Synergistic Efficiency of Tricresyl Phosphate and Montmorillonite on the Mechanical Characteristics and Flame Retardant Properties of Polylactide and Poly(butylene succinate) Blends

Tunsuda Suparanon; Jiratchaya Surisaeng; Neeranuch Phusunti; Worasak Phetwarotai

doi:10.1007/s10118-018-2043-9

Your Location：

Home >

Browse articles >

Synergistic Efficiency of Tricresyl Phosphate and Montmorillonite on the Mechanical Characteristics and Flame Retardant Properties of Polylactide and Poly(butylene succinate) Blends

Articles | Updated：2021-02-18

- Synergistic Efficiency of Tricresyl Phosphate and Montmorillonite on the Mechanical Characteristics and Flame Retardant Properties of Polylactide and Poly(butylene succinate) Blends
- Synergistic Efficiency of Tricresyl Phosphate and Montmorillonite on the Mechanical Characteristics and Flame Retardant Properties of Polylactide and Poly(butylene succinate) Blends
- Chinese Journal of Polymer Science 2018年36卷第5期页码：620-631
- Affiliations：
  
  a.Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hatyai 90112, Thailand
  b.Department of Chemistry, Faculty of Science, Prince of Songkla University, Hatyai 90112, Thailand
  c.Bioplastic Research Unit, Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Songkhla 90112, Thailand
- Author bio：
  
  Worasak Phetwarotai, E-mail w.phetwarotai@hotmail.com
- Funds：
- DOI：10.1007/s10118-018-2043-9
  中图分类号：
- 收稿：2017-07-12，
  
  录用：2017-9-12，
  
  网络首发：2018-01-11，
  
  纸质出版：2018-05-05
- Accepted：
Scan QR Code
Tunsuda Suparanon, Jiratchaya Surisaeng, Neeranuch Phusunti, 等. Synergistic Efficiency of Tricresyl Phosphate and Montmorillonite on the Mechanical Characteristics and Flame Retardant Properties of Polylactide and Poly(butylene succinate) Blends[J]. Chinese Journal of Polymer Science, 2018,36(5):620-631.

Tunsuda Suparanon, Jiratchaya Surisaeng, Neeranuch Phusunti, et al. Synergistic Efficiency of Tricresyl Phosphate and Montmorillonite on the Mechanical Characteristics and Flame Retardant Properties of Polylactide and Poly(butylene succinate) Blends[J]. Chinese Journal of Polymer Science, 2018, 36(5): 620-631.
Tunsuda Suparanon, Jiratchaya Surisaeng, Neeranuch Phusunti, 等. Synergistic Efficiency of Tricresyl Phosphate and Montmorillonite on the Mechanical Characteristics and Flame Retardant Properties of Polylactide and Poly(butylene succinate) Blends[J]. Chinese Journal of Polymer Science, 2018,36(5):620-631. DOI： 10.1007/s10118-018-2043-9.

Tunsuda Suparanon, Jiratchaya Surisaeng, Neeranuch Phusunti, et al. Synergistic Efficiency of Tricresyl Phosphate and Montmorillonite on the Mechanical Characteristics and Flame Retardant Properties of Polylactide and Poly(butylene succinate) Blends[J]. Chinese Journal of Polymer Science, 2018, 36(5): 620-631. DOI： 10.1007/s10118-018-2043-9.

摘要

Abstract

The main aim of this research was to investigate the synergistic influence of additives and poly(butylene succinate) (PBS) in improving both the mechanical and flame retardant properties of polylactide (PLA) blends. Tricresyl phosphate (TCP) and montmorillonite (MMT) were the additives used to improve the mechanical characteristics and fire resistance of PLA. Differential scanning calorimetry (DSC) thermograms revealed that the addition of TCP and MMT significantly affected their thermal behaviors. The results of the mechanical and morphological characterizations were in agreement with the changes in thermal behavior. The impact strength and limiting oxygen index (LOI) value of PLA significantly increased with the presence of PBS. The failure mode of the blends as evidenced by scanning electron microscopy (SEM) changed from brittle to ductile. The addition of TCP and MMT produced excellent anti-dripping and self-extinguishing behaviors of the blends

achieving Ⅴ-0 rating. For the PLA/PBS blends

the synergistic combination of PBS and additives led to an acceleration of cold crystallization

a significant increment of flexibility and impact toughness

and an improvement of flame retardancy.

