Initiation, Development and Stabilization of Cavities during Tensile Deformation of Semicrystalline Polymers

Ying Lu; Yong-Feng Men

doi:10.1007/s10118-018-2123-x

Your Location：

Home >

Browse articles >

Initiation, Development and Stabilization of Cavities during Tensile Deformation of Semicrystalline Polymers

ARTICLE | Updated：2021-02-18

- Initiation, Development and Stabilization of Cavities during Tensile Deformation of Semicrystalline Polymers
- Initiation, Development and Stabilization of Cavities during Tensile Deformation of Semicrystalline Polymers
- Chinese Journal of Polymer Science 2018年36卷第10期页码：1195-1199
- Affiliations：
  
  a.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.University of Science and Technology of China, Hefei 230026, China
- Author bio：
  
  men@ciac.ac.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51525305 and 21134006), and the Newton Advanced Fellowship of Royal Society (No. NA150222). We thank Dr. Bijin Xiong for his assistance during USAXS experiments.
- DOI：10.1007/s10118-018-2123-x
  中图分类号：
- 收稿：2018-01-10，
  
  修回：2018-1-10，
  
  录用：2018-2-5，
  
  网络首发：2018-03-21，
  
  纸质出版：2018-10
- Accepted：
Scan QR Code
Citation: Lu, Y.; Men, Y. F. Initiation, Development and Stabilization of Cavities during Tensile Deformation of Semicrystalline Polymers. Chinese J. Polym. Sci. 2018, 36(10), 1195–1199.

Ying Lu, Yong-Feng Men. Initiation, Development and Stabilization of Cavities during Tensile Deformation of Semicrystalline Polymers[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1195-1199.
Citation: Lu, Y.; Men, Y. F. Initiation, Development and Stabilization of Cavities during Tensile Deformation of Semicrystalline Polymers. Chinese J. Polym. Sci. 2018, 36(10), 1195–1199. DOI： 10.1007/s10118-018-2123-x.

Ying Lu, Yong-Feng Men. Initiation, Development and Stabilization of Cavities during Tensile Deformation of Semicrystalline Polymers[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1195-1199. DOI： 10.1007/s10118-018-2123-x.

摘要

Abstract

By using polybutene-1 as a typical example

we illustrate the initiation

development and stabilization of cavities in the sample during tensile deformation. Samples with the same crystallinity

long spacing and crystalline lamellar thickness but very different sizes of spherulites were prepared

via

changing the melt history. Dimension of cavities during stretching the samples was determined by

in situ

ultra small angle X-ray scattering techniques. It turned out that the size of the cavities was bigger in the sample with larger spherulites than the one with smaller spherulites. The results show clear evidence of initiating cavities within crystalline phase at the grain-boundary of crystalline blocks

growing of cavities passing through parallel stacked lamellar crystals and amorphous layers and finally stablized by tilted lamellae at both ends of the plate-like cavities within the spherulites.

关键词

Keywords

references

Strobl, G., "The physics of polymers", 2nd ed., Springer, Berlin, Germany, 1997

Lin, L.; Argon, A. S . Structure and plastic-deformation of polyethylene . J. Mater. Sci. , 1994 . 29 ( 2 ): 294 - 323 . DOI: 10.1007/BF01162485 http://doi.org/10.1007/BF01162485 .

Chen, W.; Li, X. Y.; Liu, Y. P.; Li, J.; Zhou, W. M.; Chen, L.; Li, L. B . The spatial correlation between crystalline and amorphous orientations of isotactic polypropylene during plastic deformation: An in situ observation with FTIR imaging . Chinese J. Polym. Sci. , 2015 . 33 ( 4 ): 613 - 620 . DOI: 10.1007/s10118-015-1613-3 http://doi.org/10.1007/s10118-015-1613-3 .

Qiu, J.; Wang, Z. G.; Yang, L.; Zhao, J. C.; Niu, Y. H.; Hsiao, B. S . Deformation-induced highly oriented and stable mesomorphic phase in quenched isotactic polypropylene . Polymer , 2007 . 48 ( 23 ): 6934 - 6947 . DOI: 10.1016/j.polymer.2007.08.066 http://doi.org/10.1016/j.polymer.2007.08.066 .

