanced electrochemical performance . Chem. Commun. , 2017 . 53 6303 - 6306 . DOI: 10.1039/C7CC01902E http://doi.org/10.1039/C7CC01902E .

Ma, T.; Kapustin, E. A.; Yin, S.; Liang, L.; Zhou. Z.; Niu, J.; Li, L.; Wang, Y.; Su, J.; Li, J.; Wang, X.; Wang, W.; Wang, W.; Sun, J.; Yaghi, O. M . Single-crystal X-ray diffraction structures of covalent organic frameworks . Science , 2018 . 361 48 - 52 . DOI: 10.1126/science.aat7679 http://doi.org/10.1126/science.aat7679 .

Evans, A. M.; Parent, L. R.; Flanders, N. C.; Bisbey, R. P.; Vitaku, E.; Kirschner, M. S; Schaller, R. D.; Chen, L. X.; Gianneschi, N. C.; Dichtel, W. R . Seeded growth of single-crystal two-dimensional covalent organic frameworks . Science , 2018 . 361 52 - 57 . DOI: 10.1126/science.aar7883 http://doi.org/10.1126/science.aar7883 .

Dogru, M.; Handloser, M.; Auras, F.; Kunz, T.; Medina, D. A . A photoconductive thienothiophene-based covalent organic framework showing charge transfer towards included fullerene . Angew. Chem. Int. Ed. , 2013 . 125 2992 - 2996 . DOI: 10.1002/ange.201208514 http://doi.org/10.1002/ange.201208514 .

Feng, X.; Chen, L.; Honsho, Y.; Saengsawang, O.; Liu, L. L.; Wang, L.; Saeki, A.; Irle, S.; Seki, S.; Dong, Y. P.; Jiang, D. L . An ambipolar conducting covalent organic framework with self-sorted and periodic electron donor-acceptor ordering . Adv. Mater. , 2012 . 24 3026 - 3031 . DOI: 10.1002/adma.v24.22 http://doi.org/10.1002/adma.v24.22 .

Ding, S. Y.; Gao, J.; Wang, Q.; Zhang, Y.; Song, W. G.; Su, C. Y.; Wang, W . Construction of covalent organic framework for catalysis: Pd/COF-LZU1 in Suzuki-Miyaura coupling reaction . J. Am. Chem. Soc. , 2011 . 133 19816 - 19822 . DOI: 10.1021/ja206846p http://doi.org/10.1021/ja206846p .

Calik, M.; Auras, F.; Salonen, L. M.; Bader, K.; Grill, I.; Handloser, M.; Medina, D. D.; Dogru, M.; Löbermann, F.; Trauner, D.; Hartschuh, A.; Bein, T . Extraction of photogenerated electrons and holes from a covalent organic framework integrated heterojunction . J. Am. Chem. Soc. , 2014 . 136 17802 - 17807 . DOI: 10.1021/ja509551m http://doi.org/10.1021/ja509551m .

Warren, N. J.; Armes, S. P . Polymerization-induced self-assembly of block copolymer nano-objects via RAFT aqueous dispersion polymerization . J. Am. Chem. Soc. , 2014 . 136 10174 - 10185 . DOI: 10.1021/ja502843f http://doi.org/10.1021/ja502843f .

Smith, B. J.; Hwang, N.; Chavez, A. D.; Novotney, J. L.; Dichtel, W. R . Growth rates and water stability of 2D boronate ester covalent organic frameworks . Chem. Commun. , 2015 . 51 7532 - 7535 . DOI: 10.1039/C5CC00379B http://doi.org/10.1039/C5CC00379B .

Smith, B. J.; Overholts, A. C.; Hwang, N.; Dichtel, W. R . Insight into the crystallization of amorphous imine-linked polymer networks to 2D covalent organic frameworks . Chem. Commun. , 2016 . 52 3690 - 3693 . DOI: 10.1039/C5CC10221A http://doi.org/10.1039/C5CC10221A .

Smith, B. J.; Dichtel, W. R . Mechanistic studies of two-dimensional covalent organic frameworks rapidly polymerized from initially homogenous conditions . J. Am. Chem. Soc. , 2014 . 136 8783 - 8789 . DOI: 10.1021/ja5037868 http://doi.org/10.1021/ja5037868 .