关键词

Keywords

references

W. S. Chow , E. L. Teoh . Flexible and flame resistant poly(lactic acid)/organomontmorillonite nanocomposite . J. Appl. Polym. Sci. , 2015 . 132 ( 2 ): 41253 - 41264 . http://www.researchgate.net/publication/264562212_flexible_and_flame_resistant_poly(lactic_acid)organomontmorillonite_nanocomposites http://www.researchgate.net/publication/264562212_flexible_and_flame_resistant_poly(lactic_acid)organomontmorillonite_nanocomposites , .

X. Wang , L. Song , H. Yang , H. Lu , Y. Hu . Synergistic effect of graphene on antidripping and fire resistance of intumescent flame retardant poly(butylene succinate) composites . Ind. Eng. Chem. Res. , 2011 . 50 ( 9 ): 5376 - 5383 . DOI: 10.1021/ie102566y http://doi.org/10.1021/ie102566y .

L. T. Lim , R. Auras , M. Rubino . Processing technologies for poly(lactic acid) . Prog. Polym. Sci. , 2008 . 33 ( 8 ): 820 - 852 . DOI: 10.1016/j.progpolymsci.2008.05.004 http://doi.org/10.1016/j.progpolymsci.2008.05.004 .

C. F. Wang , H. Y. Xie , Y. P. Cheng , L. Chen , M. Z. Hu , S. Chen . Chemical synthesis and optical properties of CdS-poly(lactic acid) nanocomposites and their transparent fluorescent films . Colloid. Polym. Sci. , 2011 . 289 ( 4 ): 395 - 400 . DOI: 10.1007/s00396-011-2377-0 http://doi.org/10.1007/s00396-011-2377-0 .

X. Shi , G. Zhang , T. V. Phuong , A. Lazzeri . Synergistic effects of nucleating agents and plasticizers on the crystallization behavior of poly(lactic acid) . Molecules , 2015 . 20 ( 1 ): 1579 - 1593 . DOI: 10.3390/molecules20011579 http://doi.org/10.3390/molecules20011579 .

A. K. Mohapatra , S. Mohanty , S. K. Nayak . Study of thermo-mechanical and morphological behavior of biodegradable PLA/PBAT/layered silicate blend nanocomposites . J. Polym. Environ. , 2014 . 22 ( 3 ): 398 - 408 . DOI: 10.1007/s10924-014-0639-x http://doi.org/10.1007/s10924-014-0639-x .

t B. Suksu , C. Deeprasertkul . Effect of nucleating agents on physical properties of poly(lactic acid) and its blend with natural rubber . J. Polym. Environ. , 2011 . 19 ( 1 ): 288 - 296 . DOI: 10.1007/s10924-010-0278-9 http://doi.org/10.1007/s10924-010-0278-9 .

J. N. Gavgani , H. Adelnia , G. M. M. Sadeghi , F. Zafari . Intumescent flame retardant polyurethane/starch composites:thermal, mechanical, and rheological properties . J. Appl. Polym. Sci. , 2014 . 131 ( 23 ): 41158 - 41166 . http://onlinelibrary.wiley.com/doi/10.1002/app.41158/full?scrollTo=references http://onlinelibrary.wiley.com/doi/10.1002/app.41158/full?scrollTo=references , .

K. C. Cheng , Y. H. Lin , W. Guo , T. Hwang , T. M. Don . Flammability and tensile properties of polylactide nanocomposites with short carbon fibers . J. Mater. Sci. , 2015 . 50 ( 4 ): 1605 - 1612 . DOI: 10.1007/s10853-014-8721-2 http://doi.org/10.1007/s10853-014-8721-2 .

M. Murariu , L. Bonnaud , P. Yoann , G. Fontaine , S. Bourbigot , P. Dubois . New trends in polylactide (PLA)-based materials:"Green" PLA-calcium sulfate (nano)composites tailored with flame retardant properties . Polym. Degrad. Stab. , 2010 . 95 ( 3 ): 374 - 381 . DOI: 10.1016/j.polymdegradstab.2009.11.032 http://doi.org/10.1016/j.polymdegradstab.2009.11.032 .

G. Tang , X. Wang , W. Xing , P. Zhang , B. Wang , N. Hong , W. Yang , Y. Hu , L. Song . Thermal degradation and flame retardance of biobased polylactide composites based on aluminum hypophosphite . Ind. Eng. Chem. Res. , 2012 . 51 ( 37 ): 12009 - 12016 . DOI: 10.1021/ie3008133 http://doi.org/10.1021/ie3008133 .

G. Tang , R. Zhang , X. Wang , B. Wang , L. Song , Y. Hu , X. Gong . Enhancement of flame retardant performance of bio-based polylactic acid composites with the incorporation of aluminum hypophosphite and expanded graphite . J. Macromol. Sci. , 2013 . 50 ( 2 ): 255 - 269 . DOI: 10.1080/10601325.2013.742835 http://doi.org/10.1080/10601325.2013.742835 .

S. Li , H. Yuan , T. Yu , W. Yuan , J. Ren . Flame-retardancy and anti-dripping effects of intumescent flame retardant incorporating montmorillonite on poly(lactic acid) . Polym. Adv. Technol. , 2009 . 20 ( 12 ): 1114 - 1120 . DOI: 10.1002/pat.v20:12 http://doi.org/10.1002/pat.v20:12 .

S. Bourbigot , S. Duquesne , G. Fontaine , S. Bellayer , T. Turf , F. Samyn . Characterization and reaction to fire of polymer nanocomposites with and without conventional flame retardants . Mol. Cryst. Liq. Cryst. , 2008 . 486 ( 1 ): 1367 - 1381 . http://www.tandfonline.com/doi/pdf/10.1080/15421400801921983?needAccess=true http://www.tandfonline.com/doi/pdf/10.1080/15421400801921983?needAccess=true , .

X. Wang , Y. Hu , L. Song , S. Xuan , W. Xing , Z. Bai , H. Lu . Flame retardancy and thermal degradation of intumescent flame retardant poly(lactic acid)/starch biocomposites . Ind. Eng. Chem. Res. , 2011 . 50 713 - 720 . DOI: 10.1021/ie1017157 http://doi.org/10.1021/ie1017157 .

M. L. Bras , S. Bourbigot , Y. L. Tallec , J. Laureyns . Synergy in intumescence-application to Î²-cyclodextrin carbonisation agent in intumescent additives for fire retardant polyethylene formulations . Polym. Degrad. Stab. , 1997 . 56 ( 1 ): 11 - 21 . DOI: 10.1016/S0141-3910(96)00190-5 http://doi.org/10.1016/S0141-3910(96)00190-5 .

J. Zhan , L. Song , S. Nie , Y. Hu . Combustion properties and thermal degradation behavior of polylactide with an effective intumescent flame retardant . Polym. Degrad. Stab. , 2009 . 94 ( 3 ): 291 - 296 . DOI: 10.1016/j.polymdegradstab.2008.12.015 http://doi.org/10.1016/j.polymdegradstab.2008.12.015 .

K. Wu , M. M. Shen , Y. Hu , W. Xing , X. Wang . Thermal degradation and intumescent flame retardation of cellulose whisker/epoxy resin composite . J. Therm. Anal. Calorim. , 2011 . 104 ( 3 ): 1083 - 1090 . DOI: 10.1007/s10973-011-1380-5 http://doi.org/10.1007/s10973-011-1380-5 .

H. Yang , L. Song , Q. Tai , X. Wang , B. Yu , Y. Yuan , Y. Hu , R. K. K. Yuen . Comparative study on the flame retarded efficiency of melamine phosphate, melamine phosphite and melamine hypophosphite on poly(butylene succinate) composites . Polym. Degrad. Stab. , 2014 . 105 248 - 256 . DOI: 10.1016/j.polymdegradstab.2014.04.021 http://doi.org/10.1016/j.polymdegradstab.2014.04.021 .

X. Lai , X. Zeng , H. Li , F. Liao , H. Zhang , C. Yin . Preparation and properties of flame retardant polypropylene with an intumescent system encapsulated by thermoplastic polyurethane . J. Macromol. Sci. , 2012 . 51 ( 1 ): 35 - 47 . DOI: 10.1080/00222348.2011.564099 http://doi.org/10.1080/00222348.2011.564099 .

S. Bourbigot , M. L. Bras , S. Duquesne , M. Rochery . Recent Advances for Intumescent Polymers . Macromol. Mater. Eng. , 2004 . 289 ( 6 ): 499 - 511 . DOI: 10.1002/(ISSN)1439-2054 http://doi.org/10.1002/(ISSN)1439-2054 .

Fox, D. M. ; Lee, J. ; Ford, E. ; Balsley, E. ; Zammarano, M. ; Matko, S. ; Gilman, J. W. POSS modified cellulose for improving flammability characteristics of polystyrene. in '10th international conference on wood & biofiber plastic composites. Wisconsin, USA', 2009, 337-342.

J. Wang , X. Y. Dong , W.L. Hao , Z. Yi , G. Xi , W. Ding . Application properties of TCP/OMMT flame retardant system in NR composites . J. Elastom. Plast. , 2012 . 45 ( 2 ): 107 - 119 . http://journals.sagepub.com/doi/abs/10.1177/0095244312445525 http://journals.sagepub.com/doi/abs/10.1177/0095244312445525 , .

J. U. Calderon , B. Lennox , M. R. Kamai . Thermally stable phosphonium-montmorillonite organoclays . Appl. Clay. Sci. , 2008 . 40 ( 1-4 ): 90 - 98 . DOI: 10.1016/j.clay.2007.08.004 http://doi.org/10.1016/j.clay.2007.08.004 .

S. Famg , Y. Hu , L. Song , J. Wu . Preparation and investigation of ethylene-vinyl acetate copolymer/silicone rubber/clay nanocomposites . Polym. Plast. Technol. Eng. , 2008 . 47 ( 1 ): 752 - 761 . http://www.researchgate.net/publication/243893896_Preparation_and_investigation_of_ethylene-vinyl_acetate_copolymersilicone_rubberclay_nanocomposites?ev=auth_pub http://www.researchgate.net/publication/243893896_Preparation_and_investigation_of_ethylene-vinyl_acetate_copolymersilicone_rubberclay_nanocomposites?ev=auth_pub , .

Y. Wu , H. Huang , W. Zhao , H. Zhang , Y. Wang , L. Zhang . Flame retardance of montmorillonite/rubber composites . J. Appl. Polym. Sci. , 2007 . 107 ( 5 ): 3318 - 3324 . http://www.academia.edu/9783493/Flame_retardance_of_montmorillonite_rubber_composites http://www.academia.edu/9783493/Flame_retardance_of_montmorillonite_rubber_composites , .

X. Zhang , Y. Zhang . Reinforcement effect of poly(butylene succinate) (PBS)-graftedcellulose nanocrystal on toughened PBS/polylactic acid blends . Carbohydr. Polym. , 2016 . 140 374 - 382 . DOI: 10.1016/j.carbpol.2015.12.073 http://doi.org/10.1016/j.carbpol.2015.12.073 .

W. Pivsa-Art , K. Fujii , K. Nomura , Y. Aso , H. Ohara , H. Yamane . The effect of poly(ethylene glycol) as plasticizer in blends of poly(lactic acid) and poly(butylene succinate) . J. Appl. Polym. Sci. , 2016 . 133 ( 8 ): 43044 - 43053 . http://www.researchgate.net/publication/283974179_The_effect_of_polyethylene_glycol_as_plasticizer_in_blends_of_polylactic_acid_and_polybutylene_succinate http://www.researchgate.net/publication/283974179_The_effect_of_polyethylene_glycol_as_plasticizer_in_blends_of_polylactic_acid_and_polybutylene_succinate , .

H. T. Oyama . Super-tough poly(lactic acid) materials:reactive blending with ethylene copolymer . Polymer , 2009 . 50 ( 3 ): 747 - 751 . DOI: 10.1016/j.polymer.2008.12.025 http://doi.org/10.1016/j.polymer.2008.12.025 .

P. Buenaventutada , P. Calabia , F. Ninomiya , H. Yagi , A. Oishi , K. Taguchi , M. Kunioka , K. Funabashi . Biodegradable poly(butylene succinate) composites reinforced by cotton fiber with silane coupling agent . Polymers , 2013 . 5 ( 1 ): 128 - 141 . DOI: 10.3390/polym5010128 http://doi.org/10.3390/polym5010128 .

