Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene

Pei Xu; Zhao-Pei Cui; Gang Ruan; Yun-Sheng Ding

doi:10.1007/s10118-019-2192-5

Your Location：

Home >

Browse articles >

Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene

ARTICLE | Updated：2021-02-18

- Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene
- Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene
- Chinese Journal of Polymer Science 2019年37卷第3期页码：243-252
- Affiliations：
  
  Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, and Anhui Key Laboratory of Advanced Functional Materials and Devices, Hefei University of Technology, Hefei 230009, China
- Author bio：
  
  chxuper@hfut.edu.cn (P.X.)
  dingys@hfut.edu.cn (Y.S.D.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51603060) and the Fundamental Research Funds for the Central Universities (No. JZ2017YYPY0250).
- DOI：10.1007/s10118-019-2192-5
  中图分类号：
- 收稿：2018-07-04，
  
  修回：2018-9-23，
  
  录用：2018-9-25，
  
  网络首发：2018-11-02，
  
  纸质出版：2019-03
- Accepted：
Scan QR Code
Citation: Xu, P.; Cui, Z. P.; Ruan, G.; Ding, Y. S. Enhanced crystallization kinetics of PLLA by ethoxycarbonyl ionic liquid modified graphene. Chinese J. Polym. Sci. 2019, 37, 243–252

Pei Xu, Zhao-Pei Cui, Gang Ruan, et al. Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene[J]. Chinese Journal of Polymer Science, 2019, 37(3): 243-252.
Citation: Xu, P.; Cui, Z. P.; Ruan, G.; Ding, Y. S. Enhanced crystallization kinetics of PLLA by ethoxycarbonyl ionic liquid modified graphene. Chinese J. Polym. Sci. 2019, 37, 243–252 DOI： 10.1007/s10118-019-2192-5.

Pei Xu, Zhao-Pei Cui, Gang Ruan, et al. Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene[J]. Chinese Journal of Polymer Science, 2019, 37(3): 243-252. DOI： 10.1007/s10118-019-2192-5.

摘要

Abstract

To investigate the performance of graphene (Gra) modified with ethoxycarbonyl ionic liquid (IL)

chain mobility and crystallization kinetics of poly(L-lactic acid) (PLLA)

a series of PLLA nanocomposites have been prepared using solution-cast method. IL can improve the dispersion of Gra in PLLA matrix and the samples containing IL have higher growth rate of PLLA spherulite than neat PLLA does. PLLA/IL/Gra and PLLA/2Gra exhibit the same relaxation strength and time of

relaxation that corresponds to the longest normal mode motion at 110−140 °C. PLLA/IL/Gra shows a faster crystallization rate than PLLA/2Gra does

which might be attributed to the Gra-imidazolium cation interaction in IL modified Gra

the significant dispersion effect of IL at Gra surface

and the increase of nuclei density of PLLA/IL/Gra.

关键词

Keywords

references

Gupta, B.; Revagade, N.; Hilborn, J . Poly(lactic acid) fiber: An overview . Prog. Polym. Sci. , 2007 . 32 455 - 482 . DOI: 10.1016/j.progpolymsci.2007.01.005 http://doi.org/10.1016/j.progpolymsci.2007.01.005 .

Drumright, R. E.; Gruber, P. R.; Henton, D. E . Polylactic acid technology . Adv. Mater. , 2000 . 23 1841 - 1846 . .

Proikakis, C. S.; Mamouzelos, N. J.; Tarantili, P. A.; Andreopoulos, A. G . Swelling and hydrolytic degradation of poly(D, L-lactic acid) in aqueous solutions . Polym. Degrad. Stab. , 2006 . 91 614 - 619 . DOI: 10.1016/j.polymdegradstab.2005.01.060 http://doi.org/10.1016/j.polymdegradstab.2005.01.060 .

