Preparation of Polylactide/Poly(ether)urethane Blends with Excellent Electro-actuated Shape Memory via Incorporating Carbon Black and Carbon Nanotubes Hybrids Fillers

Yuan Wei; Rui Huang; Peng Dong; Xiao-Dong Qi; Qiang Fu

doi:10.1007/s10118-018-2138-3

Your Location：

Home >

Browse articles >

Preparation of Polylactide/Poly(ether)urethane Blends with Excellent Electro-actuated Shape Memory via Incorporating Carbon Black and Carbon Nanotubes Hybrids Fillers

ARTICLE | Updated：2021-02-18

- Preparation of Polylactide/Poly(ether)urethane Blends with Excellent Electro-actuated Shape Memory via Incorporating Carbon Black and Carbon Nanotubes Hybrids Fillers
- Preparation of Polylactide/Poly(ether)urethane Blends with Excellent Electro-actuated Shape Memory via Incorporating Carbon Black and Carbon Nanotubes Hybrids Fillers
- Chinese Journal of Polymer Science 2018年36卷第10期页码：1175-1186
- Affiliations：
  
  College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  qxdjianhu@163.com (X.D.Q.)
  qiangfu@scu.edu.cn (Q.F.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51421061 and 51210005).
- DOI：10.1007/s10118-018-2138-3
  中图分类号：
- 收稿：2017-12-27，
  
  修回：2018-3-6，
  
  录用：2018-3-30，
  
  网络首发：2018-04-28，
  
  纸质出版：2018-10
- Accepted：
Scan QR Code
Citation: Wei, Y.; Huang, R.; Dong, P.; Qi, X. D.; Fu, Q. Preparation of Polylactide/Poly(ether)urethane Blends with Excellent Electro-actuated Shape Memory via Incorporating Carbon Black and Carbon Nanotubes Hybrids Fillers. Chinese J. Polym. Sci. 2018, 36(10), 1175–1186.

Yuan Wei, Rui Huang, Peng Dong, et al. Preparation of Polylactide/Poly(ether)urethane Blends with Excellent Electro-actuated Shape Memory via Incorporating Carbon Black and Carbon Nanotubes Hybrids Fillers[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1175-1186.
Citation: Wei, Y.; Huang, R.; Dong, P.; Qi, X. D.; Fu, Q. Preparation of Polylactide/Poly(ether)urethane Blends with Excellent Electro-actuated Shape Memory via Incorporating Carbon Black and Carbon Nanotubes Hybrids Fillers. Chinese J. Polym. Sci. 2018, 36(10), 1175–1186. DOI： 10.1007/s10118-018-2138-3.

Yuan Wei, Rui Huang, Peng Dong, et al. Preparation of Polylactide/Poly(ether)urethane Blends with Excellent Electro-actuated Shape Memory via Incorporating Carbon Black and Carbon Nanotubes Hybrids Fillers[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1175-1186. DOI： 10.1007/s10118-018-2138-3.

摘要

Abstract

In this work

hybrid conductive fillers of carbon black (CB) and carbon nanotubes (CNTs) were introduced into polylactide (PLA)/thermoplastic poly(ether)urethane (TPU) blend (70/30 by weight) to tune the phase morphology and realize rapid electrically actuated shape memory effect (SME). Particularly

the dispersion of conductive fillers

the phase morphology

the electrical conductivities and the shape memory properties of the composites containing CB or CB/CNTs were comparatively investigated. The results suggested that both CB and CNTs were selectively localized in TPU phase

and induced the morphological change from the sea-island structure to the co-continuous structure. The presence of CNTs resulted in a denser CB/CNTs network

which enhanced the continuity of TPU phase. Because the formed continuous TPU phase provided stronger recovery driving force

the PLA/TPU/CB/CNTs composites showed better shape recovery properties compared with the PLA/TPU/CB composites at the same CB content. Moreover

the CB and CNTs exerted a synergistic effect on enhancing the electrical conductivities of the composites. As a result

the prepared composites exhibited excellent electrically actuated SME and the shape recovery speed was also greatly enhanced. This work demonstrated a promising strategy to achieve rapid electrically actuated SME

via

the addition of hybrid nanoparticles with self-networking ability in binary PLA/TPU blends over a much larger composition range.

