Effect of Butyl <italic style="font-style: italic">α</italic>-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced <italic style="font-style: italic">via</italic> Aqueous Emulsion Polymerization-induced Self-assembly

Shou-Kuo Man; Xiao Wang; Jin-Wen Zheng; Ze-Sheng An

doi:10.1007/s10118-019-2303-3

Your Location：

Home >

Browse articles >

Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly

ARTICLE | Updated：2019-09-06

- Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly
- Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly
- Chinese Journal of Polymer Science 2020年38卷第1期页码：9-16
- Affiliations：
  
  a.Institute of Nanochemistry and Nanobiology, College of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
  b.State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China
- Author bio：
  
  wangxiao93@t.shu.edu.cn (X.W.)
  anzesheng@jiu.edu.cn (Z.S.A.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 21674059).
- DOI：10.1007/s10118-019-2303-3
  中图分类号：
- 收稿：2019-04-12，
  
  修回：2019-5-17，
  
  录用：2019-5-25，
  
  网络首发：2019-09-06，
  
  纸质出版：2020-01
- Accepted：
Scan QR Code
Citation: Man, S. K.; Wang, X.; Zheng, J. W.; An, Z. S. Effect of butyl α-hydroxymethyl acrylate monomer structure on the morphology produced via aqueous emulsion polymerization-induced self-assembly. Chinese J. Polym. Sci. 2020, 38, 9–16

Shou-Kuo Man, Xiao Wang, Jin-Wen Zheng, et al. Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly[J]. Chinese Journal of Polymer Science, 2020, 38(1): 9-16. DOI: 10.1007/s10118-019-2303-3.
Citation: Man, S. K.; Wang, X.; Zheng, J. W.; An, Z. S. Effect of butyl α-hydroxymethyl acrylate monomer structure on the morphology produced via aqueous emulsion polymerization-induced self-assembly. Chinese J. Polym. Sci. 2020, 38, 9–16 DOI： 10.1007/s10118-019-2303-3.

Shou-Kuo Man, Xiao Wang, Jin-Wen Zheng, et al. Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly[J]. Chinese Journal of Polymer Science, 2020, 38(1): 9-16. DOI: 10.1007/s10118-019-2303-3. DOI：

摘要

Abstract

Polymerization-induced self-assembly (PISA) is an efficient and versatile method to afford polymeric nano-objects with polymorphic morphologies. Compared to dispersion PISA syntheses based on soluble monomers

the vast majority of emulsion PISA formulations using insoluble monomers leads to kinetically-trapped spheres. Herein

we present aqueous emulsion PISA formulations generating worms and vesicles besides spheres. Two monomers with different butyl groups

-butyl (

BHMA) and

tert

-butyl (

BHMA)

-hydroxymethyl acrylate

and thus possessing different water solubilities were synthesized

via

Baylis-Hillman reaction. Photoinitiated aqueous emulsion polymerizations of

BHMA and

BHMA employing poly(ethylene glycol) macromolecular chain transfer agents (macro-CTAs

PEG

-CTA

and PEG

113

-CTA) at 40 °C were systematically investigated to evaluate the effect of monomer structure and solubility on the morphology of the generated block copolymer nano-objects. Higher order morphologies including worms and vesicles were readily accessed for

BHMA

which has a higher water solubility than that of

BHMA. This study proves that plasticization of the core-forming block by water plays a key role in enhancing chain mobility required for morphological transition in emulsion PISA.

关键词

Keywords

references

Zhang, W. J.; Hong, C. Y.; Pan, C. Y . Formation of hexagonally packed hollow hoops and morphology transition in RAFT ethanol dispersion polymerization . Macromol. Rapid Commun. , 2015 . 36 1428 - 1436 . DOI: 10.1002/marc.v36.15 http://doi.org/10.1002/marc.v36.15 .

