Dendronized Polymers with High FTC-chromophore Loading Density: Large Second-order Nonlinear Optical Effects, Good Temporal and Thermal Stability

Meng Jin; Zhao-Chen Zhu; Qiu-Yan Liao; Qian-Qian Li; Zhen Li

doi:10.1007/s10118-019-2307-z

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Dendronized Polymers with High FTC-chromophore Loading Density: Large Second-order Nonlinear Optical Effects, Good Temporal and Thermal Stability

ARTICLE | Updated：2019-09-24

- Dendronized Polymers with High FTC-chromophore Loading Density: Large Second-order Nonlinear Optical Effects, Good Temporal and Thermal Stability
- Dendronized Polymers with High FTC-chromophore Loading Density: Large Second-order Nonlinear Optical Effects, Good Temporal and Thermal Stability
- Chinese Journal of Polymer Science 2020年38卷第2期页码：118-125
- Affiliations：
  
  a.Department of Chemistry, Sauvage Center for Molecular Sciences, Wuhan University, Wuhan 430072, China
  b.Institute of Molecular Aggregation Science, Tianjin University, Tianjin 300072, China
- Author bio：
  
  qianqian-alinda@163.com (Q.Q.L.)
  lizhen@whu.edu.cn,lichemlab@163.com (Z.L.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 21734007).
- DOI：10.1007/s10118-019-2307-z
  中图分类号：
- 收稿：2019-05-04，
  
  修回：2019-5-23，
  
  录用：2019-5-25，
  
  网络首发：2019-09-24，
  
  纸质出版：2020-02
- Accepted：
Scan QR Code
Jin, M.; Zhu, Z. C.; Liao, Q. Y.; Li, Q. Q.; Li, Z. Dendronized polymers with high FTC-chromophore loading density: large second-order nonlinear optical effects, good temporal and thermal stability. Chinese J. Polym. Sci. 2020, 38, 118–125.

Meng Jin, Zhao-Chen Zhu, Qiu-Yan Liao, et al. Dendronized Polymers with High FTC-chromophore Loading Density: Large Second-order Nonlinear Optical Effects, Good Temporal and Thermal Stability[J]. Chinese Journal of Polymer Science, 2020, 38(2): 118-125.
Jin, M.; Zhu, Z. C.; Liao, Q. Y.; Li, Q. Q.; Li, Z. Dendronized polymers with high FTC-chromophore loading density: large second-order nonlinear optical effects, good temporal and thermal stability. Chinese J. Polym. Sci. 2020, 38, 118–125. DOI： 10.1007/s10118-019-2307-z.

Meng Jin, Zhao-Chen Zhu, Qiu-Yan Liao, et al. Dendronized Polymers with High FTC-chromophore Loading Density: Large Second-order Nonlinear Optical Effects, Good Temporal and Thermal Stability[J]. Chinese Journal of Polymer Science, 2020, 38(2): 118-125. DOI： 10.1007/s10118-019-2307-z.

摘要

Abstract

In this study

two new dendronized nonlinear optical (NLO) polymers were synthesized with high FTC chromophore loading density by introduction of high generation chromophore dendrons on the side chains. Due to their suitable molecular weights

both of them possessed good solubility in common solvents. They also inherited the advantages of dendrimers (large NLO coefficient)

especially for

PG2

whose NLO coefficient

value was as high as 282 pm·V

–1

. Also

PG2

had a good temporal stability with 80% of its maximum value being retained at the temperature as high as 129 °C.

关键词

Keywords

references

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