Soluble Two-dimensional Supramolecular Organic Frameworks (SOFs): An Emerging Class of 2D Supramolecular Polymers with Internal Long-range Orders

Shu-Yan Jiang; Xin Zhao

doi:10.1007/s10118-019-2189-0

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Soluble Two-dimensional Supramolecular Organic Frameworks (SOFs): An Emerging Class of 2D Supramolecular Polymers with Internal Long-range Orders

REVIEW | Updated：2021-02-18

- Soluble Two-dimensional Supramolecular Organic Frameworks (SOFs): An Emerging Class of 2D Supramolecular Polymers with Internal Long-range Orders
- Soluble Two-dimensional Supramolecular Organic Frameworks (SOFs): An Emerging Class of 2D Supramolecular Polymers with Internal Long-range Orders
- Chinese Journal of Polymer Science 2019年37卷第1期页码：1-10
- Affiliations：
  
  CAS Key Laboratory of Synthetic and Self-assembly Chemistry for Organic Functional Molecules, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
- Author bio：
  
  xzhao@sioc.ac.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21472225, 21725404) and the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDAB20000000).
- DOI：10.1007/s10118-019-2189-0
  中图分类号：
- 收稿：2018-08-08，
  
  修回：2018-9-14，
  
  录用：2018-9-16，
  
  网络首发：2018-11-02，
  
  纸质出版：2019-01
- Accepted：
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Citation: Jiang, S. Y.; Zhao, X. Soluble two-dimensional supramolecular organic frameworks (SOFs): an emerging class of 2D supramolecular polymers with internal long-range orders. Chinese J. Polym. Sci. 2019, 37, 1–10

Shu-Yan Jiang, Xin Zhao. Soluble Two-dimensional Supramolecular Organic Frameworks (SOFs): An Emerging Class of 2D Supramolecular Polymers with Internal Long-range Orders[J]. Chinese Journal of Polymer Science, 2019, 37(1): 1-10.
Citation: Jiang, S. Y.; Zhao, X. Soluble two-dimensional supramolecular organic frameworks (SOFs): an emerging class of 2D supramolecular polymers with internal long-range orders. Chinese J. Polym. Sci. 2019, 37, 1–10 DOI： 10.1007/s10118-019-2189-0.

Shu-Yan Jiang, Xin Zhao. Soluble Two-dimensional Supramolecular Organic Frameworks (SOFs): An Emerging Class of 2D Supramolecular Polymers with Internal Long-range Orders[J]. Chinese Journal of Polymer Science, 2019, 37(1): 1-10. DOI： 10.1007/s10118-019-2189-0.

摘要

Abstract

Two-dimensional (2D) materials have been demonstrated to exhibit unique properties originating from its 2D nature. In recent years

the construction of 2D materials has become a topic of great interest. This article summarizes the recent advance of 2D supramolecular organic frameworks (SOFs) which are homogeneously constructed in solution phase through self-assembly of rationally designed building blocks. These 2D SOFs are soluble and still maintain stable network structures in solutions

which exhibit uniqueness not only in structures but also in properties. In this concise review

the SOFs-related background is briefly introduced firstly

followed by outlining the research progress of soluble 2D SOFs from the perspective of monomer design

assembly

and structural characterization. The article ends with a personal outlook on the future development of this new class of supramolecular polymers.

关键词

Keywords

references

Pedersen, C. J . Cyclic polyethers and their complexes with metal salts . J. Am. Chem. Soc. , 1967 . 89 7017 - 7036 . DOI: 10.1021/ja01002a035 http://doi.org/10.1021/ja01002a035 .

Lehn J. M. in Supramolecular Chemistry: Concepts and Perspectives . Wiley VCH, Weinheim, 2006 .

Fouquuey, C.; Lehn, J. M.; Levelut, A. M . Molecular recognition directed self-assembly of supramolecular liquid crystalline polymers from complementary chiral components . Adv. Mater. , 1990 . 2 254 - 257 . DOI: 10.1002/(ISSN)1521-4095 http://doi.org/10.1002/(ISSN)1521-4095 .

Aida, T.; Meijer, E. W.; Stupp, S. I. Functional supramolecular polymers. Science 2012 , 335 , 813−817.

Yang, L.; Tan, X.; Wang, Z.; Zhang, X . Supramolecular polymers: Historical development, preparation, characterization, and functions . Chem. Rev. , 2015 . 115 7196 - 7293 . DOI: 10.1021/cr500633b http://doi.org/10.1021/cr500633b .

Qu, D. H.; Wang, Q. C.; Zhang, Q. W.; Ma, X.; Tian, H . Photoresponsive host-guest functional systems . Chem. Rev. , 2015 . 115 7543 - 7588 . DOI: 10.1021/cr5006342 http://doi.org/10.1021/cr5006342 .

Guo, D. S.; Liu, Y . Calixarene-based supramolecular polymerization in solution . Chem. Soc. Rev. , 2012 . 41 5907 - 5921 . DOI: 10.1039/c2cs35075k http://doi.org/10.1039/c2cs35075k .

Xu, J. F.; Zhang, X . Study on supramolecular polymers in China: An overview and outlook . Acta Polymerica Sinica (in Chinese) , 2017 . 37 - 49 . DOI: 10.11777/j.issn1000-3304.2017.16262 http://doi.org/10.11777/j.issn1000-3304.2017.16262 .

Wei, P.; Yan, X.; Huang, F . Supramolecular polymers constructed by orthogonal self-assembly based on host-guest and metal-ligand interaction . Chem. Soc. Rev. , 2015 . 44 815 - 832 . DOI: 10.1039/C4CS00327F http://doi.org/10.1039/C4CS00327F .

Harada A. in Supramolecular Polymers Chemistry . Wiley VCH, Weinheim, 2012 .

Fan, Y.; Lin, F.; Xu, X. N.; Xu, J. Q.; Zhao, X . Construction of a rod-coil supramolecular copolymer through CB[8]-encapsulation-enhanced donor-acceptor interaction . Acta Polymerica Sinica (in Chinese) , 2017 . 80 - 85 . DOI: 10.11777/j.issn1000-3004.2017.16242 http://doi.org/10.11777/j.issn1000-3004.2017.16242 .

Yi, Z. J.; Wu, Z. Q.; Lin, F.; Qi, Q. Y.; Xu, X. N.; Zhao, X . A supramolecular bottlebrush polymer assembled on the basis of cucurbit[8]uril-encapsulation-enhanced donor-acceptor interaction . Chinese Chem. Lett. , 2017 . 28 1167 - 1171 . DOI: 10.1016/j.cclet.2017.03.029 http://doi.org/10.1016/j.cclet.2017.03.029 .

Chen, S. G.; Yu, Y.; Zhao, X.; Ma, Y.; Jiang, X. K.; Li, Z. T . Highly stable chiral (A) 6 -B supramolecular copolymers: A multivalency-based self-assembly process . J. Am. Chem. Soc. , 2011 . 133 11124 - 11127 . DOI: 10.1021/ja205059z http://doi.org/10.1021/ja205059z .

Zhou, C.; Tian, J.; Wang, J. L.; Zhang, D. W.; Zhao, X.; Liu, Y.; Li, Z. T . A three-dimensional cross-linking supramolecular polymer stabilized by the cooperative dimerization of the viologen radical cation . Polym. Chem. , 2014 . 5 341 - 345 . DOI: 10.1039/C3PY01006F http://doi.org/10.1039/C3PY01006F .

Ji, X. F.; Wang, P.; Wang, H.; Huang, F . A fluorescent supramolecular crosslinked polymer gel formed by crown ether based host-guest interactions and aggregation induced emission . Chinese J. Polym. Sci. , 2015 . 33 890 - 898 . DOI: 10.1007/s10118-015-1639-6 http://doi.org/10.1007/s10118-015-1639-6 .

Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. E.; Grigorieva, I. V.; Firsov, A. A . Electric field in atomically thin carbon films . Science , 2004 . 306 666 - 669 . DOI: 10.1126/science.1102896 http://doi.org/10.1126/science.1102896 .

Stock, N.; Biswas, S . Synthesis of metal-organic frameworks (MOFs): Routes to various MOF topologies, morphologies, and composites . Chem. Rev. , 2012 . 112 933 - 969 . DOI: 10.1021/cr200304e http://doi.org/10.1021/cr200304e .

Zhou, H. C.; Long, J. R.; Yaghi, O. M . Introduction to metal-organic frameworks . Chem. Rev. , 2012 . 112 673 - 674 . DOI: 10.1021/cr300014x http://doi.org/10.1021/cr300014x .

Ding, S. Y.; Wang, W . Covalent organic frameworks (COFs): From design to applications . Chem. Soc. Rev. , 2013 . 42 548 - 568 . DOI: 10.1039/C2CS35072F http://doi.org/10.1039/C2CS35072F .