Gao, P.; Cao, H.; Ding, Y.; Cai, M.; Cui, Z.; Lu, X.; Cai, Y . Synthesis of hydrogen-bonded pore-switchable cylindrical vesicles via visible-light-mediated RAFT room-temperature aqueous dispersion polymerization . ACS Macro Lett. , 2016 . 5 1327 - 1331 . DOI: 10.1021/acsmacrolett.6b00796 http://doi.org/10.1021/acsmacrolett.6b00796 .

Li, Y.; Armes, S. P . RAFT synthesis of sterically stabilized methacrylic nanolatexes and vesicles by aqueous dispersion polymerization . Angew. Chem. Int. Ed. , 2010 . 49 4042 - 6 . DOI: 10.1002/anie.201001461 http://doi.org/10.1002/anie.201001461 .

Zhou, W.; Qu, Q.; Xu, Y.; An, Z . Aqueous polymerization-induced self-assembly for the synthesis of ketone-functionalized nano-objects with low polydispersity . ACS Macro Lett. , 2015 . 4 495 - 499 . DOI: 10.1021/acsmacrolett.5b00225 http://doi.org/10.1021/acsmacrolett.5b00225 .

Canning, S. L.; Smith, G. N.; Armes, S. P . A critical appraisal of RAFT-mediated polymerization-induced self-assembly . Macromolecules , 2016 . 49 1985 - 2001 . DOI: 10.1021/acs.macromol.5b02602 http://doi.org/10.1021/acs.macromol.5b02602 .

Warren, N. J.; Armes, S. P . Polymerization-induced self-assembly of block copolymer nano-objects via RAFT aqueous dispersion polymerization . J. Am. Chem. Soc. , 2014 . 136 10174 - 10185 . DOI: 10.1021/ja502843f http://doi.org/10.1021/ja502843f .

Huo, M.; Zhang, Y.; Zeng, M.; Liu, L.; Wei, Y.; Yuan, J . Morphology evolution of polymeric assemblies regulated with fluoro-containing mesogen in polymerization-induced self-assembly . Macromolecules , 2017 . 50 8192 - 8201 . DOI: 10.1021/acs.macromol.7b01437 http://doi.org/10.1021/acs.macromol.7b01437 .

Guan, S.; Zhang, C.; Wen, W.; Qu, T.; Zheng, X.; Zhao, Y.; Chen, A . Formation of anisotropic liquid crystalline nanoparticles via polymerization-induced hierarchical self-assembly . ACS Macro Lett. , 2018 . 7 358 - 363 . DOI: 10.1021/acsmacrolett.8b00082 http://doi.org/10.1021/acsmacrolett.8b00082 .

Wang, X.; Shen, L.; An, Z . Dispersion polymerization in environmentally benign solvents via reversible deactivation radical polymerization . Prog. Polym. Sci. , 2018 . 83 1 - 27 . DOI: 10.1016/j.progpolymsci.2018.05.003 http://doi.org/10.1016/j.progpolymsci.2018.05.003 .

Wang, X.; An, Z . New insights into RAFT dispersion polymerization-induced self-assembly: from monomer library, morphological control, and stability to driving forces . Macromol. Rapid Commun. , 2019 . 40 1800325 DOI: 10.1002/marc.v40.2 http://doi.org/10.1002/marc.v40.2 .

Derry, M. J.; Fielding, L. A.; Armes, S. P . Polymerization-induced self-assembly of block copolymer nanoparticles via RAFT non-aqueous dispersion polymerization . Prog. Polym. Sci. , 2016 . 52 1 - 18 . DOI: 10.1016/j.progpolymsci.2015.10.002 http://doi.org/10.1016/j.progpolymsci.2015.10.002 .

Shi, P.; Zhou, H.; Gao, C.; Wang, S.; Sun, P.; Zhang, W . Macro-RAFT agent mediated dispersion copolymerization: a small amount of solvophilic co-monomer leads to a great change . Polym. Chem. , 2015 . 6 4911 - 4920 . DOI: 10.1039/C5PY00697J http://doi.org/10.1039/C5PY00697J .

