Self-healing Behavior of Ethylene Propylene Diene Rubbers Based on Ionic Association

Zhi-Fei Zhang; Kun Yang; Shu-Gao Zhao; Lai-Na Guo

doi:10.1007/s10118-019-2241-0

Your Location：

Home >

Browse articles >

Self-healing Behavior of Ethylene Propylene Diene Rubbers Based on Ionic Association

ARTICLE | Updated：2021-02-18

- Self-healing Behavior of Ethylene Propylene Diene Rubbers Based on Ionic Association
- Self-healing Behavior of Ethylene Propylene Diene Rubbers Based on Ionic Association
- Chinese Journal of Polymer Science 2019年37卷第7期页码：700-707
- Affiliations：
  
  a.Key Laboratory of Rubber-plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-Plastics, Qingdao University of Science & Technology, Qingdao 266042, China
  b.College of Chemical Engineering and Materials Science, Tianjin University of Science & Technology, Tianjin 300457, China
  c.Hutchinson, research center, Rue Gustave Nourry, Chalette sur Loing, 45120, France
- Author bio：
  
  yangkun1463@126.com (K.Y.)
  zhaosgqd@hotmail.com (S.G.Z.)
- Funds：
  
  This work was financially supported by the National Basic Research Program of China (Nos. 2015CB654700 and 2015CB654706), the National Natural Science Foundation of China (No. 51403115), and the Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-plastics of Qingdao University of Science & Technology (KF2017008). We are also grateful for the support from Hutchinson.
- DOI：10.1007/s10118-019-2241-0
  中图分类号：
- 收稿：2018-12-25，
  
  修回：2019-2-19，
  
  录用：2019-2-21，
  
  网络首发：2019-04-04，
  
  纸质出版：2019-07
- Accepted：
Scan QR Code
Citation: Zhang, Z. F.; Yang, K.; Zhao, S. G.; Guo, L. N. Self-healing behavior of ethylene propylene diene rubbers based on ionic association. Chinese J. Polym. Sci. 2019, 37, 700–707

Zhi-Fei Zhang, Kun Yang, Shu-Gao Zhao, et al. Self-healing Behavior of Ethylene Propylene Diene Rubbers Based on Ionic Association[J]. Chinese Journal of Polymer Science, 2019, 37(7): 700-707.
Citation: Zhang, Z. F.; Yang, K.; Zhao, S. G.; Guo, L. N. Self-healing behavior of ethylene propylene diene rubbers based on ionic association. Chinese J. Polym. Sci. 2019, 37, 700–707 DOI： 10.1007/s10118-019-2241-0.

Zhi-Fei Zhang, Kun Yang, Shu-Gao Zhao, et al. Self-healing Behavior of Ethylene Propylene Diene Rubbers Based on Ionic Association[J]. Chinese Journal of Polymer Science, 2019, 37(7): 700-707. DOI： 10.1007/s10118-019-2241-0.

摘要

Abstract

To meet the increasing demand for safe

environmentally friendly and high-performance smart materials

self-healing rubbers are highly desired. Here

the self-healing performance of ethylene propylene diene monomer rubber (EPDM) is reported

which was designed by graft-polymerization of zinc dimethacrylate (ZDMA) onto rubber chains to form a reversible ionic cross-linked network. Single ionic cross-linked network and dual network

combining covalent and ionic cross-links

could be tuned by controlling vulcanization process to achieve tailorable mechanical and self-healing properties. It was found that ionic cross-linked EPDM showed a recovery of more than 95% of the original mechanical strength through a healing process of 1 h at 100 °C. The covalent cross-links could improve mechanical properties but block self-healing. Adding 50 wt% liquid rubber to " dry” EPDM could effectively enhance self-healing capability of the dual cross-linked network and the healed tensile strength could reach 0.9 MPa. A compromise between mechanical performance and healing capability could be potentially tailored by controlling vulcanization process and liquid rubber content.

关键词

Keywords

references

Vélez, J. S.; Velásquez, S.; Giraldo, D . Mechanical and rheometric properties of gilsonite/carbon black/natural rubber compounds cured using conventional and efficient vulcanization systems . Polym. Test. , 2016 . 56 1 - 9 . DOI: 10.1016/j.polymertesting.2016.09.005 http://doi.org/10.1016/j.polymertesting.2016.09.005 .

Hosseini, S. M.; Razzaghi-Kashani, M . On the role of nano-silica in the kinetics of peroxide vulcanization of ethylene propylene diene rubber . Polymer , 2017 . 133 8 - 19 . DOI: 10.1016/j.polymer.2017.10.061 http://doi.org/10.1016/j.polymer.2017.10.061 .

Movahed, S. O.; Ansarifar, A.; Zohuri, G.; Ghaneie, N.; Kermany, Y . Devulcanization of ethylene-propylene-diene waste rubber by microwaves and chemical agents . J. Elastomer Plast. , 2014 . 48 ( 2 ): 122 - 144 . .

Yu, B. C.; Jung, J. W.; Park, K.; Goodenough, J. B . A new approach for recycling waste rubber products in Li-S batteries . Energ. Environ. Sci. , 2017 . 10 ( 1 ): 86 - 90 . DOI: 10.1039/C6EE02770A http://doi.org/10.1039/C6EE02770A .

Molanorouzi, M.; Mohaved, S. O . Reclaiming waste tire rubber by an irradiation technique . Polym. Degrad. Stab. , 2016 . 128 ( C ): 115 - 125 . .

Keller, M. W.; White, S. R.; Sottos, N. R . A self-healing poly(dimethyl siloxane) elastomer . Adv. Funct. Mater. , 2007 . 17 ( 14 ): 2399 - 2404 . DOI: 10.1002/(ISSN)1616-3028 http://doi.org/10.1002/(ISSN)1616-3028 .

Chowdhury, R. A.; Hosur, M. V.; Nuruddin, M.; Tcherbi-Narteh, A.; Kumar, A.; Boddu, V.; Jeelani, S . Self-healing epoxy composites: Preparation, characterization and healing performance . J. Mater. Res. Technol. , 2015 . 4 ( 1 ): 33 - 43 . DOI: 10.1016/j.jmrt.2014.10.016 http://doi.org/10.1016/j.jmrt.2014.10.016 .

Pepels, M.; Filot, I.; Klumperman, B.; Goossens, H . Self-healing systems based on disulfide-thiol exchange reactions . Polym. Chem. , 2013 . 4 ( 18 ): 4955 - 11 . DOI: 10.1039/c3py00087g http://doi.org/10.1039/c3py00087g .

Guo, Y. K.; Li, H.; Zhao, P. X.; Wang, X. F.; Astruc, D.; Shuai, M. B . Thermo-reversible MWCNTs/epoxy polymer for use in self-healing and recyclable epoxy adhesive . Chinese J. Polym. Sci. , 2017 . 35 ( 6 ): 728 - 738 . DOI: 10.1007/s10118-017-1920-y http://doi.org/10.1007/s10118-017-1920-y .

Kang, J.; Son, D.; Wang, G. J. N.; Liu, Y.; Lopez, J.; Kim, Y.; Oh, J. Y.; Katsumata, T.; Mun, J.; Lee, Y.; Jin, L.; Tok, J. B. H.; Bao, Z . Tough and water-insensitive self-healing elastomer for robust electronic skin . Adv. Mater. , 2018 . 15 1706846 .

Liu, X.; Lu, C.; Wu, X.; Zhang, X . Self-healing strain sensors based on nanostructured supramolecular conductive elastomers . J. Mater. Chem. A , 2017 . 5 ( 20 ): 9824 - 9832 . DOI: 10.1039/C7TA02416A http://doi.org/10.1039/C7TA02416A .

Luan, Y. G.; Zhang, X. A.; Jiang, S. L.; Chen, J. H.; Lyu, Y. F . Self-healing supramolecular polymer composites by hydrogen bonding interactions between hyperbranched polymer and graphene oxide . Chinese J. Polym. Sci. , 2018 . 36 ( 5 ): 584 - 591 . DOI: 10.1007/s10118-018-2025-y http://doi.org/10.1007/s10118-018-2025-y .

Liu, J.; Liu, J.; Wang, S.; Huang, J.; Wu, S.; Tang, Z.; Guo, B.; Zhang, L . An advanced elastomer with an unprecedented combination of excellent mechanical properties and high self-healing capability . J. Mater. Chem. A , 2017 . 5 ( 48 ): 25660 - 25671 . DOI: 10.1039/C7TA08255J http://doi.org/10.1039/C7TA08255J .

Jia, X. Y.; Mei, J. F.; Lai, J. C.; Li, C. H.; You, X. Z . A highly stretchable polymer that can be thermally healed at mild temperature . Macromol. Rapid Commun. , 2016 . 37 ( 12 ): 952 - 956 . DOI: 10.1002/marc.v37.12 http://doi.org/10.1002/marc.v37.12 .

