Synthesis of Eugenol Bio-based Reactive Epoxy Diluent and Study on the Curing Kinetics and Properties of the Epoxy Resin System

Bin Chen; Feng Wang; Jing-Yu Li; Jia-Lu Zhang; Yan Zhang; Hai-Chao Zhao

doi:10.1007/s10118-019-2210-7

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Synthesis of Eugenol Bio-based Reactive Epoxy Diluent and Study on the Curing Kinetics and Properties of the Epoxy Resin System

ARTICLE | Updated：2021-02-18

- Synthesis of Eugenol Bio-based Reactive Epoxy Diluent and Study on the Curing Kinetics and Properties of the Epoxy Resin System
- Synthesis of Eugenol Bio-based Reactive Epoxy Diluent and Study on the Curing Kinetics and Properties of the Epoxy Resin System
- Chinese Journal of Polymer Science 2019年37卷第5期页码：500-508
- Affiliations：
  
  a.School of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
  b.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
- Author bio：
  
  bchen63@163.com (B.C.)
  zhaohaichao@nimte.ac.cn (H.C.Z.)
- Funds：
  
  The authors gratefully acknowledged the financial support provided by “One Hundred Talented People” of the Chinese Academy of Sciences–China (No. Y60707WR04) and Natural Science Foundation of Zhejiang Province (No. Y16B040008).
- DOI：10.1007/s10118-019-2210-7
  中图分类号：
- 收稿：2018-09-06，
  
  修回：2018-12-8，
  
  录用：2018-12-11，
  
  网络首发：2019-01-11，
  
  纸质出版：2019-05
- Accepted：
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Citation: Chen, B.; Wang, F.; Li, J. Y.; Zhang, J. L.; Zhang, Y.; Zhao, H. C. Synthesis of eugenol bio-based reactive epoxy diluent and study on the curing kinetics and properties of the epoxy resin system. Chinese J. Polym. Sci. 2019, 37, 500–508

Bin Chen, Feng Wang, Jing-Yu Li, et al. Synthesis of Eugenol Bio-based Reactive Epoxy Diluent and Study on the Curing Kinetics and Properties of the Epoxy Resin System[J]. Chinese Journal of Polymer Science, 2019, 37(5): 500-508.
Citation: Chen, B.; Wang, F.; Li, J. Y.; Zhang, J. L.; Zhang, Y.; Zhao, H. C. Synthesis of eugenol bio-based reactive epoxy diluent and study on the curing kinetics and properties of the epoxy resin system. Chinese J. Polym. Sci. 2019, 37, 500–508 DOI： 10.1007/s10118-019-2210-7.

Bin Chen, Feng Wang, Jing-Yu Li, et al. Synthesis of Eugenol Bio-based Reactive Epoxy Diluent and Study on the Curing Kinetics and Properties of the Epoxy Resin System[J]. Chinese Journal of Polymer Science, 2019, 37(5): 500-508. DOI： 10.1007/s10118-019-2210-7.

摘要

Abstract

In this study

monoglycidyl silyl etherated eugenol (GSE) was synthesized as reactive epoxy diluent

and the chemical structure of GSE

intermediates

and products were characterized by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (

H-NMR). GSE existed as a potential bio-based reactive diluent for petroleum-based epoxy resin. The curing kinetics of EP/HHPA/GSE system was studied by non-isothermal DSC method. The kinetics parameters were calculated by using the Kissinger model

Crane model

Ozawa model

and

(temperature-heating rate) extrapolation

respectively. In addition

the effects of GSE on the thermo-mechanical properties and thermal stability of EP/HHPA/GSE systems were studied

indicating that GSE can effectively improve the toughness and thermal decomposition temperature of the epoxy system.

关键词

Keywords

references

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