Preparation of Three Dimensional Hydroxyapatite Nanoparticles/Poly(vinylidene fluoride) Blend Membranes with Excellent Dye Removal Efficiency and Investigation of Adsorption Mechanism

Jian-Hua Li; Hui Zheng; Hua-Xiang Lin; Bo-Xin Zhang; Jia-Bin Wang; Tong-Lei Li; Qi-Qing Zhang

doi:10.1007/s10118-019-2271-7

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Preparation of Three Dimensional Hydroxyapatite Nanoparticles/Poly(vinylidene fluoride) Blend Membranes with Excellent Dye Removal Efficiency and Investigation of Adsorption Mechanism

ARTICLE | Updated：2021-02-18

- Preparation of Three Dimensional Hydroxyapatite Nanoparticles/Poly(vinylidene fluoride) Blend Membranes with Excellent Dye Removal Efficiency and Investigation of Adsorption Mechanism
- Preparation of Three Dimensional Hydroxyapatite Nanoparticles/Poly(vinylidene fluoride) Blend Membranes with Excellent Dye Removal Efficiency and Investigation of Adsorption Mechanism
- Chinese Journal of Polymer Science 2019年37卷第12期页码：1234-1247
- Affiliations：
  
  a.Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou 350001, China
  b.State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou 350116, China
  c.Department of Industrial and Physical Pharmacy, Purdue University, 575 Stadium Mall Drive, West Lafayette, IN 47906, USA
- Author bio：
  
  jhli_2005@163.com
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51303028, 31771893, and 31401609) and the Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University (No. SKLPEE-KF201720).
- DOI：10.1007/s10118-019-2271-7
  中图分类号： M
- 收稿：2019-03-07，
  
  录用：2019-4-8，
  
  网络首发：2019-06-06，
  
  纸质出版：2019-12
- Accepted：
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Li, J. H.; Zheng, H.; Lin, H. X.; Zhang, B. X.; Wang, J. B.; Li, T. L.; Zhang, Q. Q. Preparation of three dimensional hydroxyapatite nanoparticles/poly(vinylidene fluoride) blend membranes with excellent dye removal efficiency and investigation of adsorption mechanism. Chinese J. Polym. Sci. 2019, 37, 1234–1247.

Jian-Hua Li, Hui Zheng, Hua-Xiang Lin, et al. Preparation of Three Dimensional Hydroxyapatite Nanoparticles/Poly(vinylidene fluoride) Blend Membranes with Excellent Dye Removal Efficiency and Investigation of Adsorption Mechanism[J]. Chinese Journal of Polymer Science, 2019, 37(12): 1234-1247.
Li, J. H.; Zheng, H.; Lin, H. X.; Zhang, B. X.; Wang, J. B.; Li, T. L.; Zhang, Q. Q. Preparation of three dimensional hydroxyapatite nanoparticles/poly(vinylidene fluoride) blend membranes with excellent dye removal efficiency and investigation of adsorption mechanism. Chinese J. Polym. Sci. 2019, 37, 1234–1247. DOI： 10.1007/s10118-019-2271-7.

Jian-Hua Li, Hui Zheng, Hua-Xiang Lin, et al. Preparation of Three Dimensional Hydroxyapatite Nanoparticles/Poly(vinylidene fluoride) Blend Membranes with Excellent Dye Removal Efficiency and Investigation of Adsorption Mechanism[J]. Chinese Journal of Polymer Science, 2019, 37(12): 1234-1247. DOI： 10.1007/s10118-019-2271-7.

摘要

Abstract

In this work

poly(vinylidene fluoride) (PVDF) membranes with hydrophilicity as well as preeminent mechanical strength and dye removal efficiency were fabricated by blending with three dimensional hydroxyapatite nanoparticles (HAPNPs). Surface chemical composition and morphology of the prepared membranes were systematically investigated by ATR-FTIR

XPS

XRD

FESEM

and EDS mapping analyses. The results verified that a large number of HAPNPs were successfully embedded on the modified membrane cross-sections. Moreover

HAPNPs content in the casting solution is an important factor that could have profound influence on the structures and performances of PVDF/HAPNPs blend membranes. The optimal membrane M2 with 2 wt% HAPNPs exhibited excellent hydrophilicity

outstanding mechanical strength of 19.60 MPa

and high water flux of (2466 ± 31) L·m

–2

·h

–1

. The maximum static adsorption capacity of the optimal membrane was about 10.83 mg/g

which is 3.75 times that of the pristine PVDF membrane (2.89 mg/g). PVDF/HAPNPs membranes were not only utilized for static adsorption

but also applied to dynamic dye removal. The possible adsorption mechanism between Congo red (CR) and HAPNPs embedded on the blend membranes was firstly discussed in this work. HAPNPs interacted with CR

via

Lewis reaction

hydrogen bond interaction

as well as electrostatic attraction to achieve the adsorption effect. Herein

the PVDF/HAPNPs blend membranes with extraordinary hydrophilicity

mechanical strength

and dye removal efficiency possess tremendous potential for practical applications of wastewater treatment.

关键词

Keywords

references

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