Chen, X. W.; Lv, F.; Su, F. M.; Ji, Y. X.; Meng, L. P.; Wan, C. X.; Lin, Y. F.; Li, X. Y.; Li, L. B . Deformation mechanism of ipp under uniaxial stretching over a wide temperature range: An in-situ synchrotron radiation saxs/waxs study . Polymer , 2017 . 118 12 - 21 . DOI: 10.1016/j.polymer.2017.04.054 http://doi.org/10.1016/j.polymer.2017.04.054 .

Young, R. J.; Bowden, P. B.; Ritchie, J. M.; Rider, J. G . Deformation mechanisms in oriented high-density polyethylene . J. Mater. Sci. , 1973 . 8 ( 1 ): 23 - 36 . DOI: 10.1007/BF00755579 http://doi.org/10.1007/BF00755579 .

Bowden, P. B.; Young, R. J . Deformation mechanisms in crystalline polymers . J. Mater. Sci. , 1974 . 9 ( 12 ): 2034 - 2051 . DOI: 10.1007/BF00540553 http://doi.org/10.1007/BF00540553 .

Song, H. H.; Argon, A. S.; Cohen, R. E . Morphology of highly textured high-density polyethylene . Macromolecules , 1990 . 23 ( 3 ): 870 - 876 . DOI: 10.1021/ma00205a030 http://doi.org/10.1021/ma00205a030 .

Seiberle, H.; Stille, W.; Strobl, G . Comparative-study of individual and collective rotational motion in mixtures of liquid-crystalline side group polymers and low-molecular- weight mesogens . Macromolecules , 1990 . 23 ( 7 ): 2008 - 2016 . DOI: 10.1021/ma00209a022 http://doi.org/10.1021/ma00209a022 .

Flory, P. J.; Yoon, D. Y . Molecular morphology in semi-crystalline polymers . Nature , 1978 . 272 ( 5650 ): 226 - 229 . DOI: 10.1038/272226a0 http://doi.org/10.1038/272226a0 .

Popli, R.; Mandelkern, L . Influence of structural and morphologi-cal factors on the mechanical-properties of the polyethylenes . J. Polym. Sci., Part B: Polym. Phys. , 1987 . 25 ( 3 ): 441 - 483 . DOI: 10.1002/polb.1987.090250301 http://doi.org/10.1002/polb.1987.090250301 .

Wang, Y. T.; Jiang, Z. Y.; Wu, Z. H.; Men, Y. F . Tensile deformation of polybutene-1 with stable form I at elevated temperature . Macromolecules , 2013 . 46 ( 2 ): 518 - 522 . DOI: 10.1021/ma302389j http://doi.org/10.1021/ma302389j .

Hiss, R.; Hobeika, S.; Lynn, C.; Strobl, G . Network stretching, slip processes, and fragmentation of crystallites during uniaxial drawing of polyethylene and related copolymers . A comparative study. Macromolecules , 1999 . 32 ( 13 ): 4390 - 4403 . .

Hobeika, S.; Men, Y.; Strobl, G . Temperature and strain rate independence of critical strains in polyethylene and poly(ethylene- co -vinyl acetate) . Macromolecules , 2000 . 33 ( 5 ): 1827 - 1833 . DOI: 10.1021/ma9910484 http://doi.org/10.1021/ma9910484 .

Hong, K.; Strobl, G . Network stretching during tensile drawing of polyethylene: a study using X-ray scattering and microscopy . Macromolecules , 2006 . 39 ( 1 ): 268 - 273 . DOI: 10.1021/ma051726o http://doi.org/10.1021/ma051726o .

Men, Y.; Rieger, J.; Strobl, G . Role of the entangled amorphous network in tensile deformation of semicrystalline polymers . Phys. Rev. Lett. , 2003 . 91 ( 9 ): 095502 DOI: 10.1103/PhysRevLett.91.095502 http://doi.org/10.1103/PhysRevLett.91.095502 .

Galeski, A.; Rozanski, A . Flory prize lecture: cavitation during drawing of crystalline polymers . Macromol. Symp. , 2010 . 298 ( 1 ): 1 - 9 . DOI: 10.1002/masy.v298.1 http://doi.org/10.1002/masy.v298.1 .