Bunck, D. N.; Dichtel, W. R . Internal functionalization of three-dimensional covalent organic frameworks . Angew. Chem. Int. Ed. , 2012 . 51 1885 - 1889 . DOI: 10.1002/anie.v51.8 http://doi.org/10.1002/anie.v51.8 .

Vitaku, E.; Dichtel, W. R . Synthesis of 2D imine-linked covalent organic frameworks through formal transimination reactions . J. Am. Chem. Soc. , 2017 . 139 12911 - 12914 . DOI: 10.1021/jacs.7b06913 http://doi.org/10.1021/jacs.7b06913 .

Biswal, B. P.; Chandra, S.; Kandambeth, S.; Lukose, B.; Heine, T.; Banerjee, R . Mechanochemical synthesis of chemically stable isoreticular covalent organic frameworks . J. Am. Chem. Soc. , 2013 . 135 5328 - 5331 . DOI: 10.1021/ja4017842 http://doi.org/10.1021/ja4017842 .

Huang, W.; Jiang, Y.; Li, X.; Li, X. J.; Wang, J. Y.; Wu, Q.; Liu, X. K . Solvothermal synthesis of microporous, crystalline covalent organic framework nanofibers and their colorimetric nanohybrid structures . ACS Appl. Mater. Interfaces , 2013 . 5 8845 - 8849 . DOI: 10.1021/am402649g http://doi.org/10.1021/am402649g .

Xu, H.; Tao, S. S.; Jiang, D. L . Proton conduction in crystalline and porous covalent organic frameworks . Nat. Mater. , 2016 . 15 722 - 726 . DOI: 10.1038/nmat4611 http://doi.org/10.1038/nmat4611 .

Kandambeth, S.; Mallick, A.; Lukose, B.; Mane, M. V.; Heine, T.; Banerjee, R . Construction of crystalline 2D covalent organic frameworks with remarkable chemical (acid/base) stability via a combined reversible and irreversible route . J. Am. Chem. Soc. , 2012 . 134 19524 - 19527 . DOI: 10.1021/ja308278w http://doi.org/10.1021/ja308278w .

Kuecken, S.; Schmidt, J.; Zhi, L.; Thomas, A . Conversion of amorphous polymer networks to covalent organic frameworks under ionothermal conditions: A facile synthesis route for covalent triazine frameworks . J. Mater. Chem. A , 2015 . 3 24422 - 24427 . DOI: 10.1039/C5TA07408H http://doi.org/10.1039/C5TA07408H .

Gao, Q.; Bai, L.; Zeng, Y.; Wang, P.; Zhang, X.; Zou, R.; Zhao, Y . Reconstruction of covalent organic frameworks by dynamic equilibrium . Chemistry , 2015 . 21 16818 - 16822 . DOI: 10.1002/chem.v21.47 http://doi.org/10.1002/chem.v21.47 .

Iwasawa, N.; Takahagi, H . Boronic esters as a system for crystallization-induced dynamic self-assembly equipped with an " on-off” switch for equilibration . J. Am. Chem. Soc. , 2007 . 129 7754 - 7755 . DOI: 10.1021/ja072319q http://doi.org/10.1021/ja072319q .

Gilroy, J. B.; Gädt, T.; Whittell, G. R.; Chabanne, L.; Mitchels, J. M.; Richardson, R. M.; Winnik, M. A.; Manners, I . Monodisperse cylindrical micelles by crystallization-driven living self-assembly . Nat. Chem. , 2010 . 2 566 - 570 . DOI: 10.1038/nchem.664 http://doi.org/10.1038/nchem.664 .

Chandra, S.; Kandambeth, S.; Biswal, B. P.; Lukose, B.; Kunjir, S. M.; Chaudhary, M.; Babarao, R.; Heine, T.; Banerjee, R . Chemically stable multilayered covalent organic nanosheets from covalent organic frameworks via mechanical delamination . J. Am. Chem. Soc. , 2013 . 135 17853 - 17861 . DOI: 10.1021/ja408121p http://doi.org/10.1021/ja408121p .

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