Waller, P. J.; Gandara, F.; Yaghi, O. M . Chemistry of covalent organic frameworks . Acc. Chem. Res. , 2015 . 48 3053 - 3063 . DOI: 10.1021/acs.accounts.5b00369 http://doi.org/10.1021/acs.accounts.5b00369 .

Zhang, K. D.; Tian, J.; Hanifi, D.; Zhang, Y.; Sue, A. C.; Zhou, T. Y.; Zhang, L.; Zhao, X.; Liu, Y.; Li, Z. T . Toward a single-layer two-dimensional honeycomb supramolecular organic framework in water . J. Am. Chem. Soc. , 2013 . 135 17913 - 17918 . DOI: 10.1021/ja4086935 http://doi.org/10.1021/ja4086935 .

Wang, H.; Zhang, D. W.; Zhao, X.; Li, Z. T . Supramolecular organic frameworks (SOFs): Water-phase periodic porous self-assembled architectures . Acta Chimica Sinica (in Chinese) , 2015 . 73 471 - 479 . DOI: 10.6023/A14120880 http://doi.org/10.6023/A14120880 .

Tian, J.; Chen, L.; Zhang, D. W.; Liu, Y.; Li, Z. T . Supramolecular organic frameworks: Engineering periodicity in water through host–guest chemistry . Chem. Commun. , 2016 . 52 6351 - 6362 . DOI: 10.1039/C6CC02331B http://doi.org/10.1039/C6CC02331B .

Wang, H.; Zhang, D. W.; Li, Z. T . Supramolecular organic frameworks: porous periodic supramolecular polymers . Acta Polymerica Sinica (in Chinese) , 2017 . 19 - 26 . DOI: 10.11777/j.issn1000-3304.2017.16234 http://doi.org/10.11777/j.issn1000-3304.2017.16234 .

Zhang, Z. J.; Zhang, H. Y.; Chen, L.; Liu, Y . Interconversion between [5]pseudorotaxane and [3]pseudorotaxane by pasting/detaching two axle molecule . J. Org. Chem. , 2011 . 76 8270 - 8276 . DOI: 10.1021/jo201441r http://doi.org/10.1021/jo201441r .

Jeon, W. S.; Kim, H. J.; Lee, C.; Kim, K . Control of the stoichiometry in host-guest complexation by redox chemistry of guests: Inclusion of methylviologen in cucurbit[8]uril . Chem. Commun. , 2002 . 1828 - 1829 . .

Zhang, L.; Zhou, T. Y.; Tian, J.; Wang, H.; Zhang, D. W.; Zhao, X.; Liu, Y.; Li, Z. T . A two-dimensional single-layer supramolecular organic framework that is driven by viologen radical cation dimerization and further promoted by cucurbit[8]uril . Polym. Chem. , 2014 . 5 4715 - 4721 . DOI: 10.1039/C4PY00139G http://doi.org/10.1039/C4PY00139G .

Zhang, L.; Jia, Y.; Wang, H.; Zhang, D. W.; Zhang, Q.; Liu, Y.; Li, Z. T . pH-Responsive single-layer honeycomb supramolecular organic frameworks that exhibit antimicrobial activity . Polym. Chem. , 2016 . 7 1861 - 1865 . DOI: 10.1039/C5PY02054A http://doi.org/10.1039/C5PY02054A .

Pfeffermann, M.; Dong, R.; Graf, R.; Zajaczkowshi, W.; Gorelik, T.; Pisula, W.; Barita, A.; Müllen, K.; Feng, X . Free-standing monolayer two-dimensional supramolecular organic framework with good internal order . J. Am. Chem. Soc. , 2015 . 137 14525 - 14532 . DOI: 10.1021/jacs.5b09638 http://doi.org/10.1021/jacs.5b09638 .

Zhou, T. Y.; Qi, Q. Y.; Zhao, Q. L.; Fu, J.; Liu, Y.; Ma, Z.; Zhao, X . Highly thermally stable hydrogels derived from monolayered two-dimensional supramolecular polymers . Polym. Chem. , 2015 . 6 3018 - 3023 . DOI: 10.1039/C5PY00072F http://doi.org/10.1039/C5PY00072F .

Zhang, Y.; Zhou, T. Y.; Zhang, K. D.; Dai, J. L.; Zhu, Y. Y.; Zhao, X . Encapsulation enhanced dimerization of a series of 4-aryl- N -methylpyridinium derivatives in water: New building blocks for self-assembly in aqueous media . Chem. Asian J. , 2014 . 9 1530 - 1534 . DOI: 10.1002/asia.v9.6 http://doi.org/10.1002/asia.v9.6 .

Zhang, Y.; Zhan, T. G.; Zhou, T. Y.; Qi, Q. Y.; Xu, X. N.; Zhao, X . Fluorescence enhancement through the formation of a single-layer two-dimensional supramolecular organic framework and its application in highly selective recognition of picric acid . Chem. Commun. , 2016 . 52 7588 - 7591 . DOI: 10.1039/C6CC03631G http://doi.org/10.1039/C6CC03631G .

Zhang, S.; Yan, J. M.; Qin, A. J.; Sun, J. Z.; Tang, B. Z . The specific detection of Cu(II) using an AIE-active alanine ester . Chinese Chem. Lett. , 2013 . 24 668 - 672 . DOI: 10.1016/j.cclet.2013.05.014 http://doi.org/10.1016/j.cclet.2013.05.014 .

Lee, H. J.; Kim, H. J.; Lee, E. C.; Kim, J.; Park, S. Y . Highly luminescent and water-soluble two-dimensional supramolecular organic framework: All-organic photosensitizer template for visible-light-driven hydrogen evolution from water . Chem. Asian J. , 2018 . 13 390 - 394 . DOI: 10.1002/asia.v13.4 http://doi.org/10.1002/asia.v13.4 .

Zhang, X.; Nie, C. B.; Zhou, T. Y.; Qi, Q. Y.; Fu, J.; Wang, X. Z.; Dai, L.; Chen, Y.; Zhao, X . The construction of single-layer two-dimensional supramolecular organic frameworks in water through the self-assembly of rigid vertexes and flexible edges . Polym. Chem. , 2015 . 6 1923 - 1927 . DOI: 10.1039/C4PY01669F http://doi.org/10.1039/C4PY01669F .

Xu, S. Q.; Zhang, X.; Nie, C. B.; Pang, Z. F.; Xu, X. N.; Zhao, X . The construction of a two-dimensional supramolecular organic framework with parallelogram pores and stepwise fluorescence enhancement . Chem. Commun. , 2015 . 51 16417 - 16420 . DOI: 10.1039/C5CC05875A http://doi.org/10.1039/C5CC05875A .

Chen, X. M.; Zhang, Y. M.; Liu, Y . Adsorption of anionic dyes from water by thermostable supramolecular hydrogel . Supramol. Chem. , 2016 . 28 817 - 824 . DOI: 10.1080/10610278.2016.1158406 http://doi.org/10.1080/10610278.2016.1158406 .

Li, Y. W.; Dong, Y. H.; Miao, X. R.; Ren, Y. L.; Zhang, B. L.; Wang, P. P.; Yu, Y.; Li, B.; Isaacs, L.; Cao, L. P . Shape-controllable and fluorescent supramolecular organic frameworks through aqueous host-guest complexation . Angew. Chem. Int. Ed. , 2018 . 57 729 - 733 . DOI: 10.1002/anie.201710553 http://doi.org/10.1002/anie.201710553 .

Yue, L.; Wang, S.; Zhou, D.; Zhang, H.; Li, B.; Wu, L. X . Flexible single-layer ionic organic-inorganic frameworks towards precise nano-size separation . Nat. Commun. , 2016 . 7 10742 DOI: 10.1038/ncomms10742 http://doi.org/10.1038/ncomms10742 .

Zhou, T. Y.; Xu, S. Q.; Wen, Q.; Pang, Z. F.; Zhao, X . One-step construction of two different kinds of pores in a 2D covalent organic framework . J. Am. Chem. Soc. , 2014 . 136 15885 - 15888 . DOI: 10.1021/ja5092936 http://doi.org/10.1021/ja5092936 .

Pang, Z. F.; Xu, S. Q.; Zhou, T. Y.; Liang, R. R.; Zhan, T. G.; Zhao, X . Construction of covalent organic frameworks bearing three different kinds of pores through the heterostructural mixed linker strategy . J. Am. Chem. Soc. , 2016 . 138 4710 - 4713 . DOI: 10.1021/jacs.6b01244 http://doi.org/10.1021/jacs.6b01244 .

Qian, C.; Qi, Q. Y.; Jiang, G. F.; Cui, F. Z.; Tian, Y.; Zhao, X . Toward covalent organic frameworks bearing three different kinds of pores: the strategy for construction and COF-to-COF transformation via heterogeneous linker exchange . J. Am. Chem. Soc. , 2017 . 139 6736 - 6743 . DOI: 10.1021/jacs.7b02303 http://doi.org/10.1021/jacs.7b02303 .

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