关键词

Keywords

references

Lendlein, A.; Kelch, S . Shape-memory polymers . Angew. Chem. Int. Ed. , 2002 . 41 ( 12 ): 2034 DOI: 10.1002/1521-3773(20020617)41:12<2034::AID-ANIE2034>3.0.CO;2-M http://doi.org/10.1002/1521-3773(20020617)41:12<2034::AID-ANIE2034>3.0.CO;2-M .

Hu, J. L.; Zhu, Y.; Huang, H. H.; Lu, J . Recent advances in shape-memory polymers, structure; mechanism; functionality; modeling and applications . Prog. Polym. Sci. , 2012 . 37 ( 12 ): 1720 - 1763 . DOI: 10.1016/j.progpolymsci.2012.06.001 http://doi.org/10.1016/j.progpolymsci.2012.06.001 .

Zhao, Q.; Qi, H. J.; Xie, T . Recent progress in shape memory polymer, new behavior; enabling materials; and mechanistic understanding . Prog. Polym. Sci. , 2015 . 49-50 79 - 120 . DOI: 10.1016/j.progpolymsci.2015.04.001 http://doi.org/10.1016/j.progpolymsci.2015.04.001 .

Xie, T . Recent advances in polymer shape memory . Polymer , 2011 . 52 ( 22 ): 4985 - 5000 . DOI: 10.1016/j.polymer.2011.08.003 http://doi.org/10.1016/j.polymer.2011.08.003 .

Liu, Y. J.; Lv, H. B.; Lan, X.; Leng, J.; Du, S. Y . Review of electro-active shape-memory polymer composite . Compos. Sci. Technol. , 2009 . 69 ( 13 ): 2064 - 2068 . DOI: 10.1016/j.compscitech.2008.08.016 http://doi.org/10.1016/j.compscitech.2008.08.016 .

Tang, Z. H.; Sun, D. Q.; Yang, D.; Guo, B. C.; Zhang, L. Q.; Jia, D. M . Vapor grown carbon nanofiber reinforced bio-based polyester for electroactive shape memory performance . Compos. Sci. Technol. , 2013 . 75 15 - 21 . DOI: 10.1016/j.compscitech.2012.11.019 http://doi.org/10.1016/j.compscitech.2012.11.019 .

Zhang, Z. X.; Wang, W. Y.; Yang, J. H.; Zhang, N.; Huang, T.; Wang, Y . Excellent electroactive shape memory performance of EVA/PCL/CNT blend composites with selectively localized CNTs . J. Phys. Chem. C , 2016 . 120 ( 40 ): 22793 - 22802 . DOI: 10.1021/acs.jpcc.6b06345 http://doi.org/10.1021/acs.jpcc.6b06345 .

Xiao, Y.; Zhou, S.; Wang, L.; Gong T . Electro-active shape memory properties of poly(epsilon-caprolactone)/ functionalized multiwalled carbon nanotube nanocomposite . ACS Appl. Mater. Interfaces , 2012 . 2 ( 12 ): 3506 - 3514 . .

Leng, J. S.; Huang, W. M.; Lan, X.; Liu, Y. J.; Du, S. Y . Significantly reducing electrical resistivity by forming conductive Ni chains in a polyurethane shape-memory polymer/carbon-black composite . Appl. Phys. Lett. , 2008 . 92 ( 20 ): 204101 DOI: 10.1063/1.2931049 http://doi.org/10.1063/1.2931049 .

Yu, K.; Zhang, Z. C.; Liu, Y. J.; Leng J. S . Carbon nanotube chains in a shape memory polymer/carbon black composite, to significantly reduce the electrical resistivity . Appl. Phys. Lett. , 2011 . 98 ( 7 ): 074102 DOI: 10.1063/1.3556621 http://doi.org/10.1063/1.3556621 .