Figg, C. A.; Simula, A.; Gebre, K. A.; Tucker, B. S.; Haddleton, D. M.; Sumerlin, B. S . Polymerization-induced thermal self-assembly (PITSA) . Chem. Sci. , 2015 . 6 1230 - 1236 . DOI: 10.1039/C4SC03334E http://doi.org/10.1039/C4SC03334E .

Sugihara, S.; Ma'Radzi, A. H.; Ida, S.; Irie, S.; Kikukawa, T.; Maeda, Y . In situ nano-objects via RAFT aqueous dispersion polymerization of 2-methoxyethyl acrylate using poly(ethylene oxide) macromolecular chain transfer agent as steric stabilizer . Polymer , 2015 . 76 17 - 24 . DOI: 10.1016/j.polymer.2015.08.051 http://doi.org/10.1016/j.polymer.2015.08.051 .

Chen, S. L.; Shi, P. F.; Zhang, W. Q . In situ synthesis of block copolymer nano-assemblies by polymerization-induced self-assembly under heterogeneous condition . Chinese J. Polym. Sci. , 2017 . 35 455 - 455 . DOI: 10.1007/s10118-017-1907-8 http://doi.org/10.1007/s10118-017-1907-8 .

Wan, W. M.; Hong, C. Y.; Pan, C. Y . One-pot synthesis of nanomaterials via RAFT polymerization induced self-assembly and morphology transition . Chem. Commun. , 2009 . 5883 .

Wan, W. M.; Pan, C. Y . One-pot synthesis of polymeric nanomaterials via RAFT dispersion polymerization induced self-assembly and re-organization . Polym. Chem. , 2010 . 1 1475 - 1484 . DOI: 10.1039/c0py00124d http://doi.org/10.1039/c0py00124d .

Tritschler, U.; Pearce, S.; Gwyther, J.; Whittell, G. R.; Manners, I . 50 th Anniversary perspective: functional nanoparticles from the solution self-assembly of block copolymers . Macromolecules , 2017 . 50 3439 - 3463 . DOI: 10.1021/acs.macromol.6b02767 http://doi.org/10.1021/acs.macromol.6b02767 .

Zhang, W.; D’Agosto, F.; Boyron, O.; Rieger, J.; Charleux, B . Toward a better understanding of the parameters that lead to the formation of nonspherical polystyrene particles via RAFT-mediated one-pot aqueous emulsion polymerization . Macromolecules , 2012 . 45 4075 - 4084 . DOI: 10.1021/ma300596f http://doi.org/10.1021/ma300596f .

Zhang, B.; Lv, X.; An, Z . Modular monomers with tunable solubility: synthesis of highly incompatible block copolymer nano-objects via RAFT aqueous dispersion polymerization . ACS Macro Lett. , 2017 . 6 224 - 228 . DOI: 10.1021/acsmacrolett.7b00056 http://doi.org/10.1021/acsmacrolett.7b00056 .

Wang, X.; Man, S.; Zheng, J.; An, Z . Alkyl α -hydroxymethyl acrylate monomers for aqueous dispersion polymerization-induced self-assembly . ACS Macro Lett. , 2018 . 7 1461 - 1467 . DOI: 10.1021/acsmacrolett.8b00839 http://doi.org/10.1021/acsmacrolett.8b00839 .

Yu, Q.; Ding, Y.; Cao, H.; Lu, X.; Cai, Y . Use of polyion complexation for polymerization-induced self-assembly in water under visible light irradiation at 25 °C . ACS Macro Lett. , 2015 . 4 1293 - 1296 . DOI: 10.1021/acsmacrolett.5b00699 http://doi.org/10.1021/acsmacrolett.5b00699 .

Ding, Y.; Cai, M.; Cui, Z.; Huang, L.; Wang, L.; Lu, X.; Cai, Y . Synthesis of low-dimensional polyion complex nanomaterials via polymerization-induced electrostatic self-assembly . Angew. Chem. Int. Ed. , 2018 . 57 1053 - 1056 . DOI: 10.1002/anie.201710811 http://doi.org/10.1002/anie.201710811 .

