In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene

Gui-Qiu Ma; Guan-Kai Sun; Zhe Ma; Jing-Qing Li; Jing Sheng

doi:10.1007/s10118-018-2023-0

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In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene

ARTICLE | Updated：2021-02-18

- In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene
- In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene
- Chinese Journal of Polymer Science 2018年36卷第8期页码：979-983
- Affiliations：
  
  Department of Polymer Material Science and Engineering, Institute of Advanced Polymer Materials, School of Material Science and Engineering, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300350, China
- Author bio：
  
  magq@tju.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51473113) and the Natural Science Foundation of Tianjin (No. 12JCYBJC11900).
- DOI：10.1007/s10118-018-2023-0
  中图分类号：
- 收稿：2017-11-09，
  
  录用：2017-12-9，
  
  网络首发：2018-03-06，
  
  纸质出版：2018-08
- Accepted：
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Gui-Qiu Ma, Guan-Kai Sun, Zhe Ma, 等. In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene[J]. Chinese Journal of Polymer Science, 2018,36(8):979-983.

Gui-Qiu Ma, Guan-Kai Sun, Zhe Ma, et al. In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene[J]. Chinese Journal of Polymer Science, 2018, 36(8): 979-983.
Gui-Qiu Ma, Guan-Kai Sun, Zhe Ma, 等. In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene[J]. Chinese Journal of Polymer Science, 2018,36(8):979-983. DOI： 10.1007/s10118-018-2023-0.

Gui-Qiu Ma, Guan-Kai Sun, Zhe Ma, et al. In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene[J]. Chinese Journal of Polymer Science, 2018, 36(8): 979-983. DOI： 10.1007/s10118-018-2023-0.

摘要

Abstract

Pentaerythritol triacrylate (PETA) was successfully grafted onto the plasma-treated isotactic polypropylene (

PP)

via

the

situ

melt processing. The X-ray photoelectron spectroscopy (XPS) results showed that the hydroxyl and carbonyl groups

and peroxides could be generated

via

plasma treatment. The content of free radical in plasma-treated

PP (P

PP) was measured by 2

2-diphenyl-1-picrylhydrazyl (DPPH). It was found that the resulting peroxides induced the grafting copolymerization of PETA onto

and the grafted PETA promoted the formation of

-crystal in P

which was evidenced by Fourier transform infrared spectroscopy (FTIR)

differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD) measurements

respectively.

关键词

Keywords

references

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