Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on <italic style="font-style: italic">in situ</italic> Compatibilization by Dicumyl Peroxide

Sheng-Xue Qin; Cui-Xiang Yu; Xue-Yang Chen; Hai-Ping Zhou; Li-Fen Zhao

doi:10.1007/s10118-018-2065-3

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Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide

Articles | Updated：2021-02-18

- Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide
- Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide
- Chinese Journal of Polymer Science 2018年36卷第6期页码：783-790
- Affiliations：
  
  a.College of Mechanical and Electric Engineering, College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China
  b.Qingdao Reinforced Thermoplastic Pipes Engineering Technology Center, Qingdao 266590, China
- Author bio：
  
  Hai-Ping Zhou, E-mail zhouhp325@163.com (H.P.Z)
  Li-Fen Zhao, E-mail lfzhao2009@126.com (L.F.Z)
- Funds：
- DOI：10.1007/s10118-018-2065-3
  中图分类号：
- 收稿：2017-09-05，
  
  录用：2017-10-17，
  
  网络首发：2018-01-30，
  
  纸质出版：2018-06
- Accepted：
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Sheng-Xue Qin, Cui-Xiang Yu, Xue-Yang Chen, 等. Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide[J]. Chinese Journal of Polymer Science, 2018,36(6):783-790. DOI: 10.1007/s10118-018-2065-3.

Sheng-Xue Qin, Cui-Xiang Yu, Xue-Yang Chen, et al. Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide[J]. Chinese Journal of Polymer Science, 2018, 36(6): 783-790. DOI: 10.1007/s10118-018-2065-3.
Sheng-Xue Qin, Cui-Xiang Yu, Xue-Yang Chen, 等. Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide[J]. Chinese Journal of Polymer Science, 2018,36(6):783-790. DOI: 10.1007/s10118-018-2065-3. DOI：

Sheng-Xue Qin, Cui-Xiang Yu, Xue-Yang Chen, et al. Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide[J]. Chinese Journal of Polymer Science, 2018, 36(6): 783-790. DOI: 10.1007/s10118-018-2065-3. DOI：

摘要

Abstract

Fully biodegradable blends with low shape memory recovery temperature were obtained based on poly(lactic acid) (PLA) and poly(propylene carbonate) (PPC). By virtue of their similar chemical structures

in situ

cross-linking reaction initiated by dicumyl peroxide (DCP) between PLA and PPC chains was realized in PLA/PPC blends. Therefore

the compatibility between PLA and PPC was increased

which obviously changed the phase structures and increased the elongation at break of the blends. The compatibilized blends had a recovery performance at 45℃. Combining the changes of phase structures

the mechanism of the shape memory was discussed. It was demonstrated that

in situ

compatibilization by dicumyl peroxide was effective to obtain eco-friendly PLA/PPC blends with good mechanical and shape memory properties.

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references

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Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide

Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide

DOI：10.1007/s10118-018-2065-3

摘要

Abstract

关键词

Keywords

references