CO<sub>2</sub>-responsive Polymeric Fluorescent Sensor with Ultrafast Response

Yun Wang; Meng Huo; Min Zeng; Lei Liu; Qi-Quan Ye; Xi Chen; Dan Li; Liao Peng; Jin-Ying Yuan

doi:10.1007/s10118-018-2167-y

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CO₂-responsive Polymeric Fluorescent Sensor with Ultrafast Response

ARTICLE | Updated：2021-02-18

- CO₂-responsive Polymeric Fluorescent Sensor with Ultrafast Response
- CO₂-responsive Polymeric Fluorescent Sensor with Ultrafast Response
- Chinese Journal of Polymer Science 2018年36卷第12期页码：1321-1327
- Affiliations：
  
  Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
- Author bio：
  
  yuanjy@mail.tsinghua.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51573086 and 21374058) and the Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University) (No. sklpme2014-4-26).
- DOI：10.1007/s10118-018-2167-y
  中图分类号：
- 收稿：2018-05-07，
  
  修回：2018-5-27，
  
  录用：2018-5-28，
  
  网络首发：2018-07-11，
  
  纸质出版：2018-12
- Accepted：
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Citation: Wang, Y.; Huo, M.; Zeng, M.; Liu, L.; Ye, Q. Q.; Chen, X.; Li, D.; Peng, L.; Yuan, J. Y. CO₂-responsive Polymeric Fluorescent Sensor with Ultrafast Response. Chinese J. Polym. Sci. 2018, 36(12), 1321–1327 DOI: 10.1007/s10118-018-2167-y.

Yun Wang, Meng Huo, Min Zeng, et al. CO₂-responsive Polymeric Fluorescent Sensor with Ultrafast Response[J]. Chinese Journal of Polymer Science, 2018, 36(12): 1321-1327. DOI: 10.1007/s10118-018-2167-y.
Citation: Wang, Y.; Huo, M.; Zeng, M.; Liu, L.; Ye, Q. Q.; Chen, X.; Li, D.; Peng, L.; Yuan, J. Y. CO₂-responsive Polymeric Fluorescent Sensor with Ultrafast Response. Chinese J. Polym. Sci. 2018, 36(12), 1321–1327 DOI: 10.1007/s10118-018-2167-y. DOI：

Yun Wang, Meng Huo, Min Zeng, et al. CO₂-responsive Polymeric Fluorescent Sensor with Ultrafast Response[J]. Chinese Journal of Polymer Science, 2018, 36(12): 1321-1327. DOI: 10.1007/s10118-018-2167-y. DOI：

摘要

Abstract

Response speed is one of the most important evaluation criteria for CO

sensors. In this work

we report an ultrafast CO

fluorescent sensor based on poly[oligo(ethylene glycol) methyl ether methacrylate]-

-poly[

-diethylaminoethyl methacrylate-

-4-(2-methylacryloyloxyethylamino)-7-nitro-2

3-benzoxadiazole] [POEGMA-

-P(DEAEMA-

-NBDMA)]

in which DEAEMA units act as the CO

-responsive segment and 4-nitrobenzo-2-oxa-1

3-diazole (NBD) is the chromophore. The micelles composed of this copolymer could disassemble in 2 s upon CO

bubbling

accompanying with enhanced fluorescence emission with bathochromic shift. Furthermore

the quantum yield of the NBD chromophore increases with both the CO

aeration time and the NBD content. Thus we attribute the fluorescent enhancement to the inhibition of the photo-induced electron transfer between unprotonated tertiary amine groups and NBD fluorophores. The sensor is durable although it is based on " soft” materials. These micellar sensors could be facilely recycled by alternative CO

/Ar purging for at least 5 times

indicating good reversibility.

关键词

Keywords

references

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CO2-responsive Polymeric Fluorescent Sensor with Ultrafast Response

CO2-responsive Polymeric Fluorescent Sensor with Ultrafast Response

DOI：10.1007/s10118-018-2167-y

摘要

Abstract

关键词

Keywords

references

CO₂-responsive Polymeric Fluorescent Sensor with Ultrafast Response

CO₂-responsive Polymeric Fluorescent Sensor with Ultrafast Response