Rahman, M. A.; Penco, M.; Peroni, I.; Ramorino, G.; Grande, A. M.; Di Landro, L . Self-repairing systems based on ionomers and epoxidized natural rubber blends . ACS Appl. Mater. Interfaces , 2011 . 3 ( 12 ): 4865 - 4874 . DOI: 10.1021/am201417h http://doi.org/10.1021/am201417h .

García-Huete, N.; Post, W.; Laza, J. M.; Vilas, J. L.; León, L. M.; García, S. J . Effect of the blend ratio on the shape memory and self-healing behaviour of ionomer-polycyclooctene cross-linked polymer blends . Eur. Polym. J. , 2018 . 98 154 - 161 . DOI: 10.1016/j.eurpolymj.2017.11.006 http://doi.org/10.1016/j.eurpolymj.2017.11.006 .

Das, A.; Sallat, A.; Böhme, F.; Suckow, M.; Basu, D.; Wießner, S.; Stöckelhuber, K. W.; Voit, B.; Heinrich, G . Ionic modification turns commercial rubber into a self-healing material . ACS Appl. Mater. Interfaces , 2015 . 7 ( 37 ): 20623 - 20630 . DOI: 10.1021/acsami.5b05041 http://doi.org/10.1021/acsami.5b05041 .

Li, C. H.; Wang, C.; Keplinger, C.; Zuo, J. L.; Jin, L.; Sun, Y.; Zheng, P.; Cao, Y.; Lissel, F.; Linder, C.; You, X. Z.; Bao, Z . A highly stretchable autonomous self-healing elastomer . Nat. Chem. , 2016 . 8 ( 6 ): 618 - 624 . DOI: 10.1038/nchem.2492 http://doi.org/10.1038/nchem.2492 .

Chen, Y.; Kushner, A. M.; Williams, G. A.; Guan, Z . Multiphase design of autonomic self-healing thermoplastic elastomers . Nat. Chem. , 2012 . 4 ( 6 ): 467 - 472 . DOI: 10.1038/nchem.1314 http://doi.org/10.1038/nchem.1314 .

Kalista, S. J., Jr.; Ward, T. C.; Oyetunji, Z . Self-healing of poly(ethylene- co -methacrylic acid) copolymers following projectile puncture . Mech. Adv. Mater. Struc. , 2007 . 14 ( 5 ): 391 - 397 . DOI: 10.1080/15376490701298819 http://doi.org/10.1080/15376490701298819 .

Zhong, M.; Liu, Y. T.; Xie, X. M . Self-healable, super tough graphene oxide-poly(acrylic acid) nanocomposite hydrogels facilitated by dual cross-linking effects through dynamic ionic interactions . J. Mater. Chem. B , 2015 . 3 ( 19 ): 4001 - 4008 . DOI: 10.1039/C5TB00075K http://doi.org/10.1039/C5TB00075K .

Xu, C.; Cao, L.; Lin, B.; Liang, X.; Chen, Y . Design of self-healing supramolecular rubbers by introducing ionic cross-links into natural rubber via a controlled vulcanization . ACS Appl. Mater. Interfaces , 2016 . 8 ( 27 ): 17728 - 17737 . DOI: 10.1021/acsami.6b05941 http://doi.org/10.1021/acsami.6b05941 .

Zhang, J.; Huo, M.; Li, M.; Li, T.; Li, N.; Zhou, J.; Jiang, J . Shape memory and self-healing materials from supramolecular block polymers . Polymer , 2018 . 134 35 - 43 . DOI: 10.1016/j.polymer.2017.11.043 http://doi.org/10.1016/j.polymer.2017.11.043 .

Miwa, Y.; Kurachi, J.; Kohbara, Y.; Kutsumizu, S . Dynamic ionic cross-links enable high strength and ultrastretchability in a single elastomer . Commun. Chem. , 2018 . 1 5 .

Peng, Z.; Liang, X.; Zhang, Y.; Zhang, Y . Reinforcement of EPDM by in situ prepared zinc dimethacrylate . J. Appl. Polym. Sci. , 2002 . 84 ( 7 ): 1339 - 1345 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

Nie, Y.; Huang, G.; Qu, L.; Zhang, P.; Weng, G.; Wu, J . Cure kinetics and morphology of natural rubber reinforced by the in situ polymerization of zinc dimethacrylate . J. Appl. Polym. Sci. , 2010 . 115 ( 1 ): 99 - 106 . DOI: 10.1002/app.v115:1 http://doi.org/10.1002/app.v115:1 .

Chen, Y.; Xu, C . Cross-link network evolution of nature rubber/zinc dimethacrylate composite during peroxide vulcanization . Polym. Compos. , 2011 . 32 ( 10 ): 1505 - 1514 . DOI: 10.1002/pc.v32.10 http://doi.org/10.1002/pc.v32.10 .

Xu, C.; Huang, X.; Li, C.; Chen, Y.; Lin, B.; Liang, X . Design of " Zn 2+ salt-bondings” cross-linked carboxylated styrene butadiene rubber with reprocessing and recycling ability via rearrangements of ionic cross-linkings . ACS Sustain. Chem. Eng. , 2016 . 4 ( 12 ): 6981 - 6990 . DOI: 10.1021/acssuschemeng.6b01897 http://doi.org/10.1021/acssuschemeng.6b01897 .

Xu, C.; Cao, L.; Huang, X.; Chen, Y.; Lin, B.; Fu, L . Self-healing natural rubber with tailorable mechanical properties based on ionic supramolecular hybrid network . ACS Appl. Mater. Interfaces , 2017 . 9 ( 34 ): 29363 - 29373 . DOI: 10.1021/acsami.7b09997 http://doi.org/10.1021/acsami.7b09997 .

Wang, D.; Guo, J.; Zhang, H.; Cheng, B.; Shen, H.; Zhao, N.; Xu, J . Intelligent rubber with tailored properties for self-healing and shape memory . J. Mater. Chem. A , 2015 . 3 12864 - 12872 . DOI: 10.1039/C5TA01915J http://doi.org/10.1039/C5TA01915J .

Cao, L.; Huang, J.; Chen, Y . Dual cross-linked epoxidized natural rubber reinforced by tunicate cellulose nanocrystals with improved strength and extensibility . ACS Sustain. Chem. Eng. , 2018 . 6 ( 11 ): 14802 - 14811 . DOI: 10.1021/acssuschemeng.8b03331 http://doi.org/10.1021/acssuschemeng.8b03331 .

Xu, C.; Cui, R.; Fu, L.; Lin, B . Recyclable and heat-healable epoxidized natural rubber/bentonite composites . Compos. Sci. Technol. , 2018 . 167 421 - 430 . DOI: 10.1016/j.compscitech.2018.08.027 http://doi.org/10.1016/j.compscitech.2018.08.027 .

Flory, P. J . Statistical mechanics of swelling of network structures . J. Chem. Phys. , 1950 . 18 ( 1 ): 108 - 111 . DOI: 10.1063/1.1747424 http://doi.org/10.1063/1.1747424 .

Bala, P.; Samantaray, B. K.; Srivastava, S. K.; Nando, G. B . Organomodified montmorillonite as filler in natural and synthetic rubber . J. Appl. Polym. Sci. , 2004 . 92 ( 6 ): 3583 - 3592 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

Liu, X. Y.; Zhong, M.; Shi, F. K.; Xu, H.; Xie, X. M . Multi-bond network hydrogels with robust mechanical and self-healable properties . Chinese J. Polym. Sci. , 2017 . 35 ( 10 ): 1253 - 1267 . DOI: 10.1007/s10118-017-1971-0 http://doi.org/10.1007/s10118-017-1971-0 .

Yarmohammadi, M.; Shahidzadeh, M.; Ramezanzadeh, B . Designing an elastomeric polyurethane coating with enhanced mechanical and self-healing properties- the influence of disulfide chain extender . Prog. Org. Coat. , 2018 . 121 45 - 52 . DOI: 10.1016/j.porgcoat.2018.04.009 http://doi.org/10.1016/j.porgcoat.2018.04.009 .

Wool, R. P.; O’Connor, K. M . A theory crack healing in polymers . J. Appl. Phys. , 1981 . 52 ( 10 ): 5953 - 5963 . DOI: 10.1063/1.328526 http://doi.org/10.1063/1.328526 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Interplay between Microscopic Structures and Macroscopic Viscoelastic Properties of Polyampholyte Gels

Multifunctional Polyurethane with High Strength, Toughness, and Self-healing Capacity via Tannic Acid-modified Cellulose Nanocrystals

Soft-segment-engineered Self-healing Polyurethane for High-performance Electrorheological Elastomers and Capacitive Sensors

Molecular Engineering of Fluorine-containing Polyurethane Adhesives: Toughness and Self-healing Enhancement via Synergistic Disulfide-Zr4+ Coordination Bonds

pH-Responsive L-Cysteine-conjugated Polydopamine Nanocarriers for Controlled Release of Emamectin Benzoate against Pieris brassicae