Preparation and Properties of Ultrathin Flexible Expanded Graphite Film <italic style="font-style: italic">via</italic> Adding Natural Rubber

Yan-Ling Mo; Yu-Xin Tian; Yu-Hang Liu; Feng Chen; Qiang Fu

doi:10.1007/s10118-019-2264-6

Your Location：

Home >

Browse articles >

Preparation and Properties of Ultrathin Flexible Expanded Graphite Film via Adding Natural Rubber

ARTICLE | Updated：2021-02-18

- Preparation and Properties of Ultrathin Flexible Expanded Graphite Film via Adding Natural Rubber
- Preparation and Properties of Ultrathin Flexible Expanded Graphite Film via Adding Natural Rubber
- Chinese Journal of Polymer Science 2019年37卷第8期页码：806-814
- Affiliations：
  
  College of Polymer Science and Engineering, Sichuan University, State Key Laboratory of Polymer Materials Engineering, Chengdu 610065, China
- Author bio：
  
  fengchen@scu.edu.cn (F.C.)
  qiangfu@scu.edu.cn (Q.F.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51573102 and 51721091).
- DOI：10.1007/s10118-019-2264-6
  中图分类号：
- 收稿：2019-01-27，
  
  修回：2019-3-26，
  
  录用：2019-3-28，
  
  网络首发：2019-05-27，
  
  纸质出版：2019-08
- Accepted：
Scan QR Code
Mo, Y. L.; Tian, Y. X.; Liu, Y. H.; Chen, F.; Fu, Q. Preparation and properties of ultrathin flexible expanded graphite film via adding natural rubber. Chinese J. Polym. Sci. 2019, 37, 806–814.

Yan-Ling Mo, Yu-Xin Tian, Yu-Hang Liu, et al. Preparation and Properties of Ultrathin Flexible Expanded Graphite Film via Adding Natural Rubber[J]. Chinese Journal of Polymer Science, 2019, 37(8): 806-814. DOI: 10.1007/s10118-019-2264-6.
Mo, Y. L.; Tian, Y. X.; Liu, Y. H.; Chen, F.; Fu, Q. Preparation and properties of ultrathin flexible expanded graphite film via adding natural rubber. Chinese J. Polym. Sci. 2019, 37, 806–814. DOI： 10.1007/s10118-019-2264-6.

Yan-Ling Mo, Yu-Xin Tian, Yu-Hang Liu, et al. Preparation and Properties of Ultrathin Flexible Expanded Graphite Film via Adding Natural Rubber[J]. Chinese Journal of Polymer Science, 2019, 37(8): 806-814. DOI: 10.1007/s10118-019-2264-6. DOI：

摘要

Abstract

Expanded graphite (EG) films exhibit potential use in a wide field including thermal management

conductive applications

and electromagnetic interference (EMI) shielding. However

their poor tensile strength and brittleness are crucial deficiencies for commercial applications. To address these defects

in our work

natural rubber (NR) is employed to improve EG films for better mechanical strength and flexibility. The origin of the strengthening effect of EG films by the addition of natural rubber mainly arises from the formation of a simulate shell structure. Compared to the neat EG films

the addition of merely 2 wt% NR can give rise to superior ductility. Further

the loading of 10 wt% NR realizes a significant mechanical enhancement of the EG/NR films

i.e

2.4 and 11.4 times increase in tensile strength and elongation at break

respectively. Besides

EG/NR films containing 10 wt% NR can still sustain excellent thermal and electric conductivities of 173 W·m

−1

·K

−1

and 75 S·cm

−1

respectively. Furthermore

a very high EMI of 41.4 dB is achieved as the film thickness reaches 50 μm. Thus

the lightweight EG/NR films with comprehensive performance as well as their virtue of green and simple large-scale preparation endow them with the possibility of designing next-generation flexible electronics.

