Recent Progress on COS-derived Polymers

Cheng-Jian Zhang; Xing-Hong Zhang

doi:10.1007/s10118-019-2288-y

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Recent Progress on COS-derived Polymers

REVIEW | Updated：2021-02-18

- Recent Progress on COS-derived Polymers
- Recent Progress on COS-derived Polymers
- Chinese Journal of Polymer Science 2019年37卷第10期页码：951-958
- Affiliations：
  
  Key Laboratory of Macromolecular Synthesis and Functionalization (Ministry of Education), Department of Polymer Science & Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  xhzhang@zju.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 21774108) and the Distinguished Young Investigator Fund of Zhejiang Province (No. LR16B040001).
- DOI：10.1007/s10118-019-2288-y
  中图分类号：
- 收稿：2019-03-28，
  
  修回：2019-4-23，
  
  录用：2019-4-29，
  
  网络首发：2019-07-01，
  
  纸质出版：2019-10
- Accepted：
Scan QR Code
Zhang, C. J.; Zhang, X. H. Recent progress on COS-derived polymers. Chinese J. Polym. Sci. 2019, 37, 951–958.

Cheng-Jian Zhang, Xing-Hong Zhang. Recent Progress on COS-derived Polymers[J]. Chinese Journal of Polymer Science, 2019, 37(10): 951-958.
Zhang, C. J.; Zhang, X. H. Recent progress on COS-derived polymers. Chinese J. Polym. Sci. 2019, 37, 951–958. DOI： 10.1007/s10118-019-2288-y.

Cheng-Jian Zhang, Xing-Hong Zhang. Recent Progress on COS-derived Polymers[J]. Chinese Journal of Polymer Science, 2019, 37(10): 951-958. DOI： 10.1007/s10118-019-2288-y.

摘要

Abstract

The synthesis of sulfur-containing polymer

a very promising functional material

has made a great progress in the past several years. This review is focused on the very recent advances in poly(monothiocarbonate)s derived from carbonyl sulfide (COS) and epoxides including biomass-derived epoxides. Of significance

metal-free catalyst systems

including triethyl borane/Lewis base pair and thiourea/Lewis base pair are developed for the alternating copolymerization of COS with epoxides. Thereof

the thiourea/Lewis base pair is highly active to the copolymerization of COS with epoxide in a living manner. Moreover

a series of crystalline poly(monothiocarbonate)s are presented

including the copolymers derived from COS with oxetane

ethylene oxide

enantiopure epichlorohydrin

and achiral

meso

-epoxides

via

enantioselective copolymerization. Based on these COS/epoxide copolymerization process

a variety of COS-based block copolymers with well-defined structure are presented.

关键词

Keywords

references

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