Clustering-triggered Emission of Cellulose and Its Derivatives

Lin-Lin Du; Bing-Li Jiang; Xiao-Hong Chen; Yun-Zhong Wang; Lin-Min Zou; Yuan-Li Liu; Yong-Yang Gong; Chun Wei; Wang-Zhang Yuan

doi:10.1007/s10118-019-2215-2

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Clustering-triggered Emission of Cellulose and Its Derivatives

ARTICLE | Updated：2021-02-18

- Clustering-triggered Emission of Cellulose and Its Derivatives
- Clustering-triggered Emission of Cellulose and Its Derivatives
- Chinese Journal of Polymer Science 2019年37卷第4期页码：409-415
- Affiliations：
  
  a.Key Laboratory of New Processing Technology for Non-ferrous Metals and Materials, Ministry of Education, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China
  b.College of Pharmacy, Guilin Medical University, Guilin 541004, China
  c.School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
- Author bio：
  
  yygong@glut.edu.cn (Y.Y.G.)
  1986024@glut.edu.cn (C.W.)
  wzhyuan@sjtu.edu.cn (W.Z.Y.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51603050 and 51863006), the Natural Science Foundation of Guangxi (Nos. 2016GXNSFBA380196, 2016GXNSFBA380064), Guangxi University Young and Middle-aged Teachers Basic Ability Promotion Project (No. KY2016YB316), and The Open Project Foundation of Guangxi Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials (15-KF-10).
- DOI：10.1007/s10118-019-2215-2
  中图分类号：
- 收稿：2018-10-31，
  
  修回：2018-12-21，
  
  录用：2018-12-24，
  
  网络首发：2019-01-21，
  
  纸质出版：2019-04
- Accepted：
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Citation: Du, L. L.; Jiang, B. L.; Chen, X. H.; Wang, Y. Z.; Zou, L. M.; Liu, Y. L.; Gong, Y. Y.; Wei, C.; Yuan, W. Z. Clustering-triggered emission of cellulose and its derivatives. Chinese J. Polym. Sci. 2019, 37, 409–415

Lin-Lin Du, Bing-Li Jiang, Xiao-Hong Chen, et al. Clustering-triggered Emission of Cellulose and Its Derivatives[J]. Chinese Journal of Polymer Science, 2019, 37(4): 409-415.
Citation: Du, L. L.; Jiang, B. L.; Chen, X. H.; Wang, Y. Z.; Zou, L. M.; Liu, Y. L.; Gong, Y. Y.; Wei, C.; Yuan, W. Z. Clustering-triggered emission of cellulose and its derivatives. Chinese J. Polym. Sci. 2019, 37, 409–415 DOI： 10.1007/s10118-019-2215-2.

Lin-Lin Du, Bing-Li Jiang, Xiao-Hong Chen, et al. Clustering-triggered Emission of Cellulose and Its Derivatives[J]. Chinese Journal of Polymer Science, 2019, 37(4): 409-415. DOI： 10.1007/s10118-019-2215-2.

摘要

Abstract

In recent years

nonconventional luminogens free of aromatic groups have attracted extensive attention due to their academic importance and promising wide applications. Whilst previous studies generally focused on fluorescence from aliphatic amine or carbonyl-containing systems

less attention has been paid to room temperature phosphorescence (RTP) and the systems with predominant oxygen functionalities. In this work

photophysical properties of the polyhydroxy polymers

including microcrystalline cellulose (MCC)

2-hydroxyethyl cellulose (HEC)

hydroxypropyl cellulose (HPC)

and cellulose acetate (CA)

were studied and compared. While MCC

HEC

and HPC solids showed bright emission alongside distinct RTP

CA demonstrated relatively low intensity of solid emission without noticeable RTP. Their emissions were explained in terms of the clustering-triggered emission (CTE) mechanism and conformation rigidification. Additionally

on account of its intrinsic emission

concentrated HEC aqueous solution could be used as the probe for the detection of 2

6-trinitrophenol (TNP).

关键词

Keywords

references

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