a.Center for Advanced Low-dimension Materials, State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China
b.Key Laboratory of Polymer Chemistry & Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
shgyang@dhu.edu.cn
收稿:2018-11-25,
修回:2019-1-17,
录用:2019-1-25,
网络首发:2019-03-07,
纸质出版:2019-06
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Citation: Ou, K.; Xu, X.; Shao, Y.; Wang, W. J.; Zhang, W. B.; Yang, S. G. Langmuir-Blodgett films of C60-end-capped poly(ethylene oxide). Chinese J. Polym. Sci. 2019, 37, 604–608 DOI: 10.1007/s10118-019-2234-z.
Ke Ou, Xian Xu, Yu Shao, et al. Langmuir-Blodgett Films of C60-end-capped Poly(ethylene oxide)[J]. Chinese Journal of Polymer Science, 2019, 37(6): 604-608. DOI: 10.1007/s10118-019-2234-z.
Citation: Ou, K.; Xu, X.; Shao, Y.; Wang, W. J.; Zhang, W. B.; Yang, S. G. Langmuir-Blodgett films of C60-end-capped poly(ethylene oxide). Chinese J. Polym. Sci. 2019, 37, 604–608 DOI: 10.1007/s10118-019-2234-z. DOI:
Ke Ou, Xian Xu, Yu Shao, et al. Langmuir-Blodgett Films of C60-end-capped Poly(ethylene oxide)[J]. Chinese Journal of Polymer Science, 2019, 37(6): 604-608. DOI: 10.1007/s10118-019-2234-z. DOI:
Buckyballs (C
60
) are linked to one end and two ends of linear poly(ethylene oxide) (PEO) chains through highly efficient click chemistry to obtain giant amphiphilic molecules C
60
-PEO and C
60
-PEO-C
60
respectively. C
60
-PEO and C
60
-PEO-C
60
molecules are spread on water surface and then transferred to solid substrates with Langmuir-Blodgett (LB) film deposition approach. C
60
-PEO and C
60
-PEO-C
60
exhibit fractal growth behavior on the solid substrate under certain conditions owing to the crystallization ability of PEO segment. PEO chain length and the end capped mode both affect the fractal growth pattern.
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