Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO<sub>2</sub> and Propylene Oxide

Chun-Wei Zhuo; Yu-Sheng Qin; Xian-Hong Wang; Fo-Song Wang

doi:10.1007/s10118-018-2093-z

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Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide

Articles | Updated：2021-02-18

- Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide
- Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide
- Chinese Journal of Polymer Science 2018年36卷第2期页码：252-260
- Affiliations：
  
  a.Key Laboratory of Polymer Ecomaterial, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.University of Science and Technology of China, Hefei 230026, China
- Author bio：
  
  Yu-Sheng Qin, E-mail ysqin@ciac.ac.cn
  Xian-Hong Wang, E-mail xhwang@ciac.ac.cn
- Funds：
- DOI：10.1007/s10118-018-2093-z
  中图分类号：
- 收稿：2017-11-06，
  
  录用：2017-11-15，
  
  网络首发：2017-11-29，
  
  纸质出版：2018-02-05
- Accepted：
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Chun-Wei Zhuo, Yu-Sheng Qin, Xian-Hong Wang, 等. Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide[J]. Chinese Journal of Polymer Science, 2018,36(2):252-260. DOI: 10.1007/s10118-018-2093-z.

Chun-Wei Zhuo, Yu-Sheng Qin, Xian-Hong Wang, et al. Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide[J]. Chinese Journal of Polymer Science, 2018, 36(2): 252-260. DOI: 10.1007/s10118-018-2093-z.
Chun-Wei Zhuo, Yu-Sheng Qin, Xian-Hong Wang, 等. Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide[J]. Chinese Journal of Polymer Science, 2018,36(2):252-260. DOI: 10.1007/s10118-018-2093-z. DOI：

Chun-Wei Zhuo, Yu-Sheng Qin, Xian-Hong Wang, et al. Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide[J]. Chinese Journal of Polymer Science, 2018, 36(2): 252-260. DOI: 10.1007/s10118-018-2093-z. DOI：

摘要

Abstract

Aluminum porphyrin complexes are heavy-metal-free and soil-tolerant green catalysts for the copolymerization of CO

and propylene oxide (PO)

but they suffer from relatively poor poly(propylene carbonate) (PPC) selectivity. Herein

steric hindrance porphyrin ligand was used to enhance the PPC selectivity. Typically

a bulky anthracene-like group was incorporated into the porphyrin ring to form 5

20-tetra(1

8-octahydro-1

4:5

8-dimethanoanthracen-9-yl) porphyrin

the aluminum porphyrin complex with this ligand

in combination with bis(triphenylphosphine) iminium chloride as a co-catalyst

produced completely alternate PPC. Additionally

the obtained PPC showed high regioselectivity

with a head-to-tail linkage content (HT) of 92%. Therefore

we demonstrated that introduction of bulky steric ligand into the porphyrin ring could reduce the propylene oxide homopolymerization activity leading to excellent PPC selectivity

and improve regioselectivity for the PO ring-opening during the copolymerization.

关键词

Keywords

references

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Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO2 and Propylene Oxide

Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO2 and Propylene Oxide

DOI：10.1007/s10118-018-2093-z

摘要

Abstract

关键词

Keywords

references

Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide

Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide