Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents

Hossein Ghasemzadeh; Maryam Dargahi; Ghazaleh Eyvazi; Bahman Vasheghani Farahani

doi:10.1007/s10118-019-2213-4

Your Location：

Home >

Browse articles >

Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents

ARTICLE | Updated：2021-02-18

- Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents
- Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents
- Chinese Journal of Polymer Science 2019年37卷第5期页码：444-450
- Affiliations：
  
  Department of Chemistry, Faculty of Science, Imam Khomeini International University, P.O. Box 288, Qazvin, Iran
- Author bio：
  
  hoghasemzadeh@gmail.com
  dargahi@sci.ikiu.ac.ir (M.D.)
  ghazaleyvazi@yahoo.com (G.E.)
  bvasheghanif@yahoo.com (V.B.F.)
- Funds：
- DOI：10.1007/s10118-019-2213-4
  中图分类号：
- 收稿：2018-09-22，
  
  修回：2018-12-8，
  
  录用：2018-12-21，
  
  网络首发：2019-01-29，
  
  纸质出版：2019-05
- Accepted：
Scan QR Code
Citation: Ghasemzadeh, H.; Dargahi, M.; Eyvazi, G.; Farahani, B. V. Nanomagnetic organogel based on dodecyl methacrylate for absorption and removal of organic solvents. Chinese J. Polym. Sci. 2019, 37, 444–450

Hossein Ghasemzadeh, Maryam Dargahi, Ghazaleh Eyvazi, et al. Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents[J]. Chinese Journal of Polymer Science, 2019, 37(5): 444-450.
Citation: Ghasemzadeh, H.; Dargahi, M.; Eyvazi, G.; Farahani, B. V. Nanomagnetic organogel based on dodecyl methacrylate for absorption and removal of organic solvents. Chinese J. Polym. Sci. 2019, 37, 444–450 DOI： 10.1007/s10118-019-2213-4.

Hossein Ghasemzadeh, Maryam Dargahi, Ghazaleh Eyvazi, et al. Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents[J]. Chinese Journal of Polymer Science, 2019, 37(5): 444-450. DOI： 10.1007/s10118-019-2213-4.

摘要

Abstract

A novel nanomagnetic organogel was synthesized by

in situ

emulsion polymerization-crosslinking method using dodecyl methacrylate (DDMA) and styrene (St) as monomers

divinylbenzene (DVB) as a crosslinking agent

azobisisobutyronitrile (AIBN) as an initiator

and Fe

as a nanomagnetic particle. Modification of the network was carried out by inclusion of the multi-walled carbon nanotubes (MWCNT) into the organogel matrix. The structure of the nanocomposite was characterized using FTIR spectroscopy

SEM

TEM

TGA/DTG

VSM

and BET analysis. The effects of various parameters such as the amount of crosslinker

initiator

and reaction time as well as monomer ratio on the oil absorption of the organogel were studied. The synthesized organogel can absorb about 35.5

22.1

29.86

14.58

17.6

15.3

and 13.7 g·g

−1

of CHCl

toluene

hexane

crude oil

gasoline

and diesel oil

under the optimized polymerization conditions

respectively. The nanocomposite organogels can be easily separated by a magnetic field after absorption of organic solvents.

关键词

Keywords

references

Doshi, B.; Sillanpaa, M.; Kalliola, S . A review of bio-based materials for oil spill treatment . Water Res. , 2018 . 135 262 - 277 . DOI: 10.1016/j.watres.2018.02.034 http://doi.org/10.1016/j.watres.2018.02.034 .

Kharisov, B. I.; González, M. O.; Quezada, T. S.; de la Fuente, I. G.; Longoria, F . Materials and nanomaterials for the removal of heavy oil components . J. Petrol. Sci. Eng. , 2017 . 156 971 - 982 . DOI: 10.1016/j.petrol.2017.06.065 http://doi.org/10.1016/j.petrol.2017.06.065 .

Cao, S.; Dong, T.; Xu, G.; Wang, F. M . Oil spill cleanup by hydrophobic natural fibers . J. Nat. Fibers , 2017 . 14 727 - 735 . DOI: 10.1080/15440478.2016.1277820 http://doi.org/10.1080/15440478.2016.1277820 .

Wang, J.; Zheng, Y.; Wang, A . Effect of kapok fiber treated with various solvents on oil absorbency . Ind. Crops. Prod. , 2012 . 40 178 - 184 . DOI: 10.1016/j.indcrop.2012.03.002 http://doi.org/10.1016/j.indcrop.2012.03.002 .

Likon, M.; Remskar, M.; Ducman, V.; Svegl, F . Populus seed fibers as a natural source for production of oil super absorbents . J. Environ. Manage. , 2013 . 114 158 - 167 . DOI: 10.1016/j.jenvman.2012.03.047 http://doi.org/10.1016/j.jenvman.2012.03.047 .

Zheng, Y.; Zhu, Y.; Wang, A.; Hu, H . Potential of Calotropis gigantea fiber as an absorbent for removal of oil from water . Ind. Crops. Prod. , 2016 . 83 387 - 390 . DOI: 10.1016/j.indcrop.2016.01.009 http://doi.org/10.1016/j.indcrop.2016.01.009 .

Ali, I.; Asim, M.; Khan, T. A . Low cost adsorbents for the removal of organic pollutants from wastewater . J. Environ. Manage. , 2012 . 113 170 - 183 . DOI: 10.1016/j.jenvman.2012.08.028 http://doi.org/10.1016/j.jenvman.2012.08.028 .

Adebajo, M. O.; Frost, R. L.; Kloprogge, J. T.; Carmody, O.; Kokot, S . Porous materials for oil spill cleanup: A review of synthesis and absorbing properties . J. Porous Mat. , 2003 . 10 159 - 170 . DOI: 10.1023/A:1027484117065 http://doi.org/10.1023/A:1027484117065 .

Chen, C.; Li, F.; Zhang, Y.; Wang, B.; Fan, Y.; Wang, X.; Sun, R . Compressive, ultralight and fire-resistant lignin-modified graphene aerogels as recyclable absorbents for oil and organic solvents . Chem. Eng. J. , 2018 . 350 173 - 180 . DOI: 10.1016/j.cej.2018.05.189 http://doi.org/10.1016/j.cej.2018.05.189 .

Li, Z.; Shao, L.; Hu, W.; Zheng, T.; Lu, L.; Cao, Y.; Chen, Y . Excellent reusable chitosan/cellulose aerogel as an oil and organic solvent absorbent . Carbohydr. Polym. , 2018 . 191 183 - 190 . DOI: 10.1016/j.carbpol.2018.03.027 http://doi.org/10.1016/j.carbpol.2018.03.027 .

Lee, J. H.; Kim, D. H.; Kim, Y. D . High-performance, recyclable and superhydrophobic oil absorbents consisting of cotton with a polydimethylsiloxane shell . J. Ind. Eng. Chem. , 2016 . 35 140 - 145 . DOI: 10.1016/j.jiec.2015.12.025 http://doi.org/10.1016/j.jiec.2015.12.025 .

Özen, İ.; Şimşek, S.; Okyay, G . Manipulating surface wettability and oil absorbency of diatomite depending on processing and ambient conditions . Appl. Surf. Sci. , 2015 . 332 22 - 31 . DOI: 10.1016/j.apsusc.2015.01.149 http://doi.org/10.1016/j.apsusc.2015.01.149 .

Cao, E.; Xiao, W.; Duan, W.; Wang, N.; Wang, A.; Zheng, Y . Metallic nanoparticles roughened Calotropis gigantea fiber enables efficient absorption of oils and organic solvents . Ind. Crops. Prod. , 2018 . 115 272 - 279 . DOI: 10.1016/j.indcrop.2018.02.052 http://doi.org/10.1016/j.indcrop.2018.02.052 .

Nwadiogbu, J. O.; Ajiwe, V. I. E.; Okoye, P. A. C . Removal of crude oil from aqueous medium by sorption on hydrophobic corncobs: Equilibrium and kinetic studies . J. Taibah. Univ. Sci. , 2018 . 10 ( 1 ): 56 - 63 . .

Shang, W.; Sheng, Z.; Shen, Y.; Ai, B.; Zheng, L.; Yang, J.; Xu, Z . Study on oil absorbency of succinic anhydride modified banana cellulose in ionic liquid . Carbohydr. Polym. , 2016 . 141 135 - 142 . DOI: 10.1016/j.carbpol.2016.01.009 http://doi.org/10.1016/j.carbpol.2016.01.009 .