Cai, M.; Ding, Y.; Wang, L.; Huang, L.; Lu, X.; Cai, Y . Synthesis of one-component nanostructured polyion complexes via polymerization-induced electrostatic self-assembly . ACS Macro Lett. , 2018 . 7 208 - 212 . DOI: 10.1021/acsmacrolett.8b00005 http://doi.org/10.1021/acsmacrolett.8b00005 .

Chen, X.; Liu, L.; Huo, M.; Zeng, M.; Peng, L.; Feng, A.; Wang, X.; Yuan, J . Direct synthesis of polymer nanotubes by aqueous dispersion polymerization of a cyclodextrin/styrene complex . Angew. Chem. Int. Ed. , 2017 . 56 16541 - 16545 . DOI: 10.1002/anie.201709129 http://doi.org/10.1002/anie.201709129 .

Blanazs, A.; Madsen, J.; Battaglia, G.; Ryan, A. J.; Armes, S. P . Mechanistic insights for block copolymer morphologies: how do worms form vesicles? . J. Am. Chem. Soc. , 2011 . 133 16581 - 7 . DOI: 10.1021/ja206301a http://doi.org/10.1021/ja206301a .

Shen, L.; Guo, H.; Zheng, J.; Wang, X.; Yang, Y.; An, Z . RAFT Polymerization-induced self-assembly as a strategy for versatile synthesis of semifluorinated liquid-crystalline block copolymer nanoobjects . ACS Macro Lett. , 2018 . 7 287 - 292 . DOI: 10.1021/acsmacrolett.8b00070 http://doi.org/10.1021/acsmacrolett.8b00070 .

Chambon, P.; Blanazs, A.; Battaglia, G.; Armes, S. P . Facile synthesis of methacrylic ABC triblock copolymer vesicles by RAFT aqueous dispersion polymerization . Macromolecules , 2012 . 45 5081 - 5090 . DOI: 10.1021/ma300816m http://doi.org/10.1021/ma300816m .

Huo, M.; Zeng, M.; Li, D.; Liu, L.; Wei, Y.; Yuan, J . Tailoring the multicompartment nanostructures of fluoro-containing ABC triblock terpolymer assemblies via polymerization-induced self-assembly . Macromolecules , 2017 . 50 8212 - 8220 . DOI: 10.1021/acs.macromol.7b01629 http://doi.org/10.1021/acs.macromol.7b01629 .

Gao, C.; Wu, J.; Zhou, H.; Qu, Y.; Li, B.; Zhang, W . Self-assembled blends of AB/BAB block copolymers prepared through dispersion RAFT polymerization . Macromolecules , 2016 . 49 4490 - 4500 . DOI: 10.1021/acs.macromol.6b00771 http://doi.org/10.1021/acs.macromol.6b00771 .

Zhang, W. J.; Hong, C. Y.; Pan, C. Y . Fabrication of spaced concentric vesicles and polymerizations in RAFT dispersion polymerization . Macromolecules , 2014 . 47 1664 - 1671 . DOI: 10.1021/ma402497y http://doi.org/10.1021/ma402497y .

Gao, C.; Zhou, H.; Qu, Y.; Wang, W.; Khan, H.; Zhang, W . In situ synthesis of block copolymer nanoassemblies via polymerization-induced self-assembly in poly(ethylene glycol) . Macromolecules , 2016 . 49 3789 - 3798 . DOI: 10.1021/acs.macromol.6b00688 http://doi.org/10.1021/acs.macromol.6b00688 .

Lowe, A. B . RAFT alcoholic dispersion polymerization with polymerization-induced self-assembly . Polymer , 2016 . 106 161 - 181 . DOI: 10.1016/j.polymer.2016.08.082 http://doi.org/10.1016/j.polymer.2016.08.082 .

Huo, M.; Li, D.; Song, G.; Zhang, J.; Wu, D.; Wei, Y.; Yuan, J . Semi-fluorinated methacrylates: a class of versatile monomers for polymerization-induced self-assembly . Macromol. Rapid Commun. , 2018 . 39 1700840 DOI: 10.1002/marc.v39.7 http://doi.org/10.1002/marc.v39.7 .