Hiljanen-Vainio, M.; Varpomaa, P.; Seppälä, J.; Törmälä, P . Modification of poly(L-lactides) by blending: Mechanical and hydrolytic behavior . Macromol. Chem. Phys. , 1996 . 197 1503 - 1523 . DOI: 10.1002/macp.1996.021970427 http://doi.org/10.1002/macp.1996.021970427 .

Aou, K.; Hsu, S. L.; Kleiner, L. W.; Tang, F. W . Roles of Conformational and configurational defects on the physical aging of amorphous poly(lactic acid) . J. Phys. Chem. B , 2007 . 111 12322 - 12327 . DOI: 10.1021/jp074509t http://doi.org/10.1021/jp074509t .

Saeidlou, S.; Huneault, M. A.; Li, H.; Park, C. B . Poly(lactic acid) crystallization . Prog. Polym. Sci. , 2012 . 37 1657 - 1677 . DOI: 10.1016/j.progpolymsci.2012.07.005 http://doi.org/10.1016/j.progpolymsci.2012.07.005 .

Xing, Q.; Li, R. B.; Dong, X.; Zhang, X. Q.; Zhang, L. Y.; Wang, D. J . Phase morphology, crystallization behavior and mechanical properties of poly(L-lactide) toughened with biodegradable polyurethane: Effect of composition and hard segment ratio . Chinese J. Polym. Sci. , 2015 . 33 1294 - 1304 . DOI: 10.1007/s10118-015-1679-y http://doi.org/10.1007/s10118-015-1679-y .

Yang, G.; Gao, Q.; Ouyang, C. F.; Zheng, K. S.; Guo, Y . Influence of nucleating agent on PLLA crystalline and mechanical properties . Adv. Mater. Res. , 2013 . 624 269 - 273 . .

Xing, Q.; Li, R. B.; Dong, X.; Luo, F. L.; Kuang, X.; Wang, D. J.; Zhang, L. Y . Enhanced crystallization rate of poly(L-lactide) mediated by a hydrazide compound: Nucleating mechanism study . Macromol. Chem. Phys. , 2015 . 10 1134 - 1145 . .

Shi, H.; Chen, X.; Chen, W. K.; Pang, S. J.; Pan, L. S.; Xu, N.; Li, T . Crystallization behavior, heat resistance, and mechanical performances of PLLA/ myo -inositol blends . J. Appl. Polym. Sci. , 2017 . 134 44732 .

Xing, Q.; Li, R. B.; Zhang, X. Q.; Dong, X.; Wang, D. J.; Zhang, L. Y . Tailoring crystallization behavior of poly(L-lactide) with a low molecular weight aliphatic amide . Colloid Polym. Sci. , 2015 . 293 3573 - 3583 . DOI: 10.1007/s00396-015-3730-5 http://doi.org/10.1007/s00396-015-3730-5 .

Chen, L.; Hou, X.; Song, N.; Shi, L.; Ding, P . Cellulose/graphene bioplastic for thermal management: Enhanced isotropic thermally conductive property by three-dimensional interconnected graphene aerogel . Compos. Part A: Appl. S. , 2018 . 107 189 - 196 . DOI: 10.1016/j.compositesa.2017.12.014 http://doi.org/10.1016/j.compositesa.2017.12.014 .

Xu, J. Z.; Chen, T.; Yang, C. L.; Li, Z. M.; Mao, Y. M.; Zeng, B. Q.; Hsiao, B. S . Isothermal crystallization of poly(L-lactide) induced by graphene nanosheets and carbon nanotubes: A comparative study . Macromolecules , 2010 . 43 5000 - 5008 . DOI: 10.1021/ma100304n http://doi.org/10.1021/ma100304n .

Liang, Y. Y.; Yang, S.; Jiang, X.; Zhong, G. J.; Xu, J. Z.; Li, Z. M . Nucleation ability of thermally reduced graphene oxide for polylactide: Role of size and structural integrity . J. Phys. Chem. B , 2015 . 119 4777 - 4787 . DOI: 10.1021/jp511742b http://doi.org/10.1021/jp511742b .

