Tough Poly(L-DOPA)-containing Double Network Hydrogel Beads with High Capacity of Dye Adsorption

Pei-Bin Zhang; An-Qi Tang; Zhang-Hui Wang; Jing-Yu Lu; Bao-Ku Zhu; Li-Ping Zhu

doi:10.1007/s10118-018-2163-2

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Tough Poly(L-DOPA)-containing Double Network Hydrogel Beads with High Capacity of Dye Adsorption

ARTICLE | Updated：2021-02-18

- Tough Poly(L-DOPA)-containing Double Network Hydrogel Beads with High Capacity of Dye Adsorption
- Tough Poly(L-DOPA)-containing Double Network Hydrogel Beads with High Capacity of Dye Adsorption
- Chinese Journal of Polymer Science 2018年36卷第11期页码：1251-1261
- Affiliations：
  
  Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  lpzhu@zju.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51573159 and 51273176) and the Fundamental Research Funds for the Central Universities (No. 2016QNA4032).
- DOI：10.1007/s10118-018-2163-2
  中图分类号：
- 收稿：2018-03-15，
  
  修回：2018-5-18，
  
  录用：2018-5-24，
  
  网络首发：2018-06-29，
  
  纸质出版：2018-11
- Accepted：
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Citation: Zhang, P. B.; Tang, A. Q.; Wang, Z. H.; Lu, J. Y.; Zhu, B. K.; Zhu, L. P. Tough Poly(L-DOPA)-containing Double Network Hydrogel Beads with High Capacity of Dye Adsorption. Chinese J. Polym. Sci. 2018, 36(11), 1251–1261.

Pei-Bin Zhang, An-Qi Tang, Zhang-Hui Wang, et al. Tough Poly(L-DOPA)-containing Double Network Hydrogel Beads with High Capacity of Dye Adsorption[J]. Chinese Journal of Polymer Science, 2018, 36(11): 1251-1261.
Citation: Zhang, P. B.; Tang, A. Q.; Wang, Z. H.; Lu, J. Y.; Zhu, B. K.; Zhu, L. P. Tough Poly(L-DOPA)-containing Double Network Hydrogel Beads with High Capacity of Dye Adsorption. Chinese J. Polym. Sci. 2018, 36(11), 1251–1261. DOI： 10.1007/s10118-018-2163-2.

Pei-Bin Zhang, An-Qi Tang, Zhang-Hui Wang, et al. Tough Poly(L-DOPA)-containing Double Network Hydrogel Beads with High Capacity of Dye Adsorption[J]. Chinese Journal of Polymer Science, 2018, 36(11): 1251-1261. DOI： 10.1007/s10118-018-2163-2.

摘要

Abstract

Developing a low-cost and well-recyclable adsorbent with high adsorption capacity is greatly desirable in dye wastewater treatment. Here

we demonstrate a kind of novel tough and reusable hydrogel beads with quite high capacity of dye adsorption

via

incorporating mussel-bioinspired poly(L-DOPA) (PDOPA) into alginate/poly(acrylamide) double network (DN) hydrogels. The synthesized PDOPA nanoaggregates were introduced into the DN hydrogels by simple one-pot mixing with the monomers prior to polymerization. The fabricated hydrogel beads exhibited high mechanical strength and good elastic recovery due to the interpenetrating Ca

-alginate and poly(acrylamide) networks. It was shown that the beads exhibited relatively high dye adsorption capacity compared to other adsorbents reported in literature

and the introduction of PDOPA with an appropriate amount raised the adsorption capacity. It is believed that the addition of PDOPA and the matrix of double network architecture contributed synergistically to the high adsorption capacity of hydrogel beads. Moreover

the desorption of dyes could be easily realized

via

rinsing in acidic water and ethanol solution. The hydrogel beads remained the high adsorption capacity even after 5 times of adsorption and desorption cycles. This tough and stable hydrogel with high adsorption capacity may have potential in treatment of dye wastewater released by textile dyeing industry.

关键词

Keywords

references

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