Diffusion Mode Transition between Gaussian and Non-Gaussian of Nanoparticles in Polymer Solutions

Yi Ye; Han Qin; Ming Tian; Jian-Guo Mi

doi:10.1007/s10118-019-2237-9

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Diffusion Mode Transition between Gaussian and Non-Gaussian of Nanoparticles in Polymer Solutions

ARTICLE | Updated：2021-02-18

- Diffusion Mode Transition between Gaussian and Non-Gaussian of Nanoparticles in Polymer Solutions
- Diffusion Mode Transition between Gaussian and Non-Gaussian of Nanoparticles in Polymer Solutions
- Chinese Journal of Polymer Science 2019年37卷第7期页码：719-728
- Affiliations：
  
  a.State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
  b.Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  tianm@mail.buct.edu.cn (M.T.)
  mijg@mail.buct.edu.cn (J.G.M.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51790502 and 51525301), the National Supercomputer Centre in Guangzhou, and Chemcloudcomputing of Beijing University of Chemical Technology.
- DOI：10.1007/s10118-019-2237-9
  中图分类号：
- 收稿：2018-12-24，
  
  修回：2019-1-27，
  
  录用：2019-1-31，
  
  网络首发：2019-03-12，
  
  纸质出版：2019-07
- Accepted：
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Citation: Ye, Y.; Qin, H.; Tian, M.; Mi, J. G. Diffusion mode transition between Gaussian and non-Gaussian of nanoparticles in polymer solutions. Chinese J. Polym. Sci. 2019, 37, 719–728

Yi Ye, Han Qin, Ming Tian, et al. Diffusion Mode Transition between Gaussian and Non-Gaussian of Nanoparticles in Polymer Solutions[J]. Chinese Journal of Polymer Science, 2019, 37(7): 719-728.
Citation: Ye, Y.; Qin, H.; Tian, M.; Mi, J. G. Diffusion mode transition between Gaussian and non-Gaussian of nanoparticles in polymer solutions. Chinese J. Polym. Sci. 2019, 37, 719–728 DOI： 10.1007/s10118-019-2237-9.

Yi Ye, Han Qin, Ming Tian, et al. Diffusion Mode Transition between Gaussian and Non-Gaussian of Nanoparticles in Polymer Solutions[J]. Chinese Journal of Polymer Science, 2019, 37(7): 719-728. DOI： 10.1007/s10118-019-2237-9.

摘要

Abstract

The dynamic density functional theory is applied to study the diffusion of nanoparticles in polymer solutions

in which different diffusion modes have been identified by exploiting the density and free energy evolutions. Under the condition of low polymer concentration

diffusion is controlled by particle free motion with a normal Gaussian type. As the concentration increases

the non-Gaussian behavior can be observed when the particle size is comparable to the correlation length of polymer chain. Particles need to penetrate through a cage and overcome an entropic barrier

where the hopping and the model-coupling diffusion coexist. Further increase of polymer concentration can result in complete restriction of the particle by surrounding polymer segments. In this case

the non-Gaussian process fades away

and particle diffusion is controlled by Rouse dynamics of polymer chains with the generalized Gaussian characteristics.

关键词

Keywords

references

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