Humbert, S.; Lame, O.; Chenal, J. M.; Rochas, C.; Vigier, G . New insight on initiation of cavitation in semicrystalline polymers: in-situ SAXS measurements . Macromolecules , 2010 . 43 ( 17 ): 7212 - 7221 . DOI: 10.1021/ma101042d http://doi.org/10.1021/ma101042d .

Xiong, B.; Lame, O.; Chenal, J. M.; Rochas, C.; Seguela, R.; Vigier, G . In-situ SAXS study and modeling of the cavitation/crystal-shear competition in semi-crystalline polymers: influence of temperature and microstructure in polyethylene . Polymer , 2013 . 54 ( 20 ): 5408 - 5418 . DOI: 10.1016/j.polymer.2013.07.055 http://doi.org/10.1016/j.polymer.2013.07.055 .

Men, Y. F.; Rieger, J.; Homeyer, J . Synchrotron ultrasmall-angle X-ray scattering studies on tensile deformation of poly(1-butene) . Macromolecules , 2004 . 37 ( 25 ): 9481 - 9488 . DOI: 10.1021/ma048274k http://doi.org/10.1021/ma048274k .

Wang, Y. T.; Jiang, Z. Y.; Fu, L. L.; Lu, Y.; Men, Y. F . Lamellar thickness and stretching temperature dependency of cavitation in semicrystalline polymers . Plos One , 2014 . 9 ( 5 ): e97234 DOI: 10.1371/journal.pone.0097234 http://doi.org/10.1371/journal.pone.0097234 .

Lu, Y.; Wang, Y. T.; Chen, R.; Zhao, J. Y.; Jiang, Z. Y.; Men, Y. F . Cavitation in lsotactic polypropylene at large strains during tensile deformation at elevated temperatures . Macromolecules , 2015 . 48 ( 16 ): 5799 - 5806 . DOI: 10.1021/acs.macromol.5b00818 http://doi.org/10.1021/acs.macromol.5b00818 .

Taraiya, A. K.; Richardson, A.; Ward, I. M . Production and properties of highly oriented polypropylene by die drawing . J. Appl. Polym. Sci. , 1987 . 33 ( 7 ): 2559 - 2579 . DOI: 10.1002/app.1987.070330723 http://doi.org/10.1002/app.1987.070330723 .

Tashiro, K.; Hu, J.; Wang, H.; Hanesaka, M.; Saiani, A . Refinement of the crystal structures of forms I and II of isotactic polybutene-1 and a proposal of phase transition mechanism between them . Macromolecules , 2016 . 49 ( 4 ): 1392 - 1404 . DOI: 10.1021/acs.macromol.5b02785 http://doi.org/10.1021/acs.macromol.5b02785 .

Maruyama, M.; Sakamoto, Y.; Nozaki, K.; Yamamoto, T.; Kajioka, H.; Toda, A.; Yamada, K . Kinetic study of the ii-i phase transition of isotactic polybutene-1 . Polymer , 2010 . 51 ( 23 ): 5532 - 5538 . DOI: 10.1016/j.polymer.2010.09.066 http://doi.org/10.1016/j.polymer.2010.09.066 .

Gohil, R. M.; Milles, M. J.; Petermann, J . On the molecular mechanism of the crystal transformation (tetragonal-hexagonal) in polybutene-1 . J. Macromol. Sci. Phys. , 1982 . B21 ( 2 ): 189 - 201 . .

Rubin, I. D . Relative stabilities of polymorphs of polybutene-1 obtained from melt . J. Polym. Sci., Part B: Polym. Phys. Lett. , 1964 . 2 ( 7pb ): 747 - 749 . .

Porod, G., in "Small-angle X-ray scattering", ed. by Glatter, O. and Kratky, O., Academic Press, New York, 1982, p. 35

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Spatially Resolved Cavitation within Tensile Stretched Isotactic Polybutene-1 Spherulite

Real-Time Monitoring of Component Conversion during the Foaming and Curing Process of Self-expanding Polyurethane Grouts

Polymeric Hydrogels as Wound Dressing and Wound Healing Applications: A Review

Dual-responsive Flexible Dielectric Switching Composites for Overheating Warning and Small Deformation Monitoring

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber