Synthesis of Alkyne-functionalized Polymers <italic style="font-style: italic">via</italic> Living Anionic Polymerization and Investigation of Features during the Post-“thiol-yne” Click Reaction

Lin-Can Yang; Li Han; Hong-Wei Ma; Pi-Bo Liu; He-Yu Shen; Chao Li; Song-Bo Zhang; Yang Li

doi:10.1007/s10118-019-2203-6

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Synthesis of Alkyne-functionalized Polymers via Living Anionic Polymerization and Investigation of Features during the Post-“thiol-yne” Click Reaction

ARTICLE | Updated：2021-02-18

- Synthesis of Alkyne-functionalized Polymers via Living Anionic Polymerization and Investigation of Features during the Post-“thiol-yne” Click Reaction
- Synthesis of Alkyne-functionalized Polymers via Living Anionic Polymerization and Investigation of Features during the Post-“thiol-yne” Click Reaction
- Chinese Journal of Polymer Science 2019年37卷第9期页码：841-850
- Affiliations：
  
  Department of Polymer Science and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
- Author bio：
  
  mahw@dlut.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21871037, 21674017, and U1508204).
- DOI：10.1007/s10118-019-2203-6
  中图分类号：
- 收稿：2018-09-26，
  
  修回：2018-11-19，
  
  录用：2018-12-3，
  
  网络首发：2018-12-29，
  
  纸质出版：2019-09
- Accepted：
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Citation: Yang, L. C.; Han, L.; Ma, H. W.; Liu, P. B.; Shen, H. Y.; Li, C.; Zhang, S. B.; Li, Y. Synthesis of alkyne-functionalized polymers via living anionic polymerization and investigation of features during the post-“thiol-yne” click reaction. Chinese J. Polym. Sci. 2019, 37, 841–850

Lin-Can Yang, Li Han, Hong-Wei Ma, et al. Synthesis of Alkyne-functionalized Polymers via Living Anionic Polymerization and Investigation of Features during the Post-“thiol-yne” Click Reaction[J]. Chinese Journal of Polymer Science, 2019, 37(9): 841-850. DOI: 10.1007/s10118-019-2203-6.
Citation: Yang, L. C.; Han, L.; Ma, H. W.; Liu, P. B.; Shen, H. Y.; Li, C.; Zhang, S. B.; Li, Y. Synthesis of alkyne-functionalized polymers via living anionic polymerization and investigation of features during the post-“thiol-yne” click reaction. Chinese J. Polym. Sci. 2019, 37, 841–850 DOI： 10.1007/s10118-019-2203-6.

Lin-Can Yang, Li Han, Hong-Wei Ma, et al. Synthesis of Alkyne-functionalized Polymers via Living Anionic Polymerization and Investigation of Features during the Post-“thiol-yne” Click Reaction[J]. Chinese Journal of Polymer Science, 2019, 37(9): 841-850. DOI: 10.1007/s10118-019-2203-6. DOI：

摘要

Abstract

" Thiol-yne” click reaction has already been widely applied in synthesis and modification of new polymer structures or novel materials due to its specific features. However

in most studies

only chain-end strategy was employed when using the di-addition feature of thiol-yne reaction

thus the in-chain di-addition strategy could endow us with a broader space to develop the synthesis of advanced polymers. Therefore

in this paper

the features of in-chain mono- and di-addition were investigated when modifying the alkyne-functionalized polymers to prepare grafted polymers

via

thiol-yne click reaction. The results showed that it is almost impossible to obtain the in-chain di-adducts even under excess feeding of chain-end thiol-functionalized grafts

while only the in-chain mono-adducts could be obtained efficiently. Further researches investigated that the controlled grafting could be encountered when carrying out the thiol-yne click reaction between chain-end alkyne-functionalized polystyrenes and chain-end thiol-functionalized polystyrenes under proper feedings. Therefore

the effect of steric-hindrance might be the primary reason for the alternative grafting

via

thiol-yne click reaction between in-chain and chain-end alkyne-functionalized polymers.

关键词

Keywords

references

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Synthesis of Alkyne-functionalized Polymers via Living Anionic Polymerization and Investigation of Features during the Post-“thiol-yne” Click Reaction

DOI：10.1007/s10118-019-2203-6

摘要

Abstract

关键词

Keywords

references