Synthesis of Cerium-containing Polymethylphenyl Silicone and Its Antioxidant Effect on Fluorosilicone Rubber

Yong Guan; Jian Hu; Yong-Kang Huang; Yang You; Huan-Yao Zhang; An-Na Zheng; Xiang Xu; Da-Fu Wei

doi:10.1007/s10118-019-2266-4

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Synthesis of Cerium-containing Polymethylphenyl Silicone and Its Antioxidant Effect on Fluorosilicone Rubber

ARTICLE | Updated：2021-02-18

- Synthesis of Cerium-containing Polymethylphenyl Silicone and Its Antioxidant Effect on Fluorosilicone Rubber
- Synthesis of Cerium-containing Polymethylphenyl Silicone and Its Antioxidant Effect on Fluorosilicone Rubber
- Chinese Journal of Polymer Science 2019年37卷第8期页码：783-789
- Affiliations：
  
  a.Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
  b.Key Laboratory for Specially Functional Polymeric Materials and Related Technology of the Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
- Author bio：
  
  xiangxu@ecust.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51573043 and 21805086) and the Fundamental Research Funds for the Central Universities (Nos. 222201817001 and 222201814004). This research was supported by the Shanghai Leading Academic Discipline Project (No. B502) and the Shanghai Key Laboratory Project (No. ZD20170203). Support from FSIR Advanced Material Co., Ltd. was also gratefully acknowledged.
- DOI：10.1007/s10118-019-2266-4
  中图分类号：
- 收稿：2019-01-04，
  
  修回：2019-3-14，
  
  录用：2019-3-30，
  
  网络首发：2019-05-10，
  
  纸质出版：2019-08
- Accepted：
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Citation: Guan, Y.; Hu, J.; Huang, Y. K.; You, Y.; Zhang, H. Y.; Zheng, A. N.; Xu, X.; Wei, D. F. Synthesis of cerium-containing polymethylphenyl silicone and its antioxidant effect on fluorosilicone rubber. Chinese J. Polym. Sci. 2019, 37, 783–789

Yong Guan, Jian Hu, Yong-Kang Huang, et al. Synthesis of Cerium-containing Polymethylphenyl Silicone and Its Antioxidant Effect on Fluorosilicone Rubber[J]. Chinese Journal of Polymer Science, 2019, 37(8): 783-789.
Citation: Guan, Y.; Hu, J.; Huang, Y. K.; You, Y.; Zhang, H. Y.; Zheng, A. N.; Xu, X.; Wei, D. F. Synthesis of cerium-containing polymethylphenyl silicone and its antioxidant effect on fluorosilicone rubber. Chinese J. Polym. Sci. 2019, 37, 783–789 DOI： 10.1007/s10118-019-2266-4.

Yong Guan, Jian Hu, Yong-Kang Huang, et al. Synthesis of Cerium-containing Polymethylphenyl Silicone and Its Antioxidant Effect on Fluorosilicone Rubber[J]. Chinese Journal of Polymer Science, 2019, 37(8): 783-789. DOI： 10.1007/s10118-019-2266-4.

摘要

Abstract

As an essential elastomer used in edge technologies

fluorosilicone rubber (FSR) suffers serious oxidative ageing problem when serving at high temperature. Cerium oxide is generally used as an antioxidant additive but remains unsatisfactory. In order to obtain better antioxidant effect on improving the thermal stability of FSR

a kind of cerium-containing polymethylphenyl silicone (PSI-Ce) was synthesized and the structure was verified by Fourier-transform infrared spectroscopy (FTIR) and proton nuclear magnetic resonance (

H-NMR). Due to the homogeneous dispersion on molecular scale

PSI-Ce imposed much better antioxidant effect than the commercial CeO

did

no matter from isothermal degradation at 320 °C or thermal-oxidative ageing test at 230 °C. In particular

after ageing for 72 h

FSR/PSI-Ce (2 phr) maintained 82% of tensile strength and 63% of elongation at break

in comparison to the corresponding values of 48% and 42% for FSR/CeO

(2 phr). Moreover

2 phr PSI-Ce was equivalent to 0.046 phr CeO

according to cerium element conservation.

关键词

Keywords

references

Zhang, X. K.; Poojari, Y.; Drechsler, L. E.; Kuo, C. M.; Fried, J. R.; Clarson, S. J . Pervaporation of organic liquids from binary aqueous mixtures using poly(trifluoropropylmethylsiloxane) and poly(dimethylsiloxane) dense membranes . J. Inorg. Organomet. Polym. Mater. , 2007 . 18 246 - 252 . .

Esmizadeh, E.; Naderi, G.; Barmar, M . Effect of organo-clay on properties and mechanical behavior of fluorosilicone rubber . Fibers Polym. , 2014 . 15 2376 - 2385 . DOI: 10.1007/s12221-014-2376-0 http://doi.org/10.1007/s12221-014-2376-0 .

Cypryk, M.; Delczyk, B.; Juhari, A.; Koynov, K . Controlled synthesis of trifluoropropylmethylsiloxane-dimethylsiloxane gradient copolymers by anionic ROP of cyclotrisiloxanes . J. Polym. Sci., Part A: Polym. Chem. , 2009 . 47 1204 - 1216 . DOI: 10.1002/pola.v47:4 http://doi.org/10.1002/pola.v47:4 .

Gao, Y.; Jiang, W.; Guan, Y.; Yang, P.; Zheng, A. N . A novel approach for anionic bulk polymerization of 1,3,5-tris(trifluoropropylmethyl)cyclotrisiloxane . Polym. Eng. Sci. , 2010 . 50 2440 - 2447 . DOI: 10.1002/pen.21690 http://doi.org/10.1002/pen.21690 .

Liu, Y.; Liu, H.; Zhang, R.; Zhou, C.; Feng, S . Preparation and properties of heat curable blended methylfluorosilicone rubber . Polym. Eng. Sci. , 2013 . 53 52 - 58 . DOI: 10.1002/pen.v53.1 http://doi.org/10.1002/pen.v53.1 .

Kahlig, H.; Zollner, P.; Mayer-Helm, B. X . Characterization of degradation products of poly[(3,3,3-trifluoropropyl)methylsiloxane] by nuclear magnetic resonance spectroscopy, mass spectrometry and gas chromatography . Polym. Degrad. Stab. , 2009 . 94 1254 - 1260 . DOI: 10.1016/j.polymdegradstab.2009.04.019 http://doi.org/10.1016/j.polymdegradstab.2009.04.019 .

Xu, X.; Xu, Z.; Chen, P.; Zhou, X.; Zheng, A. N; Guan, Y . Preparation of fluorosilicone random copolymers with properties superior to those of fluorosilicone/silicone polymer blends . J. Inorg. Organomet. Polym. Mater. , 2015 . 25 1267 - 1276 . DOI: 10.1007/s10904-015-0236-z http://doi.org/10.1007/s10904-015-0236-z .

Dai, Y.; Ruan, X.; Bai, F.; Yu, M.; Li, H.; Zhao, Z.; He, G . High solvent resistance PTFPMS/PEI hollow fiber composite membrane for gas separation . Appl. Surf. Sci. , 2016 . 360 164 - 173 . DOI: 10.1016/j.apsusc.2015.11.014 http://doi.org/10.1016/j.apsusc.2015.11.014 .

Bhuvaneswari, C. M.; Dhanasekaran, R.; Chakravarthy, S. K. R.; Kale, S. S.; Gouda, G . Evaluation of fluorosicone-silicone elastomer blend for aeronautical fuel system . Prog. Rubber Plast. Recycl. Technol. , 2015 . 31 207 - 218 . DOI: 10.1177/147776061503100305 http://doi.org/10.1177/147776061503100305 .

Smitha Alex, A.; Rajeev, R. S.; Krishnaraj, K.; Sreenivas, N.; Manu, S. K.; Gouri, C.; Sekkar, V . Thermal protection characteristics of polydimethylsiloxane-organoclay nanocomposite . Polym. Degrad. Stab. , 2017 . 144 281 - 291 . DOI: 10.1016/j.polymdegradstab.2017.08.026 http://doi.org/10.1016/j.polymdegradstab.2017.08.026 .