P. Pan , W. Kai , B. Zhu , T. Dong , Y. Inoue . Polymorphous crystallization and multiple melting behavior of poly(L-lactide):molecular weight dependence . Macromolecules , 2007 . 40 ( 19 ): 6896 - 6905 . http://www.researchgate.net/publication/231700140_Polymorphous_Crystallization_and_Multiple_Melting_Behavior_of_Poly(l-lactide)_Molecular_Weight_Dependence http://www.researchgate.net/publication/231700140_Polymorphous_Crystallization_and_Multiple_Melting_Behavior_of_Poly(l-lactide)_Molecular_Weight_Dependence , .

T. Tábil , I. E. Sajó , F. Szabó1 , A. S. Luyt , J. K. Kovács . Crystalline structure of annealed polylactic acid and its relation to processing . Express Polym. Lett. , 2010 . 4 659 - 668 . DOI: 10.3144/expresspolymlett.2010.80 http://doi.org/10.3144/expresspolymlett.2010.80 .

D. Battegazzore , S. Bocchini , A. Frache . Crystallization kinetics of poly(lactic acid)-talc composites . Express Polym. Lett. , 2011 . 5 ( 10 ): 849 - 858 . DOI: 10.3144/expresspolymlett.2011.84 http://doi.org/10.3144/expresspolymlett.2011.84 .

J. H. Lee , T. G. Park , H. S. Park , D. S. Lee , Y. K. Lee , S. C. Yoon , J. D. Nam . Thermal and mechanical characteristics of poly(L-lactic acid) nanocomposite scaffold . Biomaterials , 2003 . 24 2773 - 2778 . DOI: 10.1016/S0142-9612(03)00080-2 http://doi.org/10.1016/S0142-9612(03)00080-2 .

S. S. Ray , P. Maiti , M. Okamoto , K. Yamada , K. Ueda . New polylactide/layered silicate nanocomposites.1.Preparation, characterization, and properties . Macromolecules , 2002 . 35 ( 8 ): 3104 - 3110 . DOI: 10.1021/ma011613e http://doi.org/10.1021/ma011613e .

J. Zhou , Z. Yao , C. Zhou , D. Wei , S. Li . Mechanical properties of PLA/PBS foamed composites reinforced by organophilic montmorillonite . J. Appl. Polym. Sci. , 2014 . 131 ( 18 ): 40773 - 40781 . https://www.researchgate.net/publication/261568244_Mechanical_Properties_of_PLAPBS_Foamed_Composites_Reinforced_by_Organophilic_Montmorillonite https://www.researchgate.net/publication/261568244_Mechanical_Properties_of_PLAPBS_Foamed_Composites_Reinforced_by_Organophilic_Montmorillonite , .

C. W. Shyang , L.S. Kuen . Flexural, morphological and thermal properties of poly(lactic acid)/organo-montmorillonite nanocomposite . Polym. Polym. Compos. , 2008 . 16 ( 4 ): 263 - 270 . http://www.researchgate.net/publication/287925756_Flexural_morphological_and_thermal_properties_of_polylactic_acidorgano-montmorillonite_nanocomposites http://www.researchgate.net/publication/287925756_Flexural_morphological_and_thermal_properties_of_polylactic_acidorgano-montmorillonite_nanocomposites , .

A. Dasari , Z. Z. Yu , G. P. Cai , Y. W. Mai . Recent developments in the fire retardancy of polymericmaterials . Prog. Polym. Sci. , 2013 . 38 ( 9 ): 1357 - 1387 . DOI: 10.1016/j.progpolymsci.2013.06.006 http://doi.org/10.1016/j.progpolymsci.2013.06.006 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Improving Impact Toughness of Polylactide/Ethylene-co-vinyl-acetate Blends via Adding Fumed Silica Nanoparticles: Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica

Preparation and Characteristics of Poly(butylene adipate-co-terephthalate)/Polylactide Blend Films via Synergistic Efficiency of Plasticization and Compatibilization

Molecularly Engineered Polyimide Films with Switchable Cavitation for Bidirectional Passive Thermal Regulation

Effect of Graphene/Nickel-iron Layered Double Hydroxide Hybrids on the Thermal Decomposition and Flame Retardancy of Acrylonitrile-butadiene-styrene Copolymer Composites

Manipulating Hierarchical Aggregation Structure via Film-forming Kinetics Enables Organic Photovoltaics over 20% Efficiency