Wang, X.; Zhao, J.; Chen, M.; Ma, L.; Zhao, X.; Dang, Z. M . Improved self-healing of polyethylene/carbon black nanocomposites by their shape memory effect . J. Phys. Chem. B , 2013 . 117 ( 5 ): 1467 - 1474 . DOI: 10.1021/jp3098796 http://doi.org/10.1021/jp3098796 .

Wang, X.; Sparkman, J.; Gou J. H . Electrical actuation and shape memory behavior of polyurethane composites incorporated with printed carbon nanotube layers . Compos. Sci. Technol. , 2017 . 141 8 - 15 . DOI: 10.1016/j.compscitech.2017.01.002 http://doi.org/10.1016/j.compscitech.2017.01.002 .

Wang, K.; Zhu, G. M.; Yan, X. G.; Ren, F.; Cui, X. P . Electroactive shape memory cyanate/polybutadiene epoxy composites filled with carbon black . Chinese J. Polym. Sci. , 2016 . 34 ( 4 ): 466 - 474 . DOI: 10.1007/s10118-016-1766-8 http://doi.org/10.1007/s10118-016-1766-8 .

Guo, Y. L.; Zhang, R. Z.; Wu, K.; Chen, F.; Fu, Q . Preparation of nylon MXD6/EG/CNTs ternary composites with excellent thermal conductivity and electromagnetic interference shielding effectiveness . Chinese J. Polym. Sci. , 2017 . 35 ( 12 ): 1497 - 1507 . DOI: 10.1007/s10118-017-1985-7 http://doi.org/10.1007/s10118-017-1985-7 .

Meng, H.; Li, G. Q . A review of stimuli-responsive shape memory polymer composites . Polymer , 2013 . 54 ( 9 ): 2199 - 2221 . DOI: 10.1016/j.polymer.2013.02.023 http://doi.org/10.1016/j.polymer.2013.02.023 .

Meng, Q.; Hu, J . A review of shape memory polymer composites and blends . Compos. Part A Appl. Sci. Manuf. , 2009 . 40 ( 11 ): 1661 - 1672 . DOI: 10.1016/j.compositesa.2009.08.011 http://doi.org/10.1016/j.compositesa.2009.08.011 .

You, J. C.; Dong, W. Y.; Zhao, L. P.; Cao, X. J.; Qiu, J. S.; Sheng, W. J.; Li, Y. J . Crystal orientation behavior and shape-memory performance of poly(vinylidene fluoride)/acrylic copolymer blends . J. Phys. Chem. B , 2012 . 116 ( 4 ): 1256 - 1264 . DOI: 10.1021/jp209116u http://doi.org/10.1021/jp209116u .

You, J. C.; Fu, H.; Dong, W. Y.; Zhao, L. P.; Cao, X. J.; Li, Y. J . Shape memory performance of thermoplastic polyvinylidene fluoride/acrylic copolymer blends physically cross-linked by tiny crystals . ACS Appl. Mater. Interfaces , 2012 . 4 ( 9 ): 4825 - 4831 . DOI: 10.1021/am301161s http://doi.org/10.1021/am301161s .

Zhang, H.; Wang, H. T.; Zhong, W.; Du, Q. G . A novel type of shape memory polymer blend and the shape memory mechanism . Polymer , 2009 . 50 ( 6 ): 1596 - 1601 . DOI: 10.1016/j.polymer.2009.01.011 http://doi.org/10.1016/j.polymer.2009.01.011 .

Kurahashi, E.; Sugimoto, H.; Nakanishi, E.; Nagata, K.; Inomata, K . Shape memory properties of polyurethane/poly(oxyethylene) blends . Soft Matter , 2012 . 8 ( 2 ): 496 - 503 . DOI: 10.1039/C1SM06585H http://doi.org/10.1039/C1SM06585H .