Camino, G.; Lomakin, S. M.; Lazzari, M . Polydimethylsiloxane thermal degradation. Part 1. Kinetic aspects . Polymer , 2001 . 42 2395 - 2402 . DOI: 10.1016/S0032-3861(00)00652-2 http://doi.org/10.1016/S0032-3861(00)00652-2 .

Camino, G.; Lomakin, S. M.; Lagerad, M . Thermal polydimethylsiloxane degradation. Part 2. The degradation mechanisms . Polymer , 2002 . 43 2011 - 2015 . DOI: 10.1016/S0032-3861(01)00785-6 http://doi.org/10.1016/S0032-3861(01)00785-6 .

Patel, M.; Skinner, A. R . Thermal ageing studies on room-temperture vulcanised polysiloxane rubbers . Polym. Degrad. Stab. , 2001 . 73 399 - 402 . DOI: 10.1016/S0141-3910(01)00118-5 http://doi.org/10.1016/S0141-3910(01)00118-5 .

Jovanovic, J. D.; Govedarica, M. N.; Dvornic, P. R.; Popovic, I. G . The thermogravimetric analysis of some polysiloxanes . Polym. Degrad. Stab. , 1998 . 61 87 - 93 . DOI: 10.1016/S0141-3910(97)00135-3 http://doi.org/10.1016/S0141-3910(97)00135-3 .

Zhang, S.; Wang, H . Thermal degradation of amino-group-modified polydimethylsiloxane . J. Therm. Anal. Calorim. , 2010 . 103 711 - 716 . .

Lewicki, J. P.; Liggat, J. J.; Patel, M . The thermal degradation behaviour of polydimethylsiloxane/montmorillonite nanocomposites . Polym. Degrad. Stab. , 2009 . 94 1548 - 1557 . DOI: 10.1016/j.polymdegradstab.2009.04.030 http://doi.org/10.1016/j.polymdegradstab.2009.04.030 .

Liu, Y. R.; Huang, Y. D.; Liu, L . Thermal stability of POSS/methylsilicone nanocomposites . Compos. Sci. Technol. , 2007 . 67 2864 - 2876 . DOI: 10.1016/j.compscitech.2007.01.023 http://doi.org/10.1016/j.compscitech.2007.01.023 .

Zheng, A. N.; Huang, Y.; You, Y.; Hu, J.; Wei, D.; Xu, X.; Guan, Y . Boron particles acting as antioxidants for fluorosilicone rubber due to their radical scavenging activity . Polym. Degrad. Stab. , 2018 . 158 168 - 175 . DOI: 10.1016/j.polymdegradstab.2018.09.017 http://doi.org/10.1016/j.polymdegradstab.2018.09.017 .

Guan, Y.; Yang, R.; Huang, Y.; Yu, C.; Li, X.; Wei, D.; Xu, X . Multi-walled carbon nanotubes acting as antioxidant for fluorosilicone rubber . Polym. Degrad. Stab. , 2018 . 156 161 - 169 . DOI: 10.1016/j.polymdegradstab.2018.06.018 http://doi.org/10.1016/j.polymdegradstab.2018.06.018 .

Xu, X.; Liu, J.; Chen, P.; Wei, D.; Guan, Y.; Lu, X.; Xiao, H . The effect of ceria nanoparticles on improving heat resistant properties of fluorosilicone rubber . J. Appl. Polym. Sci. , 2016 . 133 44117 .

Paul, D. R.; Mark, J. E . Fillers for polysiloxane (" silicone”) elastomers . Prog. Polym. Sci. , 2010 . 35 893 - 901 . DOI: 10.1016/j.progpolymsci.2010.03.004 http://doi.org/10.1016/j.progpolymsci.2010.03.004 .

Li, H.; Tao, S.; Huang, Y.; Su, Z.; Zheng, J . The improved thermal oxidative stability of silicone rubber by using iron oxide and carbon nanotubes as thermal resistant additives . Compos. Sci. Technol. , 2013 . 76 52 - 60 . DOI: 10.1016/j.compscitech.2012.12.019 http://doi.org/10.1016/j.compscitech.2012.12.019 .

