Thermo-sensitive Microgels Supported Gold Nanoparticles as Temperature-mediated Catalyst

Xian-Jing Zhou; Hai-Peng Lu; Ling-Li Kong; Dong Zhang; Wei Zhang; Jing-Jing Nie; Jia-Yin Yuan; Bin-Yang Du; Xin-Ping Wang

doi:10.1007/s10118-019-2182-7

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Thermo-sensitive Microgels Supported Gold Nanoparticles as Temperature-mediated Catalyst

ARTICLE | Updated：2021-02-18

- Thermo-sensitive Microgels Supported Gold Nanoparticles as Temperature-mediated Catalyst
- Thermo-sensitive Microgels Supported Gold Nanoparticles as Temperature-mediated Catalyst
- Chinese Journal of Polymer Science 2019年37卷第3期页码：235-242
- Affiliations：
  
  a.Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, China
  b.Department of Chemistry, Zhejiang University, Hangzhou 310027, China
  c.Department of Materials and Environmental Chemistry, Stockholm University, Stockholm SE-10691, Sweden
  d.Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science & Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  duby@zju.edu.cn (B.Y.D.)
  wxinping@yahoo.com (X.P.W.)
- Funds：
  
  The authors thank the National Natural Science Foundation of China (No. 21704092) and Science Foundation of Zhejiang Sci-Tech University (No. 16062194-Y) for financial support.
- DOI：10.1007/s10118-019-2182-7
  中图分类号：
- 收稿：2018-07-22，
  
  修回：2018-8-13，
  
  录用：2018-8-14，
  
  网络首发：2018-08-30，
  
  纸质出版：2019-03
- Accepted：
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Citation: Zhou, X. J.; Lu, H. P.; Kong, L. L.; Zhang, D.; Zhang, W.; Nie, J. J.; Yuan, J. Y.; Du, B. Y.; Wang, X. P. Thermo-sensitive microgels supported gold nanoparticles as temperature-mediated catalyst. Chinese J. Polym. Sci. 2019, 37, 235–242

Xian-Jing Zhou, Hai-Peng Lu, Ling-Li Kong, et al. Thermo-sensitive Microgels Supported Gold Nanoparticles as Temperature-mediated Catalyst[J]. Chinese Journal of Polymer Science, 2019, 37(3): 235-242.
Citation: Zhou, X. J.; Lu, H. P.; Kong, L. L.; Zhang, D.; Zhang, W.; Nie, J. J.; Yuan, J. Y.; Du, B. Y.; Wang, X. P. Thermo-sensitive microgels supported gold nanoparticles as temperature-mediated catalyst. Chinese J. Polym. Sci. 2019, 37, 235–242 DOI： 10.1007/s10118-019-2182-7.

Xian-Jing Zhou, Hai-Peng Lu, Ling-Li Kong, et al. Thermo-sensitive Microgels Supported Gold Nanoparticles as Temperature-mediated Catalyst[J]. Chinese Journal of Polymer Science, 2019, 37(3): 235-242. DOI： 10.1007/s10118-019-2182-7.

摘要

Abstract

Microgels with a thermo-sensitive poly(

-isopropylacrylamide) (polyNIPAm) backbone and bis-imidazolium (VIM) ionic cross-links

denoted as poly(NIPAm-

-VIM)

were successfully prepared. The as-synthesized ionic microgels were converted to nanoreactors

denoted as Au@PNI MGs

upon generation and immobilization of gold nanoparticles (Au NPs) of 5–8 nm in size into poly(NIPAm-

-VIM). The content of Au NPs in microgels could be regulated by controlling the 1

6-dibromohexane/vinylimidazole molar ratio in the quaternization reaction. The microgel-based nanoreactors were morphologically spherical and uniform in size

and presented reversible thermo-sensitive behavior with volume phase transition temperatures (VPTTs) at 39–40 °C. The Au@PNI MGs were used for the reduction of 4-nitrophenol

of which the catalytic activity could be modulated by temperature.

关键词

Keywords

references

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