Effects of Binding Energy of Bioinspired Sacrificial Bond on Mechanical Performance of cis-1,4-Polyisoprene with Dual-crosslink

Sheng Wang; Zheng-Hai Tang; Jing Huang; Bao-Chun Guo

doi:10.1007/s10118-018-2131-x

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Effects of Binding Energy of Bioinspired Sacrificial Bond on Mechanical Performance of cis-1,4-Polyisoprene with Dual-crosslink

ARTICLE | Updated：2021-02-18

- Effects of Binding Energy of Bioinspired Sacrificial Bond on Mechanical Performance of cis-1,4-Polyisoprene with Dual-crosslink
- Effects of Binding Energy of Bioinspired Sacrificial Bond on Mechanical Performance of cis-1,4-Polyisoprene with Dual-crosslink
- Chinese Journal of Polymer Science 2018年36卷第9期页码：1055-1062
- Affiliations：
  
  Department of Polymer Materials and Engineering, South China University of Technology, Guangzhou 510641, China
- Author bio：
  
  psbcguo@scut.edu.cn
- Funds：
  
  This work was financially supported by the National Basic Research Program of China (No. 2015CB654700 (2015CB654703)), the National Natural Science Foundation of China (Nos. 51673065, 51703064, 51473050 and 51333003) and Fundamental Research Funds for the Central Universities (No. 2017PY006).
- DOI：10.1007/s10118-018-2131-x
  中图分类号：
- 收稿：2017-12-19，
  
  修回：2018-2-21，
  
  录用：2018-2-21，
  
  网络首发：2018-04-04，
  
  纸质出版：2018-09
- Accepted：
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Sheng Wang, Zheng-Hai Tang, Jing Huang, 等. Effects of Binding Energy of Bioinspired Sacrificial Bond on Mechanical Performance of cis-1,4-Polyisoprene with Dual-crosslink[J]. Chinese Journal of Polymer Science, 2018,36(9):1055-1062.

Sheng Wang, Zheng-Hai Tang, Jing Huang, et al. Effects of Binding Energy of Bioinspired Sacrificial Bond on Mechanical Performance of cis-1,4-Polyisoprene with Dual-crosslink[J]. Chinese Journal of Polymer Science, 2018, 36(9): 1055-1062.
Sheng Wang, Zheng-Hai Tang, Jing Huang, 等. Effects of Binding Energy of Bioinspired Sacrificial Bond on Mechanical Performance of cis-1,4-Polyisoprene with Dual-crosslink[J]. Chinese Journal of Polymer Science, 2018,36(9):1055-1062. DOI： 10.1007/s10118-018-2131-x.

Sheng Wang, Zheng-Hai Tang, Jing Huang, et al. Effects of Binding Energy of Bioinspired Sacrificial Bond on Mechanical Performance of cis-1,4-Polyisoprene with Dual-crosslink[J]. Chinese Journal of Polymer Science, 2018, 36(9): 1055-1062. DOI： 10.1007/s10118-018-2131-x.

摘要

Abstract

Although bioinspired sacrificial bonds have been demonstrated to be efficient in improving the mechanical properties of polymer materials

the effect of binding energy of a specific dynamic bond on the ultimate mechanical performance of a polymer network with dual-crosslink remains unclear. In this contribution

diamine and sulfur curing package are introduced simultaneously into a sulfonated

cis

-1

4-polyisoprene to create dually-crosslinked

cis

-1

4-polyisoprene network with sulfonate-aminium ionic bonds as the sacrificial bonds. Three diamines (primary

secondary and tertiary) with the same spacer between the two nitrogen atoms are used to create the ionic bonds with different binding energies. Although the binding energy of ionic bond does not affect the glass transition temperature of

cis

-1

4-polyisoprene (IR)

it exerts definite influences on strain-induced crystallization and mechanical performance. The capabilities of diamine in dissipating energy

promoting strain-induced crystallization and enhancing the mechanical performance are in the same order of secondary diamine

primary diamine

tertiary diamine. The variations in mechanical performances are correlated to the binding energy of the ionic bond

which is determined by p

values.

关键词

Keywords

references

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