Papageorgiou, G. Z.; Terzopoulou, Z.; Bikiaris, D.; Triantafyllidis, K. S.; Diamanti, E.; Gournis, D.; Pissis, P . Evaluation of the formed interface in biodegradable poly(L-lactic acid)/graphene oxide nanocomposites and the effect of nanofillers on mechanical and thermal properties . Thermochim. Acta , 2014 . 597 48 - 57 . DOI: 10.1016/j.tca.2014.10.007 http://doi.org/10.1016/j.tca.2014.10.007 .

Manafi, P.; Ghasemi, I.; Karrabi, M.; Azizi, H.; Ehsaninamin, P . Effect of graphene nanoplatelets on crystallization kinetics of poly(lactic acid) . Soft Mater. , 2014 . 12 433 - 444 . DOI: 10.1080/1539445X.2014.959598 http://doi.org/10.1080/1539445X.2014.959598 .

Huang, H. D.; Xu, J. Z.; Fan, Y.; Xu, L.; Li, Z. M . Poly(L-lactic acid) crystallization in a confined space containing graphene oxide nanosheets . J. Phys. Chem. B , 2013 . 117 10641 - 10651 . DOI: 10.1021/jp4055796 http://doi.org/10.1021/jp4055796 .

Plechkova, N. V.; Seddon, K. R . Applications of ionic liquids in the chemical industry . Chem. Soc. Rev. , 2008 . 37 123 - 150 . DOI: 10.1039/B006677J http://doi.org/10.1039/B006677J .

Armand, M.; Endres, F.; Macfarlane, D. R.; Ohno, H.; Scrosati, B . Ionic-liquid materials for the electrochemical challenges of the future . Nat. Mater. , 2009 . 8 621 - 629 . DOI: 10.1038/nmat2448 http://doi.org/10.1038/nmat2448 .

Rogers, R. D.; Seddon, K. R . Ionic liquids—solvents of the future? . Science , 2003 . 5646 792 - 793 . .

Scott, M. P.; Brazel, C. S.; Benton, M. G.; Mays, J. W.; Holbrey, J. D.; Rogers, R. D . Application of ionic liquids as plasticizers for poly(methyl methacrylate) . Chem. Commun. , 2002 . 13 1370 - 1371 . .

Gui, H.; Li, Y.; Chen, S.; Xu, P.; Zheng, B.; Ding, Y . Effects of biodegradable imidazolium-based ionic liquid with ester group on the structure and properties of PLLA . Macromol. Res. , 2014 . 22 583 - 591 . DOI: 10.1007/s13233-014-2085-y http://doi.org/10.1007/s13233-014-2085-y .

Leng, J.; Purohit, P. J.; Kang, N.; Wang, D. Y.; Falkenhagen, J.; Emmerling, F . Structure-property relationships of nanocomposites based on polylactide and MgAl layered double hydroxides . Eur. Polym. J. , 2015 . 68 338 - 354 . DOI: 10.1016/j.eurpolymj.2015.05.008 http://doi.org/10.1016/j.eurpolymj.2015.05.008 .

Saiter, A.; Delpouve, N.; Dargent, E.; Oberhauser, W.; Conzatti, L.; Cicogna, F.; Passaglia, E . Probing the chain segment mobility at the interface of semi-crystalline polylactide/clay nanocomposites . Eur. Polym. J. , 2016 . 78 274 - 289 . DOI: 10.1016/j.eurpolymj.2016.03.040 http://doi.org/10.1016/j.eurpolymj.2016.03.040 .

