Humidity-responsive Bilayer Actuators Comprised of Porous and Nonporous Poly(acrylic acid)/Poly(allylamine hydrochloride) Films

Miao Zheng; Tang-Jie Long; Xiao-Ling Chen; Jun-Qi Sun

doi:10.1007/s10118-018-2162-3

Your Location：

Home >

Browse articles >

Humidity-responsive Bilayer Actuators Comprised of Porous and Nonporous Poly(acrylic acid)/Poly(allylamine hydrochloride) Films

ARTICLE | Updated：2021-02-18

- Humidity-responsive Bilayer Actuators Comprised of Porous and Nonporous Poly(acrylic acid)/Poly(allylamine hydrochloride) Films
- Humidity-responsive Bilayer Actuators Comprised of Porous and Nonporous Poly(acrylic acid)/Poly(allylamine hydrochloride) Films
- Chinese Journal of Polymer Science 2019年37卷第1期页码：52-58
- Affiliations：
  
  State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China
- Author bio：
  
  sun_junqi@jlu.edu.cn
- Funds：
  
  This work was financially supported by the National Basic Research Program (No. 2013CB834503) and the National Natural Science Foundation of China (No. 21225419).
- DOI：10.1007/s10118-018-2162-3
  中图分类号：
- 收稿：2018-04-22，
  
  修回：2018-5-14，
  
  录用：2018-5-22，
  
  网络首发：2018-06-21，
  
  纸质出版：2019-01
- Accepted：
Scan QR Code
Citation: Zheng, M; Long, T. J.; Chen, X. L.; Sun, J. Q. Humidity-responsive bilayer actuators comprised of porous and nonporous poly(acrylic acid)/poly(allylamine hydrochloride) films. Chinese J. Polym. Sci. 2019, 37, 52–58

Miao Zheng, Tang-Jie Long, Xiao-Ling Chen, et al. Humidity-responsive Bilayer Actuators Comprised of Porous and Nonporous Poly(acrylic acid)/Poly(allylamine hydrochloride) Films[J]. Chinese Journal of Polymer Science, 2019, 37(1): 52-58.
Citation: Zheng, M; Long, T. J.; Chen, X. L.; Sun, J. Q. Humidity-responsive bilayer actuators comprised of porous and nonporous poly(acrylic acid)/poly(allylamine hydrochloride) films. Chinese J. Polym. Sci. 2019, 37, 52–58 DOI： 10.1007/s10118-018-2162-3.

Miao Zheng, Tang-Jie Long, Xiao-Ling Chen, et al. Humidity-responsive Bilayer Actuators Comprised of Porous and Nonporous Poly(acrylic acid)/Poly(allylamine hydrochloride) Films[J]. Chinese Journal of Polymer Science, 2019, 37(1): 52-58. DOI： 10.1007/s10118-018-2162-3.

摘要

Abstract

Bilayer humidity-responsive actuators are generally composed of actuating and supporting layers of different materials with largely different wettability. Such kinds of bilayer actuators suffer from low adhesive force between the two layers during usage. This study demonstrates the preparation of humidity-responsive bilayer actuators that have the same materials in the actuating and supporting layers to avoid the adhesive issue. The bilayer actuators consist of a porous poly(acrylic acid) (PAA)/poly(allylamine hydrochloride) (PAH) layer and a nonporous PAA/PAH layer that are fabricated by exponentially layer-by-layer assembly method. At a high/low relative humidity (RH)

the nonporous PAA/PAH layer can efficiently expand/shrink by absorbing/desorbing water while the volume expansion/shrinkage of the porous PAA/PAH layer in an environment with changed humidity is significantly suppressed by the micrometer-sized pores. The largely different expansion/shrinkage of the nonporous and porous PAA/PAH layers when subjected to humidity changes enables rapid and reversible rolling/unrolling motions of the bilayer actuator. The bilayer actuator shows a faster rolling speed and a larger bending curvature when subjected to a larger humidity increase.

关键词

Keywords

references

Zhao, Z. G.; Xu, Y. C.; Fang, R. C.; Liu, M. J . Bioinspired adaptive gel materials with synergistic heterostructures . Chinese J. Polym. Sci. , 2018 . 26 ( 6 ): 683 - 696 . .

