a.College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
b.Analytical & Testing Center, Sichuan University, Chengdu 610064, China
c.State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
wangxj@scu.edu.cn (X.J.W.)
ppsf@scu.edu.cn (J.Y.)
收稿:2019-03-08,
修回:2019-4-18,
录用:2019-4-22,
网络首发:2019-06-04,
纸质出版:2019-12
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Liu, Z. Y.; Wei, Z. M.; Wang, X. J.; Zhang, G.; Long, S. R.; Yang, J. Preparation and characterization of multi-layer poly(arylene sulfide sulfone) nanofibers membranes for liquid filtration. Chinese J. Polym. Sci. 2019, 37, 1248–1256.
Zhen-Yan Liu, Zhi-Mei Wei, Xiao-Jun Wang, et al. Preparation and Characterization of Multi-layer Poly(arylene sulfide sulfone) Nanofibers Membranes for Liquid Filtration[J]. Chinese Journal of Polymer Science, 2019, 37(12): 1248-1256.
Liu, Z. Y.; Wei, Z. M.; Wang, X. J.; Zhang, G.; Long, S. R.; Yang, J. Preparation and characterization of multi-layer poly(arylene sulfide sulfone) nanofibers membranes for liquid filtration. Chinese J. Polym. Sci. 2019, 37, 1248–1256. DOI: 10.1007/s10118-019-2280-6.
Zhen-Yan Liu, Zhi-Mei Wei, Xiao-Jun Wang, et al. Preparation and Characterization of Multi-layer Poly(arylene sulfide sulfone) Nanofibers Membranes for Liquid Filtration[J]. Chinese Journal of Polymer Science, 2019, 37(12): 1248-1256. DOI: 10.1007/s10118-019-2280-6.
Owing to the excellent filtration performance and low energy cost
polymeric nanofibers microfiltration (MF) membranes have attracted increasing attentions. Poly(arylene sulfide sulfone) (PASS)
as one of the structurally modified polymers based on poly(phenylene sulfide) (PPS)
has been selected as the raw material to fabricate nanofibers MF membranes
via
electrospun techniques. The effects of PASS solution and the electrospinning processing parameters on the structural morphology of nanofibers were investigated in detail. The average diameter of PASS nanofibers was (296 ± 46) nm under the optimal condition: polymer concentration of 0.27 g·mL
–1
PASS/DMI
applied voltage of 20 kV
and speed of collector drum of 300 r·min
–1
. And then the multi-layer PASS nanofibers MF membranes were fabricated from cold-pressing the optimized PASS nanofibers (as-prepared PASS nanofibers) membrane. The morphology
porosity
pore size
mechanical properties
and surface wettability of the multi-layer PASS nanofibers MF membranes could be tuned by the layers of as-prepared nanofibers membrane. The results demonstrated that the membrane with 6 layers (marked as PASS-6) exhibited the smallest porosity
smallest pore size
highest mechanical property
and best surface wettability. Meanwhile
the multi-layer PASS nanofibers MF membranes showed that the rejection ratio gradually increased
while the pure water flux decreased with increasing membranes thickness. The PASS-6 membrane exhibited large water flux of 747.76 L·m
–2
·h
–1
and high separation efficiency of 99.9% to 0.2 μm particles
making it a promising candidate for microfilter.
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