Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers

Shu-Qing Fang; Yu-Lian Pang; Ying-Quan Zou

doi:10.1007/s10118-018-2048-4

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Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers

Articles | Updated：2021-02-18

- Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers
- Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers
- Chinese Journal of Polymer Science 2018年36卷第4期页码：521-527
- Affiliations：
  
  College of Chemistry, Beijing Normal University, Beijing 100875, China
- Author bio：
  
  E-mail zouyq@263.net
- Funds：
- DOI：10.1007/s10118-018-2048-4
  中图分类号：
- 收稿：2017-05-24，
  
  录用：2017-9-22，
  
  网络首发：2017-12-20，
  
  纸质出版：2018-04-05
- Accepted：
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Shu-Qing Fang, Yu-Lian Pang, Ying-Quan Zou. Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers[J]. Chinese Journal of Polymer Science, 2018,36(4):521-527.

Shu-Qing Fang, Yu-Lian Pang, Ying-Quan Zou. Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers[J]. Chinese Journal of Polymer Science, 2018, 36(4): 521-527.
Shu-Qing Fang, Yu-Lian Pang, Ying-Quan Zou. Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers[J]. Chinese Journal of Polymer Science, 2018,36(4):521-527. DOI： 10.1007/s10118-018-2048-4.

Shu-Qing Fang, Yu-Lian Pang, Ying-Quan Zou. Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers[J]. Chinese Journal of Polymer Science, 2018, 36(4): 521-527. DOI： 10.1007/s10118-018-2048-4.

摘要

Abstract

In this paper

we combined high-end cationic UV-curable material with fluorinated chain obtaining a series of new fluorine-containing aromatic oxetane monomers

via

a mild nucleophilic substitution reaction. The structures and properties of monomers were characterized using

H-NMR

F-NMR

dynamic viscosity tests and differential scanning calorimetry (DSC). It was determined that all of the fluorinated monomers obtained had much lower viscosity and higher thermostability after the introduction of hexafluorobenzene. Then

UV-curable coatings were prepared using four fluorine-containing aromatic oxetane monomers (FOX1-4); the UV-curing kinetics

with three kinds of initiators

and properties of the cured films were evaluated using real-time Fourier transform infrared (FTIR) spectroscopy

water and diiodomethane contact angle tests

surface energy calculations and scanning electron microscopy (SEM). The FTIR spectroscopy results showed that the coatings possessed excellent conversion rate (

99% with liquid initiator PAG-201 in 150 s)

and as the fluorine content increased

the monomers exhibited decreased mobility with the increasing viscosity and worse solubility with fluorinated monomers

resulting in a lower conversion rate. Moreover

the coatings possessed favorable hydrophobic and oleophobic properties and low surface energies owing to the fluoride chains floating to the membrane-air interface

which was also confirmed by discrete concave structures in SEM images. These new kinds of monomers can replace traditional fluorinated cationic monomers applied to the fingerprint resistant

fouling resistant

scratch resistant and anti-aging coatings

adhesives or printing ink materials.

关键词

Keywords

references

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