Klonos, P.; Terzopoulou, Z.; Koutsoumpis, S.; Zidropoulos, S.; Kripotou, S.; Papageorgiou, G. Z.; Pissis, P . Rigid amorphous fraction and segmental dynamics in nanocomposites based on poly(L-lactic acid) and nano-inclusions of 1-3D geometry studied by thermal and dielectric techniques . Eur. Polym. J. , 2016 . 82 16 - 34 . DOI: 10.1016/j.eurpolymj.2016.07.002 http://doi.org/10.1016/j.eurpolymj.2016.07.002 .

Xu, P.; Gui, H. G.; Yang, S. Z.; Ding, Y. S.; Hao, Q . Dielectric and conductivity properties of poly(L-lactide) and poly(L-lactide)/ionic liquid blends . Macromol. Res. , 2014 . 22 304 - 309 . DOI: 10.1007/s13233-014-2038-5 http://doi.org/10.1007/s13233-014-2038-5 .

Zhao, Y.; Hu, Z . Graphene in ionic liquids: Collective van der Waals interaction and hindrance of self-assembly pathway . J. Phys. Chem. B , 2013 . 36 10540 - 10547 . .

Saxena, A. P.; Deepa, M.; Joshi, A. G.; Bhandari, S.; Srivastava, A. K . Poly(3,4-ethylenedioxythiophene)-ionic liquid functionalized graphene/reduced graphene oxide nanostructures: Improved conduction and electrochromism . ACS Appl. Mater. Interface , 2011 . 4 1115 - 1126 . .

Lu, J.; Yang, J. X.; Wang, J.; Lim, A.; Wang, S.; Loh, K. P . One-pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids . ACS Nano , 2009 . 8 2367 .

Li, Y.; Wang, Y.; Liu, L.; Han, L.; Xiang, F.; Zhou, Z . Crystallization improvement of poly(L-lactide) induced by functionalized multiwalled carbon nanotubes . J. Polym. Sci., Part B: Polym. Phys. , 2009 . 47 326 - 339 . DOI: 10.1002/polb.v47:3 http://doi.org/10.1002/polb.v47:3 .

Xu, J. Z.; Zhang, Z. J.; Xu, H.; Chen, J. B.; Ran, R.; Li, Z. M . Highly enhanced crystallization kinetics of poly(L-lactic acid) by poly(ethylene glycol) grafted graphene oxide simultaneously as heterogeneous nucleation agent and chain mobility promoter . Macromolecules , 2015 . 48 4891 - 4900 . DOI: 10.1021/acs.macromol.5b00462 http://doi.org/10.1021/acs.macromol.5b00462 .

Li, Y.; Wu, H.; Wang, Y.; Liu, L.; Han, L.; Wu, J.; Xiang, F . Synergistic effects of PEG and MWCNTs on crystallization behavior of PLLA . J. Polym. Sci., Part B: Polym. Phys. , 2010 . 48 520 - 528 . DOI: 10.1002/polb.v48:5 http://doi.org/10.1002/polb.v48:5 .

Androsch, R.; Iqbal, H. N.; Schick, C . Non-isothermal crystal nucleation of poly (L-lactic acid) . Polymer , 2015 . 81 151 - 158 . DOI: 10.1016/j.polymer.2015.11.006 http://doi.org/10.1016/j.polymer.2015.11.006 .

Brüster, B.; Montesinos, A.; Reumaux, P.; Pérez-Camargo, R. A.; Mugica, A.; Zubitur, M.; Addiego, F . Crystallization kinetics of polylactide: Reactive plasticization and reprocessing effects . Polym. Degrad. Stab. , 2018 . 148 56 - 66 . DOI: 10.1016/j.polymdegradstab.2018.01.009 http://doi.org/10.1016/j.polymdegradstab.2018.01.009 .

Hu, Y.; Xu, P.; Gui, H.; Yang, S.; Ding, Y . Effect of graphene modified by a long alkyl chain ionic liquid on crystallization kinetics behavior of poly(vinylidene fluoride) . RSC Adv. , 2015 . 112 92418 - 92427 . .

