Synthesis of Conjugated Polymers Containing Diketopyrrolopyrrole (DPP) Building Block and the Photophysical Study

Ying-Zhong Wu; Yi-Chen Zhang; Jia-Jun Chen; Li-Juan Fan

doi:10.1007/s10118-019-2248-6

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Synthesis of Conjugated Polymers Containing Diketopyrrolopyrrole (DPP) Building Block and the Photophysical Study

ARTICLE | Updated：2021-02-18

- Synthesis of Conjugated Polymers Containing Diketopyrrolopyrrole (DPP) Building Block and the Photophysical Study
- Synthesis of Conjugated Polymers Containing Diketopyrrolopyrrole (DPP) Building Block and the Photophysical Study
- Chinese Journal of Polymer Science 2019年37卷第11期页码：1092-1098
- Affiliations：
  
  Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
- Author bio：
  
  ljfan@suda.edu.cn
- Funds：
  
  This work was financially supported by the Natural Science Foundation of Jiangsu Higher Education Institutions (No. 18KJA430014), the Natural Science Foundation of Jiangsu Province (No. BK20181441), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
- DOI：10.1007/s10118-019-2248-6
  中图分类号：
- 收稿：2019-02-15，
  
  修回：2019-2-28，
  
  录用：2019-3-1，
  
  网络首发：2019-04-01，
  
  纸质出版：2019-11
- Accepted：
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Wu, Y. Z.; Zhang, Y. C.; Chen, J. J.; Fan, L. J. Synthesis of conjugated polymers containing diketopyrrolopyrrole (DPP) building block and the photophysical study. Chinese J. Polym. Sci. 2019, 37, 1092–1098.

Ying-Zhong Wu, Yi-Chen Zhang, Jia-Jun Chen, et al. Synthesis of Conjugated Polymers Containing Diketopyrrolopyrrole (DPP) Building Block and the Photophysical Study[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1092-1098.
Wu, Y. Z.; Zhang, Y. C.; Chen, J. J.; Fan, L. J. Synthesis of conjugated polymers containing diketopyrrolopyrrole (DPP) building block and the photophysical study. Chinese J. Polym. Sci. 2019, 37, 1092–1098. DOI： 10.1007/s10118-019-2248-6.

Ying-Zhong Wu, Yi-Chen Zhang, Jia-Jun Chen, et al. Synthesis of Conjugated Polymers Containing Diketopyrrolopyrrole (DPP) Building Block and the Photophysical Study[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1092-1098. DOI： 10.1007/s10118-019-2248-6.

摘要

Abstract

Sonogashira coupling of two different diketopyrrolopyrrole (DPP)-containing dihaloarenes with the same aromatic bisalkyne resulted in two new conjugated polymers with the same backbone but different pendant groups on the DPP moiety. The polymers were found to have designed chemical structures

via

structural characterizations in comparison with three monomers. The molecular weight measurement further demonstrated the formation of polymers with polydispersity index around 2

consistent with the polycondensation nature of the polymerization based on Sonogashira coupling. Both polymers could dissolve in many organic solvents

and the one with long alkyl side group on DPP moiety had better solubility. Photophysical investigation showed that both polymers had typical absorption/emission of conjugated polymers

and varying the solvent did not have large influence. Compared with other polar solvents

toluene reduced the quantum yield of fluorescence of the polymers

especially for the one with long alkyl pedant group

accompanying with slight red-shift in absorption/emission. The difference in the absorption/emission wavelengths between the polymers was similar to that between the corresponding monomers. Adding water into the THF solution of polymers reduced the emission intensity but no red-shift was observed. Discussion about the structure-property relationships was carried out in detail.

关键词

Keywords

references

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