Zhang, X.; Zhang, Q.; Zheng, J . Effect and mechanism of iron oxide modified carbon nanotubes on thermal oxidative stability of silicone rubber . Compos. Sci. Technol. , 2014 . 99 1 - 7 . DOI: 10.1016/j.compscitech.2014.05.003 http://doi.org/10.1016/j.compscitech.2014.05.003 .

Shentu, B. Q.; Gan, T. F.; Weng, Z. X . Modification of Fe 2 O 3 and its effect on the heat-resistance of silicone rubber . J. Appl. Polym. Sci. , 2009 . 113 3202 - 3206 . DOI: 10.1002/app.v113:5 http://doi.org/10.1002/app.v113:5 .

Gan, T. F.; Shentu, B. Q.; Weng, Z. X . Modification of CeO 2 and its effect on the heat-resistance of silicone rubber . Chinese J. Polym. Sci. , 2008 . 26 489 - 494 . DOI: 10.1142/S0256767908003163 http://doi.org/10.1142/S0256767908003163 .

Botter, W.; Ferreira Soares, R.; Galembeck, F . Interfacial reactions and self-adhesion of polydimethylsiloxanes . J. Adhes. Sci. Technol. , 1992 . 6 791 - 805 . DOI: 10.1163/156856192X00449 http://doi.org/10.1163/156856192X00449 .

Sim, L. C.; Ramanan, S. R.; Ismail, H.; Seetharamu, K. N.; Goh, T. J . Thermal characterization of Al 2 O 3 and ZnO reinforced silicone rubber as thermal pads for heat dissipation purposes . Thermochim. Acta , 2005 . 430 155 - 165 . DOI: 10.1016/j.tca.2004.12.024 http://doi.org/10.1016/j.tca.2004.12.024 .

Yao, Y. Y.; Lu, G. Q.; Boroyevich, D. S.; Ngo, K. D. T . Effect of Al 2 O 3 fibers on the high-temperature stability of silicone elastomer . Polymer , 2014 . 55 4232 - 4240 . DOI: 10.1016/j.polymer.2014.05.044 http://doi.org/10.1016/j.polymer.2014.05.044 .

Nielsen, J. M . Oxidative stabilization of dimethyl silicone fluids with iron between 70 and 370 °C . J. Polym. Sci., Polym. Symp. , 1973 . 40 189 - 197 . .

Baker, H. R.; Singleterry, C. R . Stabilization of silicone lubricating fluids above 200 °C by iron, copper, cerium, and other metal compounds . J. Chem. Eng. Data , 1961 . 6 146 - 154 . DOI: 10.1021/je60009a030 http://doi.org/10.1021/je60009a030 .

Han, W. Q.; Wu, L. J.; Zhu, Y. M . Formation and oxidation state of CeO 2- x nanotubes . J. Am. Chem. Soc. , 2005 . 127 12814 - 12815 . DOI: 10.1021/ja054533p http://doi.org/10.1021/ja054533p .

Belyavskii, S. G.; Mingalyov, P. G.; Giulieri, F.; Combarrieau, R.; Lisichkin, G. V . Chemical modification of the surface of a carbonyl iron powder . Prot. Met. , 2006 . 42 244 - 252 . DOI: 10.1134/S0033173206030064 http://doi.org/10.1134/S0033173206030064 .

Ikaev, A. M.; Mingalyov, P. G.; Lisichkin, G. V . Chemical modification of iron oxide surface with organosilicon and organophosphorous compounds . Colloid J. , 2007 . 69 741 - 746 . DOI: 10.1134/S1061933X07060105 http://doi.org/10.1134/S1061933X07060105 .

Pu, H. T.; Jiang, F. J.; Yang, Z. L . Studies on preparation and chemical stability of reduced iron particles encapsulated with polysiloxane nano-films . Mater. Lett. , 2006 . 60 94 - 97 . DOI: 10.1016/j.matlet.2005.07.079 http://doi.org/10.1016/j.matlet.2005.07.079 .

Huang, R. H.; Wang, L.; Lin, Y.; Dong, Y.; You, D . Surface modification of carbonyl iron powders with silicone polymers in supercritical fluid to get higher dispersibility and higher thermal stability . Surf. Interface Anal. , 2017 . 49 79 - 84 . DOI: 10.1002/sia.v49.2 http://doi.org/10.1002/sia.v49.2 .

Li, Y. M.; Zheng, Z. M.; Xu, C. L.; Ren, C.; Zhang, Z.; Xie, Z . Synthesis of iron-containing polysilazane and its antioxidation effect on silicone oil and rubber . J. Appl. Polym. Sci. , 2003 . 90 306 - 309 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

Cai, D.; Neyer, A.; Kuckuk, R.; Heise, H. M . Raman, mid-infrared, near-infrared and ultraviolet-visible spectroscopy of PDMS silicone rubber for characterization of polymer optical waveguide materials . J. Mol. Struct. , 2010 . 976 274 - 281 . DOI: 10.1016/j.molstruc.2010.03.054 http://doi.org/10.1016/j.molstruc.2010.03.054 .

Colthup, N. B.; Daly, L. H.; Wiberley, S. E. Introduction to infrared and Raman spectroscopy . Academic Press, San Diego, 1990 , p. 355.

Sopicka-Lizer, M.; Michalik, D.; Plewa, J.; Juestel, T.; Winkler, H.; Pawlik, T . The effect of Al―O substitution for Si―N on the luminescence properties of YAG:Ce phosphor . J. Eur. Ceram. Soc. , 2012 . 32 1383 - 1387 . DOI: 10.1016/j.jeurceramsoc.2011.04.021 http://doi.org/10.1016/j.jeurceramsoc.2011.04.021 .

Selvaraj, M.; Kim, B. H.; Lee, T. G . FTIR studies on selected mesoporous metallosilicate molecular sieves . Chem. Lett. , 2005 . 34 1290 - 1291 . DOI: 10.1246/cl.2005.1290 http://doi.org/10.1246/cl.2005.1290 .

Lin, S. L.; Hwang, C. S.; Lee, J. F . Characterization of CeO 2 -Al 2 O 3 -SiO 2 glasses by infrared and X-ray absorption near edge structure spectroscopies . J. Mater. Res. , 1996 . 11 2641 - 2650 . DOI: 10.1557/JMR.1996.0332 http://doi.org/10.1557/JMR.1996.0332 .

Park, S. H.; Kim, B. H.; Selvaraj, M.; Lee, T. G . Synthesis and characterization of mesoporous Ce-Mn-MCM-41 molecular sieves . J. Ind. Eng. Chem. , 2007 . 13 ( 4 ): 637 - 643 . .

Laha, S. C.; Mukherjee, P.; Sainkar, S. R.; Kumar, R . Cerium containing MCM-41-Type mesoporous materials and their acidic and redox catalytic properties . J. Catal. , 2002 . 207 213 - 223 . DOI: 10.1006/jcat.2002.3516 http://doi.org/10.1006/jcat.2002.3516 .

Radhakrishnan, T. S . New method for evaluation of kinetic parameters and mechanism of degradation from pyrolysis-GC studies: Thermal degradation of polydimethylsiloxanes . J. Appl. Polym. Sci. , 1999 . 73 441 - 450 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

Korsvik, C.; Patil, S.; Seal, S.; Self, W. T . Superoxide dismutase mimetic properties exhibited by vacancy engineered ceria nanoparticles . Chem. Commun. , 2007 . 1056 - 1058 . .

Tarnuzzer, R. W.; Colon, J.; Patil, S.; Seal, S . Vacancy engineered ceria nanostructures for protection from nanostructures for protection from radiation-induced cellular damage . Nano Lett. , 2005 . 5 2573 DOI: 10.1021/nl052024f http://doi.org/10.1021/nl052024f .

Xue, Y.; Luan, Q. F.; Yang, D.; Yao, X.; Zhou, K. B . Direct evidence for hydroxyl radical scavenging activity of cerium oxide nanoparticles . J. Phys. Chem. C , 2011 . 115 4433 - 4438 . DOI: 10.1021/jp109819u http://doi.org/10.1021/jp109819u .

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