Chen, H. M.; Du, X. C.; Yang, A. S.; Yang, J. H.; Huang, T.; Zhang, N.; Zhang, C. L . Effect of graphene oxides on thermal degradation and crystallization behavior of poly(L-lactide) . RSC Adv. , 2014 . 7 3443 - 3456 . .

Wei, T.; Pang, S.; Xu, N.; Pan, L.; Zhang, Z.; Xu, R.; Lin, Q . Crystallization behavior and isothermal crystallization kinetics of PLLA blended with ionic liquid, 1-butyl-3-methylimidazolium dibutylphosphate . J. Appl. Polym. Sci. , 2015 . 132 41308 .

Schick, C . Differential scanning calorimetry (DSC) of semicrystalline polymers . Anal. Bioanal. Chem. , 2009 . 395 1589 - 1611 . DOI: 10.1007/s00216-009-3169-y http://doi.org/10.1007/s00216-009-3169-y .

Wu, D.; Cheng, Y.; Feng, S.; Yao, Z.; Zhang, M . Crystallization behavior of polylactide/graphene composites . Ind. Eng. Chem. Res. , 2013 . 52 6731 - 6739 . DOI: 10.1021/ie4004199 http://doi.org/10.1021/ie4004199 .

Xiao, H.; Lu, W.; Yeh, J. T . Effect of plasticizer on the crystallization behavior of poly(lactic acid) . J. Appl. Polym. Sci. , 2009 . 113 112 - 121 . DOI: 10.1002/app.v113:1 http://doi.org/10.1002/app.v113:1 .

Zhao, Y.; Qiu, Z.; Yang, W . Effect of functionalization of multiwalled nanotubes on the crystallization and hydrolytic degradation of biodegradable poly(L-lactide) . J. Phys. Chem. B , 2008 . 112 16461 - 16468 . DOI: 10.1021/jp805230e http://doi.org/10.1021/jp805230e .

Mijović, J.; Sy, J. W . Molecular dynamics during crystallization of poly(L-lactic acid) as studied by broad-band dielectric relaxation spectroscopy . Macromolecules , 2002 . 35 6370 - 6376 . DOI: 10.1021/ma0203647 http://doi.org/10.1021/ma0203647 .

Jeszka, J. K.; Pietrzak, L.; Pluta, M.; Boiteux, G . Dielectric properties of polylactides and their nanocomposites with montmorillonite . J. Non-Cryst. Solids , 2010 . 356 818 - 821 . DOI: 10.1016/j.jnoncrysol.2009.06.057 http://doi.org/10.1016/j.jnoncrysol.2009.06.057 .

Brás, A. R.; Viciosa, M. T.; Wang, Y.; Dionísio, M.; Mano, J. F . Crystallization of poly(L-lactic acid) probed with dielectric relaxation spectroscopy . Macromolecules , 2006 . 39 6513 - 6520 . DOI: 10.1021/ma061148r http://doi.org/10.1021/ma061148r .

Klonos, P.; Kripotou, S.; Kyritsis, A.; Papageorgiou, G. Z.; Bikiaris, D.; Gournis, D.; Pissis, P . Glass transition and segmental dynamics in poly(L-lactic acid)/graphene oxide nanocomposites . Thermochim. Acta , 2015 . 617 44 - 53 . DOI: 10.1016/j.tca.2015.08.020 http://doi.org/10.1016/j.tca.2015.08.020 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Investigation of Chain Folding and Traversing during Melt Crystallization of Poly(L-lactide) Based on Selective Alkali Hydrolysis of Its Amorphous Regions

The Effect of Polymer-Substrate Interaction on the Nucleation Property: Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Multifunctional Property Enhancement of 2-Acrylamido-2-methyl-1-propanesulfonic Acid/Acrylic Acid Hydrogels with Dual-ionic Liquid Functionalized Carbon Nanotubes

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature