The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate-<italic style="font-style: italic">co</italic>-3-hydroxyvalerate) by Octavinyloctasilasesquioxane

Heng-Xue Xiang; Fatemeh Zabihi; Xu-Zhen Zhang; Mei-Fang Zhu

doi:10.1007/s10118-018-2157-0

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The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane

ARTICLE | Updated：2021-02-18

- The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane
- The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane
- Chinese Journal of Polymer Science 2018年36卷第12期页码：1353-1360
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.The Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, College of Materials and Textile, Zhejiang Sci-Tech University, Hangzhou 310018, China
- Author bio：
  
  zhumf@dhu.edu.cn
- Funds：
  
  The authors gratefully acknowledge the support of the National Natural Science Foundation of China (No. 51603033), the Fundamental Research Funds for the Central Universities (Nos. 2232018A3-01 and 2232018D3-03), the Program for Innovative Research Team in University of Ministry of Education of China (No. IRT16R13) and the Open Foundation of Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-Tech University), Education Ministry of China (No. 2017001).
- DOI：10.1007/s10118-018-2157-0
  中图分类号：
- 收稿：2018-03-10，
  
  修回：2018-4-10，
  
  录用：2018-5-10，
  
  网络首发：2018-06-11，
  
  纸质出版：2018-12
- Accepted：
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Citation: Xiang, H. X.; Zabihi, F.; Zhang, X. Z.; Zhu, M. F. The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate- co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane. Chinese J. Polym. Sci. 2018, 36(12), 1353–1360

Heng-Xue Xiang, Fatemeh Zabihi, Xu-Zhen Zhang, et al. The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane[J]. Chinese Journal of Polymer Science, 2018, 36(12): 1353-1360. DOI: 10.1007/s10118-018-2157-0.
Citation: Xiang, H. X.; Zabihi, F.; Zhang, X. Z.; Zhu, M. F. The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate- co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane. Chinese J. Polym. Sci. 2018, 36(12), 1353–1360 DOI： 10.1007/s10118-018-2157-0.

Heng-Xue Xiang, Fatemeh Zabihi, Xu-Zhen Zhang, et al. The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane[J]. Chinese Journal of Polymer Science, 2018, 36(12): 1353-1360. DOI: 10.1007/s10118-018-2157-0. DOI：

摘要

Abstract

A series of cross-linked poly(3-hydroxybutyrate-

-3-hydroxyvalerate)/octavinyloctasilasesquioxane (PHBV/OVS) composites were obtained by a simple melt reactive processing technique. Dicumyl peroxide (DCP) and OVS were employed as a free radical initiator and a cross-linking agent

respectively. The chemical structure of these produced composites were identified by

Si-nuclear magnetic resonance spectroscopy (

Si-NMR) and Fourier transform infrared spectroscopy (FTIR). The melting behavior

non-isothermal crystallization

spherulite morphology and thermal stability property of PHBV/OVS composites were also investigated. The nucleation behaviors and crystallization rate of PHBV/OVS were significantly enhanced with the formation of cross-linked networks with different side-chains and cross-linking points. The red shift of crystalline peak temperature with addition of a small amount of OVS content evidenced the higher crystalline ability compared with the neat PHBV. However there was a threshold content

beyond which the crystallization rate weakened again. Additionally

the cross-linked structure of PHBV/OVS composites could be adjusted by changing the amount of OVS.

关键词

Keywords

references

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The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane

DOI：10.1007/s10118-018-2157-0

摘要

Abstract

关键词

Keywords

references