Comparative Studies on Properties of Polymers with Bulky Side Groups Synthesized by Cyclopolymerization of <italic style="font-style: italic">α</italic>,<italic style="font-style: italic">ω</italic>-Dienes and <italic style="font-style: italic">α</italic>,<italic style="font-style: italic">ω</italic>-Diynes

Shao-Fei Song; Xiao-Yu Liu; Hao Zhang; Zhi-Sheng Fu; Jun-Ting Xu; Zhi-Qiang Fan

doi:10.1007/s10118-019-2183-6

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Comparative Studies on Properties of Polymers with Bulky Side Groups Synthesized by Cyclopolymerization of α,ω-Dienes and α,ω-Diynes

ARTICLE | Updated：2021-02-18

- Comparative Studies on Properties of Polymers with Bulky Side Groups Synthesized by Cyclopolymerization of α,ω-Dienes and α,ω-Diynes
- Comparative Studies on Properties of Polymers with Bulky Side Groups Synthesized by Cyclopolymerization of α,ω-Dienes and α,ω-Diynes
- Chinese Journal of Polymer Science 2019年37卷第2期页码：149-156
- Affiliations：
  
  Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  fanzq@zju.edu.cn
- Funds：
  
  Financial support by the National Natural Science Foundation of China (No. 51773178) is gratefully acknowledged.
- DOI：10.1007/s10118-019-2183-6
  中图分类号：
- 收稿：2018-07-18，
  
  修回：2018-8-11，
  
  录用：2018-8-19，
  
  网络首发：2018-09-10，
  
  纸质出版：2019-02
- Accepted：
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Citation: Song, S. F.; Liu, X. Y.; Zhang, H.; Fu, Z. S.; Xu, J. T.; Fan, Z. Q. Comparative studies on properties of polymers with bulky side groups synthesized by cyclopolymerization of α, ω-dienes and α, ω-diynes. Chinese J. Polym. Sci. 2019, 37, 149–156

Shao-Fei Song, Xiao-Yu Liu, Hao Zhang, et al. Comparative Studies on Properties of Polymers with Bulky Side Groups Synthesized by Cyclopolymerization of α,ω-Dienes and α,ω-Diynes[J]. Chinese Journal of Polymer Science, 2019, 37(2): 149-156. DOI: 10.1007/s10118-019-2183-6.
Citation: Song, S. F.; Liu, X. Y.; Zhang, H.; Fu, Z. S.; Xu, J. T.; Fan, Z. Q. Comparative studies on properties of polymers with bulky side groups synthesized by cyclopolymerization of α, ω-dienes and α, ω-diynes. Chinese J. Polym. Sci. 2019, 37, 149–156 DOI： 10.1007/s10118-019-2183-6.

Shao-Fei Song, Xiao-Yu Liu, Hao Zhang, et al. Comparative Studies on Properties of Polymers with Bulky Side Groups Synthesized by Cyclopolymerization of α,ω-Dienes and α,ω-Diynes[J]. Chinese Journal of Polymer Science, 2019, 37(2): 149-156. DOI: 10.1007/s10118-019-2183-6. DOI：

摘要

Abstract

Four polymers containing five-membered rings in the main chain

with or without conjugation structure along the backbone and with or without conjugated pendent groups

were designed and synthesized by metathesis cyclopolymerization of functionalized

-diynes

and cyclopolymerization of functionalized

-dienes catalyzed by the

-diimine palladium-based catalyst

respectively. High to moderate monomer conversions were achieved. Chain structure

molecular weight

and molecular weight distribution (MWD) of the cyclopolymerization products were characterized by

H-

C-NMR

FTIR

and GPC. The polymers showed regular main chain structures

moderately high molecular weight

and narrow MWD. Thermal properties and chain stacking behaviors of the polymers were investigated by differential scanning calorimetry (DSC) and X-ray diffraction (XRD) as well as atomic force microscopy (AFM). The polymer with conjugation system in both the backbone and the pendent groups exhibited UV-Vis absorption at a much longer wavelength than those with the conjugation only in the backbone or only in the side groups. The polymers with conjugated backbone need more space for chain stacking

and the conjugated backbone causes enhanced size of polymer particles assembled from solution. The results showed that primary microstructures of the polymer exerted significant influences on the physical properties.

关键词

Keywords

references

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DOI：10.1007/s10118-019-2183-6

摘要

Abstract

关键词

Keywords

references