Covering the More Visible Region by Electrochemical Copolymerization of Carbazole and Benzothiadiazole Based Donor-Acceptor Type Monomers

Emine Gul Cansu-Ergun

doi:10.1007/s10118-019-2181-8

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Covering the More Visible Region by Electrochemical Copolymerization of Carbazole and Benzothiadiazole Based Donor-Acceptor Type Monomers

ARTICLE | Updated：2021-02-18

- Covering the More Visible Region by Electrochemical Copolymerization of Carbazole and Benzothiadiazole Based Donor-Acceptor Type Monomers
- Covering the More Visible Region by Electrochemical Copolymerization of Carbazole and Benzothiadiazole Based Donor-Acceptor Type Monomers
- Chinese Journal of Polymer Science 2019年37卷第1期页码：28-35
- Affiliations：
  
  Department of Electrical and Electronics Engineering, Baskent University, TR-06810 Ankara, Turkey
- Author bio：
  
  egulcansu@baskent.edu.tr
- Funds：
  
  I would like to thank and appreciate Prof. Dr. Ahmet Muhtar Onal (Department of Chemistry, Middle East Technical University, Turkey) for his academic guidance and support.
- DOI：10.1007/s10118-019-2181-8
  中图分类号：
- 收稿：2018-06-22，
  
  修回：2018-8-10，
  
  录用：2018-8-13，
  
  网络首发：2018-09-05，
  
  纸质出版：2019-01
- Accepted：
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Citation: Cansu-Ergun, E. G. Covering the more visible region by electrochemical copolymerization of carbazole and benzothiadiazole based donor-acceptor type monomers. Chinese J. Polym. Sci. 2019, 37, 28–35

Emine Gul Cansu-Ergun. Covering the More Visible Region by Electrochemical Copolymerization of Carbazole and Benzothiadiazole Based Donor-Acceptor Type Monomers[J]. Chinese Journal of Polymer Science, 2019, 37(1): 28-35.
Citation: Cansu-Ergun, E. G. Covering the more visible region by electrochemical copolymerization of carbazole and benzothiadiazole based donor-acceptor type monomers. Chinese J. Polym. Sci. 2019, 37, 28–35 DOI： 10.1007/s10118-019-2181-8.

Emine Gul Cansu-Ergun. Covering the More Visible Region by Electrochemical Copolymerization of Carbazole and Benzothiadiazole Based Donor-Acceptor Type Monomers[J]. Chinese Journal of Polymer Science, 2019, 37(1): 28-35. DOI： 10.1007/s10118-019-2181-8.

摘要

Abstract

An electrochromic copolymer film of 2-(3

3-dihexyl-3

4-dihydro-2

-thieno[3

][1

dioxepin-6-yl)-7-(3

3-dihexyl-3

4-dihydro-2

-thieno[3

][1

dioxepin-8-yl)-9

-carbazole (

) and 4

7-bis(thiophen-2-yl)benzo[

][1

thiadiazole (

) was prepared

via

electrochemical technique. The copolymerization was performed with one to one monomer feed ratio. Electrochemical and optical properties of the resulting copolymer film (

) and the homopolymer films of

and

(

and

) were investigated by using cyclic voltammetry and UV-Vis spectrometry techniques

and the corresponding results were compared. Incorporation of

and

into copolymer matrix was clearly observed on the resulting cyclic voltammograms and UV-Vis spectra.

covered the visible regions coming from both

and

and exhibited a neutral state darker color than those of homopolymers.

film was found to have a multichromic behavior

appearing as brown in its neutral state while changing its color upon oxidation to dark-gray (at about 0.3 V)

to blue (at about 0.6 V) and finally to grayish cyan (beyond 0.9 V)

with a corresponding optical band gap of 1.65 eV.

关键词

Keywords

references

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