Zhai, T.; Zheng, Q.; Cai, Z.; Xia, H.; Gong, S . Synthesis of polyvinyl alcohol/cellulose nanofibril hybrid aerogel microspheres and their use as oil/solvent superabsorbents . Carbohydr. Polym. , 2016 . 148 300 - 308 . DOI: 10.1016/j.carbpol.2016.04.065 http://doi.org/10.1016/j.carbpol.2016.04.065 .

Chen, J.; Wang, S.; Peng, J.; Li, J.; Zhai, M . New lipophilic polyelectrolyte gels containing quaternary ammonium salt with superabsorbent capacity for organic solvents . ACS Appl. Mater. Interfaces , 2014 . 6 ( 17 ): 14894 - 14902 . DOI: 10.1021/am504102r http://doi.org/10.1021/am504102r .

Kizil, S.; Karadag, K.; Ozan Aydin, G.; Bulbul Sonmez, H . Poly(alkoxysilane) reusable organogels for removal of oil/organic solvents from water surface . J. Environ. Manage. , 2015 . 149 57 - 64 . DOI: 10.1016/j.jenvman.2014.09.030 http://doi.org/10.1016/j.jenvman.2014.09.030 .

Nam, C.; Zhang, G.; Chung, T. C. M . Polyolefin-based interpenetrating polymer network absorbent for crude oil entrapment and recovery in aqueous system . J. Hazard. Mater. , 2018 . 351 285 - 292 . DOI: 10.1016/j.jhazmat.2018.03.004 http://doi.org/10.1016/j.jhazmat.2018.03.004 .

Pourjavadi, A.; Doulabi, M.; Soleyman, R . Novel carbon-nanotube-based organogels as candidates for oil recovery . Polym. Int. , 2013 . 62 ( 2 ): 179 - 183 . DOI: 10.1002/pi.2013.62.issue-2 http://doi.org/10.1002/pi.2013.62.issue-2 .

Rahmani, Z.; Samadi, M. T.; Kazemi, A.; Rashidi, A. M.; Rahmani, A. R . Nanoporous graphene and graphene oxide-coated polyurethane sponge as a highly efficient, superhydrophobic, and reusable oil spill absorbent . J. Environ. Chem. Eng. , 2017 . 5 ( 5 ): 5025 - 5032 . DOI: 10.1016/j.jece.2017.09.028 http://doi.org/10.1016/j.jece.2017.09.028 .

Pourjavadi, A.; Doulabi, M.; Hosseini, S. H . Novel polyelectrolyte gels as absorbent polymers for nonpolar organic solvents based on polymerizable ionic liquids . Polymer , 2012 . 53 ( 25 ): 5737 - 5742 . DOI: 10.1016/j.polymer.2012.10.010 http://doi.org/10.1016/j.polymer.2012.10.010 .

Song, C.; Ding, L.; Yao, F.; Deng, J.; Yang, W . β -Cyclodextrin-based oil-absorbent microspheres: Preparation and high oil absorbency . Carbohydr. Polym. , 2013 . 91 ( 1 ): 217 - 223 . DOI: 10.1016/j.carbpol.2012.08.036 http://doi.org/10.1016/j.carbpol.2012.08.036 .

Zhang, T.; Kong, L.; Dai, Y.; Yue, X.; Rong, J.; Qiu, F.; Pan, J . Enhanced oils and organic solvents absorption by polyurethane foams composites modified with MnO 2 nanowires . Chem. Eng. J. , 2017 . 309 7 - 14 . DOI: 10.1016/j.cej.2016.08.085 http://doi.org/10.1016/j.cej.2016.08.085 .

Durgun, M.; Ozan Aydin, G.; Bulbul Sonmez, H . Aromatic alkoxysilane based hybrid organogels as sorbent for toxic organic compounds, fuels and crude oil . React. Funct. Polym. , 2017 . 115 63 - 72 . DOI: 10.1016/j.reactfunctpolym.2017.03.017 http://doi.org/10.1016/j.reactfunctpolym.2017.03.017 .

Cao, W. T.; Liu, Y. J.; Ma, M. G.; Zhu, J. F . Facile preparation of robust and superhydrophobic materials for self-cleaning and oil/water separation . Colloid. Surf. A , 2017 . 529 18 - 25 . DOI: 10.1016/j.colsurfa.2017.05.064 http://doi.org/10.1016/j.colsurfa.2017.05.064 .

Periasamy, A. P.; Wu, W. P.; Ravindranath, R.; Roy, P.; Lin, G. L.; Chang, H. T . Polymer/reduced graphene oxide functionalized sponges as superabsorbents for oil removal and recovery . Mar. Pollut. Bull. , 2017 . 114 ( 2 ): 888 - 895 . DOI: 10.1016/j.marpolbul.2016.11.005 http://doi.org/10.1016/j.marpolbul.2016.11.005 .

Wu, B.; Zhou, M. H . Recycling of waste tyre rubber into oil absorbent . Waste Manag. , 2009 . 29 ( 1 ): 355 - 359 . DOI: 10.1016/j.wasman.2008.03.002 http://doi.org/10.1016/j.wasman.2008.03.002 .

Yin, T.; Zhang, X.; Liu, X.; Wang, C . Resource recovery of Eichhornia crassipes as oil superabsorbent . Mar. Pollut. Bull. , 2017 . 118 ( 1-2 ): 267 - 274 . DOI: 10.1016/j.marpolbul.2017.01.064 http://doi.org/10.1016/j.marpolbul.2017.01.064 .

Wang, J.; Zheng, Y.; Wang, A . Superhydrophobic kapok fiber oil-absorbent: Preparation and high oil absorbency . Chem. Eng. J. , 2012 . 213 1 - 7 . DOI: 10.1016/j.cej.2012.09.116 http://doi.org/10.1016/j.cej.2012.09.116 .

Wang, Y.; Li, Q.; Bo, L.; Wang, X.; Zhang, T.; Li, S.; Ren, P.; Wei, G . Synthesis and oil absorption of biomorphic MgAl layered double oxide/acrylic ester resin by suspension polymerization . Chem. Eng. J. , 2016 . 284 989 - 994 . DOI: 10.1016/j.cej.2015.09.052 http://doi.org/10.1016/j.cej.2015.09.052 .

Yue, X.; Zhang, T.; Yang, D.; Qiu, F.; Rong, J.; Xu, J.; Fang, J . The synthesis of hierarchical porous Al 2 O 3 /acrylic resin composites as durable, efficient and recyclable absorbents for oil/water separation . Chem. Eng. J. , 2017 . 309 522 - 531 . DOI: 10.1016/j.cej.2016.10.049 http://doi.org/10.1016/j.cej.2016.10.049 .

Zhang, C.; Yang, D.; Zhang, T.; Qiu, F.; Dai, Y.; Xu, J.; Jing, Z . Synthesis of MnO 2 /poly( n -butylacrylate- co -butyl methacrylate- co -methyl methacrylate) hybrid resins for efficient oils and organic solvents absorption . J. Clean. Prod. , 2017 . 148 398 - 406 . DOI: 10.1016/j.jclepro.2017.02.009 http://doi.org/10.1016/j.jclepro.2017.02.009 .

Gao, H.; Sun, P.; Zhang, Y.; Zeng, X.; Wang, D.; Zhang, Y.; Wang, W.; Wu, J . A two-step hydrophobic fabrication of melamine sponge for oil absorption and oil/water separation . Surf. Coat. Tech. , 2018 . 339 147 - 154 . DOI: 10.1016/j.surfcoat.2018.02.022 http://doi.org/10.1016/j.surfcoat.2018.02.022 .

Gupta, S.; Tai, N. H . Carbon materials as oil sorbents: A review on the synthesis and performance . J. Mat. Chem. A , 2016 . 4 1550 - 1565 . DOI: 10.1039/C5TA08321D http://doi.org/10.1039/C5TA08321D .

Ge, J.; Zhao, H. Y.; Zhu, H. W.; Huang, J.; Shi, L. A.; Yu, S. H . Advanced sorbents for oil-spill cleanup: Recent advances and future perspectives . Adv. Mater. , 2016 . 28 ( 47 ): 10459 - 10490 . DOI: 10.1002/adma.v28.47 http://doi.org/10.1002/adma.v28.47 .

Saleem, J.; Adil Riaz, M.; Gordon, M . Oil sorbents from plastic wastes and polymers: A review . J. Hazard. Mater. , 2018 . 341 424 - 437 . DOI: 10.1016/j.jhazmat.2017.07.072 http://doi.org/10.1016/j.jhazmat.2017.07.072 .

Mi, H. Y.; Jing, X.; Xie, H.; Huang, H. X.; Turng, L. S . Magnetically driven superhydrophobic silica sponge decorated with hierarchical cobalt nanoparticles for selective oil absorption and oil/water separation . Chem. Eng. J. , 2018 . 337 541 - 551 . DOI: 10.1016/j.cej.2017.12.135 http://doi.org/10.1016/j.cej.2017.12.135 .

Gu, J.; Jiang, W.; Wang, F.; Chen, M.; Mao, J.; Xie, T . Facile removal of oils from water surfaces through highly hydrophobic and magnetic polymer nanocomposites . Appl. Surf. Sci. , 2014 . 301 492 - 499 . DOI: 10.1016/j.apsusc.2014.02.112 http://doi.org/10.1016/j.apsusc.2014.02.112 .

Song, B.; Zhu, J.; Fan, H . Magnetic fibrous sorbent for remote and efficient oil adsorption . Mar. Pollut. Bull. , 2017 . 120 ( 1-2 ): 159 - 164 . DOI: 10.1016/j.marpolbul.2017.05.011 http://doi.org/10.1016/j.marpolbul.2017.05.011 .

Turco, A.; Malitesta, C.; Barillaro, G.; Greco, A.; Maffezzoli, A.; Mazzotta, E . A magnetic and highly reusable macroporous superhydrophobic/superoleophilic DDMS/MWNT nanocomposite for oil sorption from water . J. Mater. Chem. A , 2015 . 3 17685 - 17696 . DOI: 10.1039/C5TA04353K http://doi.org/10.1039/C5TA04353K .

Gui, X.; Zeng, Z.; Lin, Z.; Gan, Q.; Xiang, R.; Zhu, Y.; Cao, A.; Tang, Z . Magnetic and highly recyclable macroporous carbon nanotubes for spilled oil sorption and separation . ACS Appl. Mater. Interfaces , 2013 . 5 ( 12 ): 5845 - 5850 . DOI: 10.1021/am4015007 http://doi.org/10.1021/am4015007 .

Cheng, Y.; Xu P.; Zeng W.; Ling, C.; Zhao, S.; Liao, K.; Sun, Y.; Zhou, A . Highly hydrophobic and ultralight graphene aerogel as high efficiency oil absorbent material . J. Environ. Chem. Eng. , 2017 . 5 1957 - 1963 . DOI: 10.1016/j.jece.2017.04.005 http://doi.org/10.1016/j.jece.2017.04.005 .

Teli, M. D.; Valia, S. P . Acetylation of banana fiber to improve oil absorbency . Carbohydr. Polym. , 2013 . 92 328 DOI: 10.1016/j.carbpol.2012.09.019 http://doi.org/10.1016/j.carbpol.2012.09.019 .

Yu, I.; Hao, G.; Liang, Q.; Zhou, S.; Zhang, N.; Jiang, W . Facile preparation and characterization of modified magnetic silica nanocomposite particles for oil absorption . Appl. Surf. Sci. B , 2015 . 357 2297 - 2305 . DOI: 10.1016/j.apsusc.2015.09.231 http://doi.org/10.1016/j.apsusc.2015.09.231 .

Liu, T.; Chen, S.; Liu, H . Oil adsorption and reuse performance of multi-walled carbon nanotubes . Procedia Eng. , 2015 . 102 1896 - 1902 . DOI: 10.1016/j.proeng.2015.01.329 http://doi.org/10.1016/j.proeng.2015.01.329 .

Lu, Y.; Wang, Y.; Liu, L.; Yuan, W . Environmental-friendly and magnetic/silanized ethyl cellulose sponges as effective and recyclable oil-absorption materials . Carbohydr. Polym. , 2017 . 173 422 - 430 . DOI: 10.1016/j.carbpol.2017.06.009 http://doi.org/10.1016/j.carbpol.2017.06.009 .

Samadi, S.; Yazd, S. S.; Abdoli, H.; Jafari, P.; Aliabadi, M . Fabrication of novel chitosan/PAN/magnetic ZSM-5 zeolite coated sponges for absorption of oil from water surfaces . Int. J. Biol. Macromol. , 2017 . 105 370 - 376 . DOI: 10.1016/j.ijbiomac.2017.07.050 http://doi.org/10.1016/j.ijbiomac.2017.07.050 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

Anionic Copolymerization of α-Methylstyrene (AMS) and Styrene (St) under the Mild Temperature

High-performance Vanillin-derived Dielectric Polymer Films for Sustainable Energy Storage

Pyrimidoisoindigo-based Polymers for Ambipolar Charge Transport

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast