Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate-<italic style="font-style: italic">b</italic>-styrene) by ATRP

Guang-Cheng Huang; Sheng-Xiang Ji

doi:10.1007/s10118-018-2139-2

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Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate-b-styrene) by ATRP

ARTICLE | Updated：2021-02-18

- Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate-b-styrene) by ATRP
- Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate-b-styrene) by ATRP
- Chinese Journal of Polymer Science 2018年36卷第11期页码：1217-1224
- Affiliations：
  
  a.Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  sji@ciac.ac.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51173181 and 51373166), “The Hundred Talents Program” from the Chinese Academy of Sciences, and Department of Science and Technology of Jilin Province (No. 20160414032GH), China. The authors also thank Shanghai Synchrotron Radiation Facility for providing the beamline (BL16B1).
- DOI：10.1007/s10118-018-2139-2
  中图分类号：
- 收稿：2018-03-02，
  
  修回：2018-3-27，
  
  录用：2018-3-30，
  
  网络首发：2018-04-24，
  
  纸质出版：2018-11
- Accepted：
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Citation: Huang, G. C.; Ji, S. X. Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate- b-styrene) by ATRP. Chinese J. Polym. Sci. 2018, 36(11), 1217–1224.

Guang-Cheng Huang, Sheng-Xiang Ji. Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate-b-styrene) by ATRP[J]. Chinese Journal of Polymer Science, 2018, 36(11): 1217-1224. DOI: 10.1007/s10118-018-2139-2.
Citation: Huang, G. C.; Ji, S. X. Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate- b-styrene) by ATRP. Chinese J. Polym. Sci. 2018, 36(11), 1217–1224. DOI： 10.1007/s10118-018-2139-2.

Guang-Cheng Huang, Sheng-Xiang Ji. Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate-b-styrene) by ATRP[J]. Chinese Journal of Polymer Science, 2018, 36(11): 1217-1224. DOI: 10.1007/s10118-018-2139-2. DOI：

摘要

Abstract

Poly(methyl methacrylate-

-styrene) (PMMA-

-PS) block copolymers are synthesized by two consecutive ATRPs and fractionated into four fractions. The halogen chain end fidelity (CEF) in PMMA-

-PS is quantified based on the analysis of each fraction. Compared to ethyl 2-phenyl-2-bromoacetate/CuBr/2

2′-bipyridine (EPBA/CuBr/bpy) and CuBr/

N′

N″

-pentamethyldiethylene-triamine (CuBr/PMDETA) catalysts

PMMA-

-PS synthesized using

-toluenesulfonyl chloride/CuCl/bpy (TsCl/CuCl/bpy) and CuCl/PMDETA catalysts has a higher halogen CEF and a better control on molecular weight.

关键词

Keywords

references

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Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate-b-styrene) by ATRP

Effect of Halogen Chain End Fidelity on the Synthesis of Poly(methyl methacrylate-b-styrene) by ATRP

DOI：10.1007/s10118-018-2139-2

摘要

Abstract

关键词

Keywords

references