关键词

Keywords

references

Nika, D. L.; Balandin, A. A . Phonons and thermal transport in graphene and graphene-based materials . Rep. Prog. Phys. , 2017 . 80 036502 DOI: 10.1088/1361-6633/80/3/036502 http://doi.org/10.1088/1361-6633/80/3/036502 .

Balandin, A. A . Thermal properties of graphene and nanostructured carbon materials . Nat. Mater. , 2011 . 10 569 - 581 . DOI: 10.1038/nmat3064 http://doi.org/10.1038/nmat3064 .

Kumar, P.; Shahzad, F.; Yu, S.; Hong, S. M.; Kim, Y. H.; Koo, C. M . Large-area reduced graphene oxide thin film with excellent thermal conductivity and electromagnetic interference shielding effectiveness . Carbon , 2015 . 94 494 - 500 . DOI: 10.1016/j.carbon.2015.07.032 http://doi.org/10.1016/j.carbon.2015.07.032 .

Renteria, J. D.; Ramirez, S.; Malekpour, H.; Alonso, B.; Centeno, A.; Zurutuza, A.; Cocemasov, A. I.; Nika, D. L.; Balandin, A. A . Strongly anisotropic thermal conductivity of free-standing reduced graphene oxide films annealed at high temperature . Adv. Funct. Mater. , 2015 . 25 4664 - 4672 . DOI: 10.1002/adfm.201501429 http://doi.org/10.1002/adfm.201501429 .

Geim, A. K.; Novoselov, K. S . The rise of graphene . Nat. Mater. , 2007 . 6 183 - 191 . DOI: 10.1038/nmat1849 http://doi.org/10.1038/nmat1849 .

Wang, N.; Tian, H.; Zhu, S. Y.; Yan, D, Y.; Mai, Y. Y . Two-dimensional nitrogen-doped mesoporous carbon/graphene nanocomposites from the self-assembly of block copolymer micelles in solution . Chinese J. Polym. Sci. , 2018 . 36 266 - 272 . DOI: 10.1007/s10118-018-2091-1 http://doi.org/10.1007/s10118-018-2091-1 .

Ranjbartoreh, A. R.; Wang, B.; Shen, X.; Wang, G . Advanced mechanical properties of graphene paper . J. Appl. Phys. , 2011 . 109 014306 DOI: 10.1063/1.3528213 http://doi.org/10.1063/1.3528213 .

Chen, H.; Müller, M. B.; Gilmore, K. J.; Wallace, G. G.; Li, D . Mechanically strong, electrically conductive, and biocompatible graphene paper . Adv. Mater. , 2008 . 20 3557 - 3561 . DOI: 10.1002/adma.200800757 http://doi.org/10.1002/adma.200800757 .

Stankovich, S.; Dikin, D. A.; Dommett, G. H. B.; Kohlhaas, K. M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff, R. S . Graphene-based composite materials . Nature , 2006 . 442 282 - 286 . DOI: 10.1038/nature04969 http://doi.org/10.1038/nature04969 .

Furio, A.; Landi, G.; Altavilla, C.; Sofia, D.; Iannace, S.; Sorrentino, A.; Neitzert, H. C . Neitzert light irradiation tuning of surface wettability, optical, and electric properties of graphene oxide thin films . Nanotechnology , 2017 . 28 054003 .

Guo, H. L.; Wang, X. F.; Qian, Q. Y.; Wang, F. B.; Xia, X. H . A green approach to the synthesis of graphene nanosheets . ACS Nano , 2009 . 3 2653 - 2659 . DOI: 10.1021/nn900227d http://doi.org/10.1021/nn900227d .

Li, D.; Müller, M. B.; Gilje, S.; Kaner, R. B.; Wallace, G. G . Processable aqueous dispersions of graphene nanosheets . Nat. Nanotechnol. , 2008 . 3 101 - 105 . DOI: 10.1038/nnano.2007.451 http://doi.org/10.1038/nnano.2007.451 .

Shen, B.; Zhai, W.; Zheng, W . Ultrathin flexible graphene film: An excellent thermal conducting material with efficient EMI shielding . Adv. Funct. Mater. , 2014 . 24 4542 - 4548 . DOI: 10.1002/adfm.v24.28 http://doi.org/10.1002/adfm.v24.28 .

Liu, Z.; Li, Z.; Xu, Z.; Xia, Z.; Hu, X.; Kou, L.; Peng, L.; Wei, Y.; Gao, C . Wet-spun continuous graphene films . Chem. Mater. , 2014 . 26 6786 - 6795 . DOI: 10.1021/cm5033089 http://doi.org/10.1021/cm5033089 .

Lin, X.; Shen, X.; Zheng, Q.; Yousefi, N.; Ye, L.; Mai, Y. W.; Kim, J. K . Fabrication of highly-aligned, conductive, and strong graphene papers using ultralarge graphene oxide sheets . ACS Nano , 2012 . 6 10708 - 10719 . DOI: 10.1021/nn303904z http://doi.org/10.1021/nn303904z .

Teng, C.; Xie, D.; Wang, J.; Yang, Z.; Ren, G.; Zhu, Y . Ultrahigh conductive graphene paper based on ball-milling exfoliated graphene . Adv. Funct. Mater. , 2017 . 27 1700240 DOI: 10.1002/adfm.v27.20 http://doi.org/10.1002/adfm.v27.20 .

Ionov, S. G.; Avdeev, V. V.; Kuvshinnikov, S. V.; Pavlova, E. P . Physical and chemical properties of flexible graphite foils . Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A , 2000 . 340 349 - 354 . DOI: 10.1080/10587250008025491 http://doi.org/10.1080/10587250008025491 .

Lai, Q . Preparation of flexible graphite sheet with fine flake graphite . Adv. Mater. Res. , 2011 . 328-330 1642 - 1645 . DOI: 10.4028/www.scientific.net/AMR.328-330 http://doi.org/10.4028/www.scientific.net/AMR.328-330 .

Leng, Y.; Gu, J.; Cao, W.; Zhang, T. Y . Influences of density and flake size on the mechanical properties of flexible graphite . Carbon , 1998 . 36 875 - 881 . DOI: 10.1016/S0008-6223(97)00196-6 http://doi.org/10.1016/S0008-6223(97)00196-6 .

Reynolds, R. A.; Greinke, R. A . Influence of expansion volume of intercalated graphite on tensile properties of flexible graphite . Carbon , 2001 . 39 479 - 481 . DOI: 10.1016/S0008-6223(00)00291-8 http://doi.org/10.1016/S0008-6223(00)00291-8 .

Veca, L. M.; Meziani, M. J.; Wang, W.; Wang, X.; Lu, F.; Zhang, P.; Lin, Y.; Fee, R.; Connell, J. W.; Sun, Y. P . Carbon nanosheets for polymeric nanocomposites with high thermal conductivity . Adv. Mater. , 2009 . 21 2088 - 2092 . DOI: 10.1002/adma.v21:20 http://doi.org/10.1002/adma.v21:20 .

Wen, B.; Wang, X. X.; Cao, W. Q.; Shi, H. L.; Lu, M. M.; Wang, G.; Jin, H. B.; Wang, W. Z.; Yuan, J.; Cao, M. S . Reduced graphene oxides: The thinnest and most lightweight materials with highly efficient microwave attenuation performances of the carbon world . Nanoscale , 2014 . 6 5754 - 5761 . DOI: 10.1039/C3NR06717C http://doi.org/10.1039/C3NR06717C .

Wei, Y.; Huang, R.; Dong, P.; Qi, X. D.; Fu, Q . Preparation of polylactide/poly(ether)urethane blends with excellent electro-actuated shape memory via incorporating carbon black and carbon nanotubes hybrids fillers . Chinese J. Polym. Sci. , 2018 . 36 1175 - 1186 . DOI: 10.1007/s10118-018-2138-3 http://doi.org/10.1007/s10118-018-2138-3 .

Wei, Z. B.; Zhao, Y.; Wang, C.; Kuga, S.; Huang, Y.; Wu, M . Antistatic PVC-graphene composite through plasticizer-mediated exfoliation of graphite . Chinese J. Polym. Sci. , 2018 . 36 1361 - 1367 . DOI: 10.1007/s10118-018-2160-5 http://doi.org/10.1007/s10118-018-2160-5 .

Sun, C. B.; Mao, H. D.; Chen, F.; Fu, Q . Preparation of polylactide composite with excellent flame retardance and improved mechanical properties . Chinese J. Polym. Sci. , 2018 . 36 1385 - 1393 . DOI: 10.1007/s10118-018-2150-7 http://doi.org/10.1007/s10118-018-2150-7 .

Pu, S. Q.; Guo, S.; Wang, K.; Fu, Q . Largely improved stretch ductility and β -form room-temperature durability of poly(vinylidene fluoride) by incorporating aliphatic polyketone . Chinese J. Polym. Sci , 2018 . 36 1277 - 1285 . DOI: 10.1007/s10118-018-2134-7 http://doi.org/10.1007/s10118-018-2134-7 .

Zhu, G. L.; Han, D.; Yuan, Y.; Chen, F.; Fu, Q . Improving damping properties and thermal stability of epoxy/polyurethane grafted copolymer by adding glycidyl POSS . Chinese J. Polym. Sci. , 2018 . 36 1297 - 1302 . DOI: 10.1007/s10118-018-2145-4 http://doi.org/10.1007/s10118-018-2145-4 .

Cote Laura, J.; Kim, J.; Tung Vincent, C.; Luo, J.; Kim, F.; Huang, J . Graphene oxide as surfactant sheets . Pure Appl. Chem. , 2010 . 83 ( 1 ): 95 - 110 . DOI: 10.1351/PAC-CON-10-10-25 http://doi.org/10.1351/PAC-CON-10-10-25 .

Liu, Y. H.; Zeng, J.; Han, D.; Wu, K.; Yu, B. W.; Chai, S. G.; Chen, F.; Fu, Q . New insight of high temperature oxidation on self-exfoliation capability of graphene oxide . Nanotechnology , 2018 . 29 185601 DOI: 10.1088/1361-6528/aaaf3d http://doi.org/10.1088/1361-6528/aaaf3d .

Wen, B.; Cao, M.; Lu, M.; Cao, W.; Shi, H.; Liu, J.; Wang, X.; Jin, H.; Fang, X.; Wang, W.; Yuan, J . Reduced graphene oxides: Light-weight and high-efficiency electromagnetic interference shielding at elevated temperatures . Adv. Mater. , 2014 . 26 3484 - 3489 . DOI: 10.1002/adma.v26.21 http://doi.org/10.1002/adma.v26.21 .

Zeng, Z.; Chen, M.; Jin, H.; Li, W.; Xue, X.; Zhou, L.; Pei, Y.; Zhang, H.; Zhang, Z . Thin and flexible multi-walled carbon nanotube/waterborne polyurethane composites with high-performance electromagnetic interference shielding . Carbon , 2016 . 96 768 - 777 . DOI: 10.1016/j.carbon.2015.10.004 http://doi.org/10.1016/j.carbon.2015.10.004 .

Wu, H. Y.; Jia, L. C.; Yan, D. X.; Gao, J. F.; Zhang, X. P.; Ren, P. G.; Li, Z. M . Simultaneously improved electromagnetic interference shielding and mechanical performance of segregated carbon nanotube/polypropylene composite via solid phase molding . Compos. Sci. Technol. , 2018 . 156 87 - 94 . DOI: 10.1016/j.compscitech.2017.12.027 http://doi.org/10.1016/j.compscitech.2017.12.027 .

Thomassin, J. M.; Jerome, C.; Pardoen, T.; Bailly, C.; Huynen, I.; Detrembleur, C . Polymer/carbon based composites as electromagnetic interference (EMI) shielding materials . Mater. Sci. Eng. Rep. , 2013 . 74 211 - 232 . DOI: 10.1016/j.mser.2013.06.001 http://doi.org/10.1016/j.mser.2013.06.001 .

Bernal, M. M.; Di Pierro, A.; Novara, C.; Giorgis, F.; Mortazavi, B.; Saracco, G.; Fina, A . Edge-grafted molecular junctions between graphene nanoplatelets: Applied chemistry to enhance heat transfer in nanomaterials . Adv. Funct. Mater. , 2018 . 28 1706954 DOI: 10.1002/adfm.v28.18 http://doi.org/10.1002/adfm.v28.18 .

Zhang, Y.; Edwards, M.; Samani, M. K.; Logothetis, N.; Ye, L.; Fu, Y.; Jeppson, K.; Liu, J . Characterization and simulation of liquid phase exfoliated graphene-based films for heat spreading applications . Carbon , 2016 . 106 195 - 201 . DOI: 10.1016/j.carbon.2016.05.014 http://doi.org/10.1016/j.carbon.2016.05.014 .

Pei, S.; Cheng, H. M . The reduction of graphene oxide . Carbon , 2012 . 50 3210 - 3228 . DOI: 10.1016/j.carbon.2011.11.010 http://doi.org/10.1016/j.carbon.2011.11.010 .

Lotya, M.; Hernandez, Y.; King, P. J.; Smith, R. J.; Nicolosi, V.; Karlsson, L. S.; Blighe, F. M.; De, S.; Wang, Z.; McGovern, I. T.; Duesberg, G. S.; Coleman, J. N . Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions . J. Am. Chem. Soc. , 2009 . 131 3611 - 3620 . DOI: 10.1021/ja807449u http://doi.org/10.1021/ja807449u .

Yang, W. X.; Zhang, Y.; Liu, T. Y.; Huang, R.; Chai, S. G.; Chen, F.; Fu, Q . Completely green approach for the preparation of strong and highly conductive graphene composite film by using nanocellulose as dispersing agent and mechanical compression . ACS Sustain. Chem. Eng. , 2017 . 5 9102 - 9113 . DOI: 10.1021/acssuschemeng.7b02012 http://doi.org/10.1021/acssuschemeng.7b02012 .

Wu, H.; Drzal, L. T . Graphene nanoplatelet paper as a light-weight composite with excellent electrical and thermal conductivity and good gas barrier properties . Carbon , 2012 . 50 1135 - 1145 . DOI: 10.1016/j.carbon.2011.10.026 http://doi.org/10.1016/j.carbon.2011.10.026 .

Hamilton, C. E.; Lomeda, J. R.; Sun, Z.; Tour, J. M.; Barron, A. R . High-yield organic dispersions of unfunctionalized graphene . Nano Lett. , 2009 . 9 3460 - 3462 . DOI: 10.1021/nl9016623 http://doi.org/10.1021/nl9016623 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites

Revealing the Effect of Non-rubber Components of Natural Rubber on Its Radiation Resistance Performance

Optimizing Sulfur Vulcanization for Enhanced Mechanical Performance of Hevea Latex-Dipped Film: Insights from AFM PeakForce Quantitative Nanomechanical Mapping

Squaramide-directed Cooperative One-dimensional Assembly in Telechelic Polydimethylsiloxane for Hierarchical Network Formation

From Molecular Defect to Macroscopic Performance: Manipulating Dichroism and Mechanics in Iodine-doped Poly(vinyl alcohol) via Ethylene Incorporation

Preparation and Properties of Ultrathin Flexible Expanded Graphite Film via Adding Natural Rubber

Preparation and Properties of Ultrathin Flexible Expanded Graphite Film via Adding Natural Rubber

DOI：10.1007/s10118-019-2264-6

摘要

Abstract

关键词

Keywords

references