Semsarilar, M.; Penfold, N.; Jones, E. R.; Armes, S. P . Semi-crystalline diblock copolymer nano-objects prepared via RAFT alcoholic dispersion polymerization of stearyl methacrylate . Polym. Chem. , 2015 . 6 1751 - 1757 . DOI: 10.1039/C4PY01664E http://doi.org/10.1039/C4PY01664E .

Boott, C. E.; Gwyther, J.; Harniman, R. L.; Hayward, D. W.; Manners, I . Scalable and uniform 1D nanoparticles by synchronous polymerization, crystallization and self-assembly . Nat. Chem. , 2017 . 9 785 - 792 . DOI: 10.1038/nchem.2721 http://doi.org/10.1038/nchem.2721 .

Zeng, M.; Huo, M.; Feng, Y.; Yuan, J . CO 2 -breathing polymer assemblies via one-pot sequential RAFT dispersion polymerization . Macromol. Rapid Commun. , 2018 . 39 1800291 DOI: 10.1002/marc.v39.15 http://doi.org/10.1002/marc.v39.15 .

Blanazs, A.; Verber, R.; Mykhaylyk, O. O.; Ryan, A. J.; Heath, J. Z.; Douglas, C. W. I.; Armes, S. P . Sterilizable gels from thermoresponsive block copolymer worms . J. Am. Chem. Soc. , 2012 . 134 9741 - 9748 . DOI: 10.1021/ja3024059 http://doi.org/10.1021/ja3024059 .

Yao, H.; Ning, Y.; Jesson, C. P.; He, J.; Deng, R.; Tian, W.; Armes, S. P . Using host-guest chemistry to tune the kinetics of morphological transitions undertaken by block copolymer vesicles . ACS Macro Lett. , 2017 . 6 1379 - 1385 . DOI: 10.1021/acsmacrolett.7b00836 http://doi.org/10.1021/acsmacrolett.7b00836 .

Deng, R.; Derry, M. J.; Mable, C. J.; Ning, Y.; Armes, S. P . Using dynamic covalent chemistry to drive morphological transitions: controlled release of encapsulated nanoparticles from block copolymer vesicles . J. Am. Chem. Soc. , 2017 . 139 7616 - 7623 . DOI: 10.1021/jacs.7b02642 http://doi.org/10.1021/jacs.7b02642 .

Canning, S. L.; Neal, T. J.; Armes, S. P . pH-responsive schizophrenic diblock copolymers prepared by polymerization-induced self-assembly . Macromolecules , 2017 . 50 6108 - 6116 . DOI: 10.1021/acs.macromol.7b01005 http://doi.org/10.1021/acs.macromol.7b01005 .

Penfold, N. J. W.; Lovett, J. R.; Warren, N. J.; Verstraete, P.; Smets, J.; Armes, S. P . pH-Responsive non-ionic diblock copolymers: protonation of a morpholine end-group induces an order-order transition . Polym. Chem. , 2016 . 7 79 - 88 . DOI: 10.1039/C5PY01510C http://doi.org/10.1039/C5PY01510C .

Wang, X.; Zhou, J.; Lv, X.; Zhang, B.; An, Z . Temperature-induced morphological transitions of poly(dimethylacrylamide)-poly(diacetone acrylamide) block copolymer lamellae synthesized via aqueous polymerization-induced self-assembly . Macromolecules , 2017 . 50 7222 - 7232 . DOI: 10.1021/acs.macromol.7b01644 http://doi.org/10.1021/acs.macromol.7b01644 .

Tan, J.; Zhang, X.; Liu, D.; Bai, Y.; Huang, C.; Li, X.; Zhang, L . Facile preparation of CO 2 -responsive polymer nano-objects via aqueous photoinitiated polymerization-induced self-assembly (photo-PISA) . Macromol. Rapid Commun. , 2017 . 38 1600508 DOI: 10.1002/marc.v38.13 http://doi.org/10.1002/marc.v38.13 .

