Preparation and Characterization of Flexible, Transparent and Thermally Stable Aromatic Co-polyamides

José Antonio Tec-Sánchez; Andrés Iván Oliva Arias; Manuel Aguilar-Vega; Juan Valerio Cauich-Rodríguez; José Luis Santiago-García

doi:10.1007/s10118-019-2190-7

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Preparation and Characterization of Flexible, Transparent and Thermally Stable Aromatic Co-polyamides

ARTICLE | Updated：2021-02-18

- Preparation and Characterization of Flexible, Transparent and Thermally Stable Aromatic Co-polyamides
- Preparation and Characterization of Flexible, Transparent and Thermally Stable Aromatic Co-polyamides
- Chinese Journal of Polymer Science 2019年37卷第2期页码：136-141
- Affiliations：
  
  a.Unidad de Materiales, Centro de Investigación Científica de Yucatán A. C., Calle 43 No.130 x 32 y 34, Col. Chuburná de Hidalgo, C.P. 97205, Mérida, Yucatán, México
  b.Centro de Investigación y de Estudios Avanzados del IPN, Unidad Mérida, Departamento de Física Aplicada, Km. 6 Antigua Carretera a Progreso, AP 73-Cordemex, 97310 Mérida Yucatán, México
- Author bio：
  
  jvcr@cicy.mx
- Funds：
  
  The authors thankfully acknowledge the financial support from CONACYT-México (No. 248378). J. A. Tec-Sánchez thanks CONACYT-México for the fellowship 427467. This work was partially supported by the project “Fortalecimiento e internacionalización del doctorado en ciencias (Materiales Poliméricos) del CICY” FOMIX YUC 2014-C17-247046. The authors thank LANNBIO Cinvestav-Merida for the NMR measurements.
- DOI：10.1007/s10118-019-2190-7
  中图分类号：
- 收稿：2018-06-06，
  
  修回：2018-8-8，
  
  录用：2018-9-25，
  
  网络首发：2018-11-01，
  
  纸质出版：2019-02
- Accepted：
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Citation: Tec-Sánchez, J. A.; Oliva, A. I.; Aguilar-Vega, M.; Cauich-Rodríguez, J. V.; Santiago-García, J. L. Preparation and characterization of flexible, transparent and thermally stable aromatic co-polyamides. Chinese J. Polym. Sci. 2019, 37, 136–141

José Antonio Tec-Sánchez, Andrés Iván Oliva Arias, Manuel Aguilar-Vega, et al. Preparation and Characterization of Flexible, Transparent and Thermally Stable Aromatic Co-polyamides[J]. Chinese Journal of Polymer Science, 2019, 37(2): 136-141.
Citation: Tec-Sánchez, J. A.; Oliva, A. I.; Aguilar-Vega, M.; Cauich-Rodríguez, J. V.; Santiago-García, J. L. Preparation and characterization of flexible, transparent and thermally stable aromatic co-polyamides. Chinese J. Polym. Sci. 2019, 37, 136–141 DOI： 10.1007/s10118-019-2190-7.

José Antonio Tec-Sánchez, Andrés Iván Oliva Arias, Manuel Aguilar-Vega, et al. Preparation and Characterization of Flexible, Transparent and Thermally Stable Aromatic Co-polyamides[J]. Chinese Journal of Polymer Science, 2019, 37(2): 136-141. DOI： 10.1007/s10118-019-2190-7.

摘要

Abstract

Two aromatic co-polyamides were synthesized combining two diacid monomers containing bulky pendant groups

5-(9

10-dihydro-9

10-ethanoanthracene-11

12-dicarboximido)isophthalic acid (DEAIA) and 5-

tert

-butylisophthalic acid (TERT)

with 4

4′-(hexafluoroisopropylidene)dianiline (HFA) or 2

6-tetramethyl-1

4-phenylenediamine (Durene) by direct polycondensation. The structures of the obtained aromatic co-polyamides were confirmed by FTIR

Raman and

H-NMR. The co-copolyamide films

DHTH and DDTD

exhibited rms-roughness values between 0.94 and 1.60 nm

respectively. Moreover

they presented good thermal stability up to 300 °C. Young’s moduli of the co-polyamide films were between 4.1 and 4.3 GPa. X-ray diffraction results showed that the co-polyamide films were amorphous due to the incorporation of both bulky pendant groups

tert

-butyl and dibenzobarrelene. The combination of bulky pendant groups provided intrinsically transparent co-polyamide films with a transmittance higher than 88% in the range of 400−780 nm. Due to these outstanding film and optical properties

they are suggested to be flexible substrates in applications for solar cell and other portable electronic devices.

关键词

Keywords

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