Yuan, D. S.; Chen, Z. H.; Xu, C. H.; Chen, K. L.; Chen Y. K . Fully biobased shape memory material based on novel cocontinuous structure in poly(lactic acid)/natural rubber TPVs fabricated via peroxide-induced dynamic vulcanization and in situ interfacial compatibilization . ACS Sustain. Chem. Eng. , 2015 . 3 ( 11 ): 2856 - 2865 . DOI: 10.1021/acssuschemeng.5b00788 http://doi.org/10.1021/acssuschemeng.5b00788 .

Zheng, Y.; Dong, R. Q.; Shen, J. B.; Guo, S. Y . Tunable shape memory performances via multilayer assembly of thermoplastic polyurethane and polycaprolactone . ACS Appl. Mater. Interfaces , 2016 . 8 ( 2 ): 1371 - 1380 . DOI: 10.1021/acsami.5b10246 http://doi.org/10.1021/acsami.5b10246 .

Gubbels, F.; Blacher, S.; Vanlathem, E.; Jerome, R.; Deltour, R.; Brouers, F.; Teyssie, P . Design of electrical composites, determining the role of the morphology on the electrical properties of carbon black filled polymer blends . Macromolecules , 1995 . 28 ( 5 ): 1559 - 1566 . DOI: 10.1021/ma00109a030 http://doi.org/10.1021/ma00109a030 .

Wu, G.; Li, B.; Jiang, J . Carbon black self-networking induced co-continuity of immiscible polymer blends . Polymer , 2010 . 51 ( 9 ): 2077 - 2083 . DOI: 10.1016/j.polymer.2010.03.007 http://doi.org/10.1016/j.polymer.2010.03.007 .

Xiu, H.; Huang, C. M.; Bai, H. W.; Jiang, J.; Chen, F.; Deng, H.; Zhang, Q.; Fu, Q . Improving impact toughness of polylactide/poly(ether)urethane blends via designing the phase morphology assisted by hydrophilic silica nanoparticles . Polymer , 2014 . 55 ( 6 ): 1593 - 1600 . DOI: 10.1016/j.polymer.2014.01.057 http://doi.org/10.1016/j.polymer.2014.01.057 .

Xiu, H.; Zhou, Y.; Huang, C. M.; Bai, H. W.; Zhang, Q.; Fu, Q . Deep insight into the key role of carbon black self-networking in the formation of co-continuous-like morphology in polylactide/poly(ether)urethane blends . Polymer , 2016 . 82 11 - 21 . DOI: 10.1016/j.polymer.2015.10.034 http://doi.org/10.1016/j.polymer.2015.10.034 .

Odent, J.; Habibi, Y.; Raquez, J. M.; Dubois, P . Ultra-tough polylactide-based materials synergistically designed in the presence of rubbery ε -caprolactone-based copolyester and silica nanoparticles . Compos. Sci. Technol. , 2013 . 84 86 - 91 . DOI: 10.1016/j.compscitech.2013.05.003 http://doi.org/10.1016/j.compscitech.2013.05.003 .

Qi, X. D.; Xiu, H.; Wei, Y.; Zhou, Y.; Guo, Y. L.; Huang, R.; Bai, H. W.; Fu, Q . Enhanced shape memory property of polylactide/thermoplastic poly(ether)urethane composites via carbon black self-networking induced co-continuous structure . Compos. Sci. Technol. , 2017 . 139 8 - 16 . DOI: 10.1016/j.compscitech.2016.12.007 http://doi.org/10.1016/j.compscitech.2016.12.007 .

Sun, Y.; Bao, H. D.; Guo, Z. X.; Yu, J . Modeling of the electrical percolation of mixed carbon fillers in polymer-based composites . Macromolecules , 2009 . 42 ( 1 ): 459 - 463 . DOI: 10.1021/ma8023188 http://doi.org/10.1021/ma8023188 .

Ma, P. C.; Liu, M. Y.; Zhang, H.; Wang, S. Q.; Wang, R.; Wang, K.; Wong, Y. K.; Tang, B. Z.; Hong, S. H.; Paik, K. W.; Kim, J. K . Enhanced electrical conductivity of nanocomposites containing hybrid fillers of carbon nanotubes and carbon black . ACS Appl. Mater. Interfaces , 2009 . 1 ( 5 ): 1090 - 1096 . DOI: 10.1021/am9000503 http://doi.org/10.1021/am9000503 .

Chen, J.; Du, X. C.; Zhang, W. B.; Yang, J. H.; Zhang, N.; Huang, T.; Wang; Y . Synergistic effect of carbon nanotubes and carbon black on electrical conductivity of PA6/ABS blend . Compos. Sci. Technol. , 2013 . 81 1 - 8 . DOI: 10.1016/j.compscitech.2013.03.014 http://doi.org/10.1016/j.compscitech.2013.03.014 .

Zou, H.; Wang, K.; Zhang, Q.; Fu, Q . A change of phase morphology in poly( p -phenylene sulfide)/polyamide 66 blends induced by adding multi-walled carbon nanotubes . Polymer , 2006 . 47 ( 22 ): 7821 - 7826 . DOI: 10.1016/j.polymer.2006.09.008 http://doi.org/10.1016/j.polymer.2006.09.008 .

Shi. Y. Y; Zhang, W. B.; Yang J. H.; Huang, T.; Zhang, N.; Wang, Y.; Yuan, G. P.; Zhang, C. L . Super toughening of the poly(L-lactide)/thermoplastic polyurethane blends by carbon nanotubes . RSC Adv. , 2013 . 3 ( 48 ): 26271 - 26282 . DOI: 10.1039/c3ra43253j http://doi.org/10.1039/c3ra43253j .

Xiao, Y. J.; Wang W. Y.; Lin, T.; Chen, X. J.; Zhang, Y. T.; Yang J. H.; Wang, Y.; Zhou, Z. W . Largely enhanced thermal conductivity and high dielectric constant of poly(vinylidene fluoride)/boron nitride composites achieved by adding a few Carbon Nanotubes . J. Phys. Chem. C , 2016 . 120 ( 12 ): 6344 - 6355 . DOI: 10.1021/acs.jpcc.5b12651 http://doi.org/10.1021/acs.jpcc.5b12651 .

He, M. J.; Xiao, W. X.; Xie, H.; Fan, C. J.; Du, L.; Deng, X. Y.; Wang, Y. Z . Facile fabrication of ternary nanocomposites with selective dispersion of multi-walled carbon nanotubes to access multi-stimuli-responsive shape-memory effects . Mater. Chem. Front. , 2017 . 1 343 - 353 . DOI: 10.1039/C6QM00047A http://doi.org/10.1039/C6QM00047A .

Tang, Z. H.; Kang, H. L.; Wei, Q. Y.; Guo, B. C.; Zhang, L. Q.; Jia, D. M . Incorporation of graphene into polyester/carbon nanofibers composites for better multi-stimuli responsive shape memory performances . Carbon , 2013 . 64 487 - 498 . DOI: 10.1016/j.carbon.2013.07.103 http://doi.org/10.1016/j.carbon.2013.07.103 .

Xu, Z. H.; Zhang, Y. Q.; Wang, Z. G.; Sun, N.; Li, H . Enhancement of electrical conductivity by changing phase morphology for composites consisting of polylactide and poly(epsilon-caprolactone) filled with acid-oxidized multiwalled carbon nanotubes . ACS Appl. Mater. Interfaces , 2011 . 3 ( 12 ): 4858 - 4864 . DOI: 10.1021/am201355j http://doi.org/10.1021/am201355j .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Phase Structure Formed by Rubber and Rigid Particles in a Polymer and Its Effect on the Composite Rigidity and Toughness

High-performance Polydimethylsiloxane Composites Based on Ordered Three-dimensional PVA-MMT Aerogel Network: Network Structure Regulation and Mechanical Enhancement Mechanism

Wide-ranging Force Responsive Composites based on 1,2-Dioxetane and ZnS as Luminescent Probes in Polyurethanes

Fabrication of Highly Anisotropic and Interconnected Porous Scaffolds to Promote Preosteoblast Proliferation for Bone Tissue Engineering

Multiple-Responsive Chiral Hydrogels from Helical Dendronized Poly(phenylacetylene)s