Zhang, B.; Lv, X.; Zhu, A.; Zheng, J.; Yang, Y.; An, Z . Morphological stabilization of block copolymer worms using asymmetric cross-linkers during polymerization-induced self-assembly . Macromolecules , 2018 . 51 2776 - 2784 . DOI: 10.1021/acs.macromol.8b00246 http://doi.org/10.1021/acs.macromol.8b00246 .

Lv, F.; An, Z.; Wu, P . Scalable preparation of alternating block copolymer particles with inverse bicontinuous mesophases . Nat. Commun. , 2019 . 10 1397 DOI: 10.1038/s41467-019-09324-5 http://doi.org/10.1038/s41467-019-09324-5 .

Truong, N. P.; Dussert, M. V.; Whittaker, M. R.; Quinn, J. F.; Davis, T. P . Rapid synthesis of ultrahigh molecular weight and low polydispersity polystyrene diblock copolymers by RAFT-mediated emulsion polymerization . Polym. Chem. , 2015 . 6 3865 - 3874 . DOI: 10.1039/C5PY00166H http://doi.org/10.1039/C5PY00166H .

Perrier, S . 50 th Anniversary perspective: RAFT polymerization—a user guide . Macromolecules , 2017 . 50 7433 - 7447 . DOI: 10.1021/acs.macromol.7b00767 http://doi.org/10.1021/acs.macromol.7b00767 .

Cunningham, V. J.; Alswieleh, A. M.; Thompson, K. L.; Williams, M.; Leggett, G. J.; Armes, S. P.; Musa, O. M . Poly(glycerol monomethacrylate)-poly(benzyl methacrylate) diblock copolymer nanoparticles via RAFT emulsion polymerization: synthesis, characterization, and interfacial activity . Macromolecules , 2014 . 47 5613 - 5623 . DOI: 10.1021/ma501140h http://doi.org/10.1021/ma501140h .

Rieger, J.; Zhang, W.; Stoffelbach, F.; Charleux, B . Surfactant-free RAFT emulsion polymerization using poly( N , N -dimethylacrylamide) trithiocarbonate macromolecular chain transfer agents . Macromolecules , 2010 . 43 6302 - 6310 . DOI: 10.1021/ma1009269 http://doi.org/10.1021/ma1009269 .

Chaduc, I.; Girod, M.; Antoine, R.; Charleux, B.; D'Agosto, F.; Lansalot, M . Batch emulsion polymerization mediated by poly(methacrylic acid) macro-RAFT agents: one-pot synthesis of self-stabilized particles . Macromolecules , 2012 . 45 5881 - 5893 . DOI: 10.1021/ma300875y http://doi.org/10.1021/ma300875y .

Chaduc, I.; Crepet, A.; Boyron, O.; Charleux, B.; D'Agosto, F.; Lansalot, M . Effect of the pH on the RAFT polymerization of acrylic acid in water. Application to the synthesis of poly(acrylic acid)-stabilized polystyrene particles by RAFT emulsion polymerization . Macromolecules , 2013 . 46 6013 - 6023 . .

Song, Y. K.; Truong, N. P.; Quinn, J. F.; Whittaker, M. R.; Davis, T. P . Polymerization-induced self-assembly: the effect of end group and initiator concentration on morphology of nanoparticles prepared via RAFT aqueous emulsion polymerization . ACS Macro Lett. , 2017 . 6 1013 - 1019 . DOI: 10.1021/acsmacrolett.7b00583 http://doi.org/10.1021/acsmacrolett.7b00583 .

Lesage de la Haye, J.; Zhang, X.; Chaduc, I.; Brunel, F.; Lansalot, M.; D'Agosto, F . The effect of hydrophile topology in RAFT-mediated polymerization-induced self-assembly . Angew. Chem. Int. Ed. , 2016 . 55 3739 - 3743 . DOI: 10.1002/anie.201511159 http://doi.org/10.1002/anie.201511159 .

Boissé, S.; Rieger, J.; Belal, K.; Di-Cicco, A.; Beaunier, P.; Li, M. H.; Charleux, B . Amphiphilic block copolymer nano-fibers via RAFT-mediated polymerization in aqueous dispersed system . Chem. Commun. , 2010 . 46 1950 - 1952 . DOI: 10.1039/b923667h http://doi.org/10.1039/b923667h .

Cockram, A. A.; Neal, T. J.; Derry, M. J.; Mykhaylyk, O. O.; Williams, N. S.; Murray, M. W.; Emmett, S. N.; Armes, S. P . Effect of monomer solubility on the evolution of copolymer morphology during polymerization-induced self-assembly in aqueous solution . Macromolecules , 2017 . 50 796 - 802 . DOI: 10.1021/acs.macromol.6b02309 http://doi.org/10.1021/acs.macromol.6b02309 .

Tan, J.; Dai, X.; Zhang, Y.; Yu, L.; Sun, H.; Zhang, L . Photoinitiated polymerization-induced self-assembly via visible light-induced RAFT-mediated emulsion polymerization . ACS Macro Lett. , 2019 . 8 205 - 212 . DOI: 10.1021/acsmacrolett.9b00007 http://doi.org/10.1021/acsmacrolett.9b00007 .

Peng, C.; Joy, A . Baylis-Hillman reaction as a versatile platform for the synthesis of diverse functionalized polymers by chain and step polymerization . Macromolecules , 2014 . 47 1258 - 1268 . DOI: 10.1021/ma4025416 http://doi.org/10.1021/ma4025416 .

Basavaiah, D.; Rao, A. J.; Satyanarayana, T . Recent advances in the Baylis-Hillman reaction and applications . Chem. Rev. , 2003 . 103 811 - 892 . DOI: 10.1021/cr010043d http://doi.org/10.1021/cr010043d .

Thang, S. H.; Chong, Y. K.; Mayadunne, R. T. A.; Moad, G.; Rizzardo, E . A novel synthesis of functional dithioesters, dithiocarbamates, xanthates and trithiocarbonates . Tetrahedron Lett. , 1999 . 40 2435 - 2438 . DOI: 10.1016/S0040-4039(99)00177-X http://doi.org/10.1016/S0040-4039(99)00177-X .

Wang, X.; Figg, C. A.; Lv, X.; Yang, Y.; Sumerlin, B. S.; An, Z . Star architecture promoting morphological transitions during polymerization-induced self-assembly . ACS Macro Lett. , 2017 . 6 337 - 342 . DOI: 10.1021/acsmacrolett.7b00099 http://doi.org/10.1021/acsmacrolett.7b00099 .

Warren, N. J.; Mykhaylyk, O. O.; Mahmood, D.; Ryan, A. J.; Armes, S. P . RAFT aqueous dispersion polymerization yields poly(ethylene glycol)-based diblock copolymer nano-objects with predictable single phase morphologies . J. Am. Chem. Soc. , 2014 . 136 1023 - 1033 . DOI: 10.1021/ja410593n http://doi.org/10.1021/ja410593n .

Dormidontova, E. E . Role of competitive PEO-water and water-water hydrogen bonding in aqueous solution PEO behavior . Macromolecules , 2002 . 35 987 - 1001 . DOI: 10.1021/ma010804e http://doi.org/10.1021/ma010804e .

Yeow, J.; Boyer, C . Photoinitiated polymerization-induced self-assembly (photo-PISA): new insights and opportunities . Adv. Sci. , 2017 . 4 1700137 DOI: 10.1002/advs.v4.7 http://doi.org/10.1002/advs.v4.7 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Core Structure Modulation of 2D Nanosheets by Selective Crystallization-driven Self-assembly of Polyhedral Oligomeric Silsesquioxane-containing Block Copolymers

Thermoplastic Liquid Crystal Elastomers Based on ABA-type Triblock Copolymers

Hydrophobicity Regulated Coacervate Droplet Size and the Thermal Protection Against Denaturation of Enzyme

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

Advances in Polymer-based Circularly Polarized Luminescent Materials

Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly

Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly

DOI：10.1007/s10118-019-2303-3

摘要

Abstract

关键词

Keywords

references