Uh, K.; Yoon, B.; Lee, C. W.; Kim, J. M . An electrolyte-free conducting polymer actuator that displays electrothermal bending and flapping wing motions under a magnetic field . ACS Appl. Mater. Interfaces , 2016 . 8 ( 2 ): 1289 - 1296 . DOI: 10.1021/acsami.5b09981 http://doi.org/10.1021/acsami.5b09981 .

Chen, N.; Hu, Y.; Zhao, Y.; Qu, L . Progress in controllable preparation and electrochemical applications of graphene/poly(pyrrole) composites . Acta Polymerica Sinica (in Chinese) , 2014 . ( 6 ): 752 - 760 . .

Zhang, L.; Naumov, P . Light- and humidity-induced motion of an acidochromic film . Angew. Chem. Int. Ed. , 2015 . 54 ( 30 ): 8642 - 8647 . DOI: 10.1002/anie.201504153 http://doi.org/10.1002/anie.201504153 .

Sattar, R.; Kausar, A.; Siddiq, M . Thermal, mechanical and electrical studies of novel shape memory polyurethane/ polyaniline blends . Chinese J. Polym. Sci. , 2015 . 33 ( 9 ): 1313 - 1324 . DOI: 10.1007/s10118-015-1680-5 http://doi.org/10.1007/s10118-015-1680-5 .

Liao, J. X.; Huang, J. H.; Wang, T.; Sun, W. W.; Tong, Z . Rapid shape memory and pH-modulated spontaneous actuation of dopamine containing hydrogels . Chinese J. Polym. Sci. , 2017 . 35 ( 10 ): 1297 - 1306 . DOI: 10.1007/s10118-017-1991-9 http://doi.org/10.1007/s10118-017-1991-9 .

Ma, M.; Guo, L.; Anderson, D. G.; Langer, R . Bio-inspired polymer composite actuator and generator driven by water gradients . Science , 2013 . 339 ( 6116 ): 186 - 189 . DOI: 10.1126/science.1230262 http://doi.org/10.1126/science.1230262 .

Liu, J. C.; Shang, Y. Y.; Zhang, D. J.; Xie, Z.; Hu, R. X.; Wang, J. X . Single-material solvent-sensitive fluorescent actuator from carbon dots inverse opals based on gradient dewetting . Chinese J. Polym. Sci. , 2017 . 35 ( 9 ): 1043 - 1050 . DOI: 10.1007/s10118-017-1981-y http://doi.org/10.1007/s10118-017-1981-y .

Islam, M. R.; Li, X.; Smyth, K.; Serpe, M. J . Polymer-based muscle expansion and contraction . Angew. Chem. Int. Ed. , 2013 . 52 ( 39 ): 10330 - 10333 . DOI: 10.1002/anie.201303475 http://doi.org/10.1002/anie.201303475 .

Chen, X.; Goodnight, D.; Gao, Z.; Cavusoglu, A. H.; Sabharwal, N.; DeLay, M.; Driks, A.; Sahin, O . Scaling up nanoscale water-driven energy conversion into evaporation-driven engines and generators . Nat. Commun. , 2015 . 6 7346 - 7352 . DOI: 10.1038/ncomms8346 http://doi.org/10.1038/ncomms8346 .

Keplinger, C.; Sun, J. Y.; Foo, C. C.; Rothemund, P.; Whitesides, G. M.; Suo, Z . Stretchable, transparent, ionic conductors . Science , 2013 . 341 ( 6149 ): 984 - 987 . DOI: 10.1126/science.1240228 http://doi.org/10.1126/science.1240228 .

Zhu, C. H.; Lu, Y.; Peng, J.; Chen, J. F.; Yu, S. H . Photothermally sensitive poly( n -isopropylacrylamide)/graphene oxide nanocomposite hydrogels as remote light-controlled liquid microvalves . Adv. Funct. Mater. , 2012 . 22 ( 19 ): 4017 - 4022 . DOI: 10.1002/adfm.v22.19 http://doi.org/10.1002/adfm.v22.19 .

Feinberg, A. W.; Feigel, A.; Shevkoplyas, S. S.; Sheehy, S.; Whitesides, G. M.; Parker, K. K . Muscular thin films for building actuators and powering devices . Science , 2007 . 317 ( 5843 ): 1366 - 1370 . DOI: 10.1126/science.1146885 http://doi.org/10.1126/science.1146885 .

Cheng, H.; Liu, J.; Zhao, Y.; Hu, C.; Zhang, Z.; Chen, N.; Jiang, L.; Qu, L . Graphene fibers with predetermined deformation as moisture-triggered actuators and robots . Angew. Chem. Int. Ed. , 2013 . 52 ( 40 ): 10482 - 10486 . DOI: 10.1002/anie.201304358 http://doi.org/10.1002/anie.201304358 .

Lee, S. W.; Prosser, J. H.; Purohit, P. K.; Lee, D . Bioinspired hygromorphic actuator exhibiting controlled locomotion . ACS Macro Lett. , 2013 . 2 ( 11 ): 960 - 965 . DOI: 10.1021/mz400439a http://doi.org/10.1021/mz400439a .

Yamada, M.; Kondo, M.; Mamiya, J.; Yu, Y.; Kinoshita, M.; Barrett, C. J.; Ikeda, T . Photomobile polymer materials: Towards light-driven plastic motors . Angew. Chem. Int. Ed. , 2008 . 47 ( 27 ): 4986 - 4988 . DOI: 10.1002/anie.v47:27 http://doi.org/10.1002/anie.v47:27 .

Mu, J.; Hou, C.; Zhu, B.; Wang, H.; Li, Y.; Zhang, Q . A multi-responsive water-driven actuator with instant and powerful performance for versatile applications . Sci. Rep. , 2015 . 5 9503 - 9509 . DOI: 10.1038/srep09503 http://doi.org/10.1038/srep09503 .

Li, M. H.; Keller, P.; Li, B.; Wang, X.; Brunet, M . Light-driven side-on nematic elastomer actuators . Adv. Mater. , 2003 . 15 ( 7-8 ): 569 - 572 . .

Yu, Y.; Maeda, T.; Mamiya, J.; Ikeda, T . Photomechanical effects of ferroelectric liquid-crystalline elastomers containing azobenzene chromophores . Angew. Chem. Int. Ed. , 2007 . 46 ( 6 ): 881 - 883 . DOI: 10.1002/(ISSN)1521-3773 http://doi.org/10.1002/(ISSN)1521-3773 .

Camacho-Lopez, M.; Finkelmann, H.; Palffy-Muhoray, P.; Shelley, M . Fast liquid-crystal elastomer swims into the dark . Nat. Mater. , 2004 . 3 ( 5 ): 307 - 310 . DOI: 10.1038/nmat1118 http://doi.org/10.1038/nmat1118 .

Ma, Y.; Zhang, Y.; Wu, B.; Sun, W.; Li, Z.; Sun, J . Polyelectrolyte multilayer films for building energetic walking devices . Angew. Chem. Int. Ed. , 2011 . 50 ( 28 ): 6254 - 6257 . DOI: 10.1002/anie.201101054 http://doi.org/10.1002/anie.201101054 .

Ma, Y.; Sun, J . Humido- and thermo-responsive free-standing films mimicking the petals of the morning glory flower . Chem. Mater. , 2009 . 21 ( 5 ): 898 - 902 . DOI: 10.1021/cm8031708 http://doi.org/10.1021/cm8031708 .

Chen, X.; Sun, J . Fabrication of macroporous films with closed honeycomb-like pores from exponentially growing layer-by-layer assembled polyelectrolyte multilayers . Chem. Asian J. , 2014 . 9 ( 8 ): 2063 - 2067 . DOI: 10.1002/asia.v9.8 http://doi.org/10.1002/asia.v9.8 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Stable Integration of Hydrophobic Silica Aerogels into Rubber Latex via Poly(vinyl alcohol)-assisted Aqueous Processing for Thermal Insulating Composites

Mechanically Robust and Degradable Poly(urethane-urea) Plastics Derived from Tannic Acid and Castor Oil for Enhanced Fruit Preservation

Robust and Self-healable Antibiofilm Multilayer Coatings

Coalescence Suppression in Flowing Polymer Blends Using Silica Rods with Different Surface Chemistries

Manipulating Hierarchical Aggregation Structure via Film-forming Kinetics Enables Organic Photovoltaics over 20% Efficiency