Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres

Wei Deng; Hua-Chao Guo; Wei-Li Yu; Cheng-You Kan

doi:10.1007/s10118-018-2012-3

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Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres

PAPERS | Updated：2021-02-18

- Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres
- Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres
- Chinese Journal of Polymer Science 2018年36卷第1期页码：43-48
- Affiliations：
  
  a.Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, School of Material Science and Engineering, Harbin University of Science and Technology, Harbin 150080, China
  b.Department of Chemical Engineering, Key Laboratory of Advanced Materials of Ministry of Education, Tsinghua University, Beijing 100084, China
- Author bio：
  
  E-mail weideng@hrbust.edu.cn (W.D.)
  E-mail kancy@tsinghua.edu.cn (C.Y.K.)
- Funds：
- DOI：10.1007/s10118-018-2012-3
  中图分类号：
- 收稿：2017-05-11，
  
  修回：2017-7-15，
  
  录用：2017-7-15，
  
  网络首发：2017-10-08，
  
  纸质出版：2018-01-05
- Accepted：
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Wei Deng, Hua-Chao Guo, Wei-Li Yu, 等. Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres[J]. Chinese Journal of Polymer Science, 2018,36(1):43-48.

Wei Deng, Hua-Chao Guo, Wei-Li Yu, et al. Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres[J]. Chinese Journal of Polymer Science, 2018, 36(1): 43-48.
Wei Deng, Hua-Chao Guo, Wei-Li Yu, 等. Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres[J]. Chinese Journal of Polymer Science, 2018,36(1):43-48. DOI： 10.1007/s10118-018-2012-3.

Wei Deng, Hua-Chao Guo, Wei-Li Yu, et al. Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres[J]. Chinese Journal of Polymer Science, 2018, 36(1): 43-48. DOI： 10.1007/s10118-018-2012-3.

摘要

Abstract

Polymer hollow microspheres were prepared by performing alkali treatment on the multilayer core/shell polymer latex particles containing carboxyl groups. Effects of the shell composition and dosage as well as alkali type on the morphology of the microspheres were investigated. Results showed that in comparison with acrylonitrile (AN) and methacrylic acid (MAA)

using butyl acrylate (BA) as the shell co-monomer decreased the glass transition temperature (

) of shell effectively and was beneficial to the formation of uniform and big hollow structure. Along with the increase of the shell dosage

the alkali-treated microspheres sequentially presented porous and hollow morphology

and the size of microspheres increased

while the hollow diameter increased first and then decreased

and the maximum hollow ratio reached 39.5%. Furthermore

the multilayer core/shell microspheres had better tolerance to NH

·H

O than to NaOH. When the molar ratio of alkali to methacrylic acid (MR

alkali/acid

) for NaOH ranged from 1.15 to 1.30 or MR

alkali/acid

for NH

·H

O ranged from 1.30 to 2.00

the regular polymer hollow microspheres could be obtained.

关键词

Keywords

references

S. Nuasaen , P. Tangboriboonrat . Optical properties of hollow latex particles as white pigment in paint film . Prog. Org. Coat. , 2015 . 79 83 - 89 . DOI: 10.1016/j.porgcoat.2014.11.012 http://doi.org/10.1016/j.porgcoat.2014.11.012 .

Y. Lan , L. Yang , M. C. Zhang , W. Q. Zhang , S. N. Wang . Microreactor of Pd nanoparticles immobilized hollow microspheres for catalytic hydrodechlorination of chlorophenols in water . ACS Appl. Mater. Interfaces , 2010 . 2 ( 1 ): 127 - 133 . DOI: 10.1021/am900622p http://doi.org/10.1021/am900622p .

L. F. Tan , W. T. Tang , T. L. Liu , X. L. Ren , C. H. Fu , L. Bo , J. Ren , X. W. Meng . Biocompatible hollow polydopamine nanoparticles loaded ionic liquid enhanced tumor microwave thermal ablation in vivo . ACS Appl. Mater. Interfaces , 2016 . 8 ( 18 ): 11237 - 11245 . DOI: 10.1021/acsami.5b12329 http://doi.org/10.1021/acsami.5b12329 .

C. J. Mcdonald , M. J. Devon . Hollow latex particles:synthesis and applications . Adv. Colloid Interf. Sci. , 2002 . 99 ( 3 ): 181 - 213 . DOI: 10.1016/S0001-8686(02)00034-9 http://doi.org/10.1016/S0001-8686(02)00034-9 .

H. Kawaguchi . Functional polymer microspheres . Prog. Polym. Sci. , 2000 . 25 ( 8 ): 1171 - 1210 . DOI: 10.1016/S0079-6700(00)00024-1 http://doi.org/10.1016/S0079-6700(00)00024-1 .

G. D. Fu , G. L. Li , K. G. Neoh , E. T. Kang . Hollow polymeric nanostructures-synthesis, morphology and function . Prog. Polym. Sci. , 2011 . 36 ( 1 ): 127 - 167 . DOI: 10.1016/j.progpolymsci.2010.07.011 http://doi.org/10.1016/j.progpolymsci.2010.07.011 .

V. N. Pavlyuchenko , O. V. Sorochinskaya , S. S. Ivanchev , V. V. Klubin , G. S. Kreichman , V. P. Budtov , M. Skrifvars , E. Halme , J. Koskinen . Hollow-particle latexes:preparation and properties . J. Polym. Sci., Part A:Polym. Chem. , 2001 . 39 ( 9 ): 1435 - 1449 . DOI: 10.1002/(ISSN)1099-0518 http://doi.org/10.1002/(ISSN)1099-0518 .

K. Akamatsu , W. Chen , Y. Suzuki , T. Ito , A. Nakao , T. Sugawara , R. Kikuchi , S. Nakao . Preparation of monodisperse chitosan microcapsules with hollow structures using the SPG membrane emulsification technique . Langmuir , 2010 . 26 ( 18 ): 14854 - 14860 . DOI: 10.1021/la101967u http://doi.org/10.1021/la101967u .

H. T. Guo , H. N. Yun , P. B. Zetterlund , S. C. Thickett . Factors influencing the preparation of hollow polymer-graphene oxide microcapsules via Pickering miniemulsion polymerization . Polymer , 2015 . 63 1 - 9 . DOI: 10.1016/j.polymer.2015.02.035 http://doi.org/10.1016/j.polymer.2015.02.035 .

P. Panahian , M. Salami-Kalajahi , M. S. Hosseini . Synthesis of dual thermoresponsive and pH-sensitive hollow nanospheres by atom transfer radical polymerization . J. Polym. Res. , 2014 . 21 ( 6 ): 1 - 8 . https://rd.springer.com/content/pdf/10.1007/s10965-014-0455-y.pdf https://rd.springer.com/content/pdf/10.1007/s10965-014-0455-y.pdf , .

H. G. Cui , Z. Chen , S. Zhong , K. L. Wooley , D. J. Pochan . Block copolymer assembly via kinetic control . Science , 2007 . 317 ( 5838 ): 647 - 650 . DOI: 10.1126/science.1141768 http://doi.org/10.1126/science.1141768 .

B. Huang , F. Bai , X. L. Yang , W. Q. Huang . Synthesis of monodisperse hollow polymer microspheres with functional groups by distillation precipitation polymerization . Chinese J. Polym. Sci. , 2010 . 28 ( 2 ): 277 - 285 . DOI: 10.1007/s10118-010-9089-7 http://doi.org/10.1007/s10118-010-9089-7 .

Kowalski, A., Vogel, M. and Blankenship, R. M., 1983, E. P. Pat., 0, 073, 529

Vogel, M., Kowalski, A. and Scott, J. D., 1987, E. P. Pat., 0, 267, 726

X. J. Wang , J. Feng , Y. C. Bai , Q. Zhang , Y. D. Yin . Synthesis, properties, and applications of hollow micro-/nanostructures . Chem. Rev. , 2016 . 116 ( 18 ): 10983 - 11060 . DOI: 10.1021/acs.chemrev.5b00731 http://doi.org/10.1021/acs.chemrev.5b00731 .

W. H. Zhang , Y. Huang , W. Tian . Polymer-based hollow microspheres:preparation methods and applications . Prog. Chem. , 2013 . 25 ( 11 ): 1951 - 1961 . https://www.researchgate.net/publication/286029887_Polymer-Based... https://www.researchgate.net/publication/286029887_Polymer-Based... , .

M. Okubo , A. Ito , T. Kanenobu . Production of submicron-sized multihollow polymer particles by alkali/cooling method . Colloid Polym. Sci. , 1996 . 274 ( 8 ): 801 - 804 . DOI: 10.1007/BF00654677 http://doi.org/10.1007/BF00654677 .

M. Okubo , K. Ichikawa , M. Fujimura . Production of multi-hollow polymer microspheres by stepwise alkali/acid method Ⅱ. Alkali treatment process . Colloid Polym. Sci. , 1991 . 269 ( 12 ): 1257 - 1262 . https://link.springer.com/article/10.1007/BF00652534 https://link.springer.com/article/10.1007/BF00652534 , .

Y. M. Jiang , B. T. Li , W. Deng , X. Y. Li , C. Y. Kan . Effect of monomer feeding mode on the preparation of hollow latexes with high MAA content in the core latex preparation . Chinese J. Polym. Sci. , 2014 . 32 ( 1 ): 21 - 28 . DOI: 10.1007/s10118-014-1391-3 http://doi.org/10.1007/s10118-014-1391-3 .

Y. M. Jiang , B. T. Li , W. J. Wang , M. Xu , C. Y. Kan . Effect of the shell crosslinking level and core/shell ratio on the morphology of latex particles in the preparation of hollow latexes . Chinese J. Polym. Sci. , 2014 . 32 ( 2 ): 177 - 186 . DOI: 10.1007/s10118-014-1387-z http://doi.org/10.1007/s10118-014-1387-z .

S. Nuasaen , P. Tangboriboonrat . Highly charged hollow latex particles prepared via seeded emulsion polymerization . J. Colloid Interf. Sci. , 2013 . 396 ( 6 ): 75 - 82 . http://europepmc.org/abstract/med/23428072 http://europepmc.org/abstract/med/23428072 , .

J. Shen , J. Xu , Y. Hu , J. W. Sun , L. X. Li , C. Y. Kan . Investigation of cationic soapless P(St- co -DMAEMA) latex and its electrostatic adsorption of laponite . Chinese J. Polym. Sci. , 2016 . 34 ( 10 ): 1240 - 1250 . DOI: 10.1007/s10118-016-1829-x http://doi.org/10.1007/s10118-016-1829-x .

J. Shen , J. Xu , Y. Hu , J. P. Li , C. Y. Kan . Fabrication of amino-containing hollow polymer latex and its composite with inorganic nanoparticles . Colloid Polym. Sci. , 2017 . 295 ( 4 ): 679 - 688 . DOI: 10.1007/s00396-017-4059-z http://doi.org/10.1007/s00396-017-4059-z .

Y. J. Fang , W. Deng , H. Zuo , C. Y. Kan . Preparation of hollow polymer particles and orthogonal experiment design for alkali post-treatment conditions . Acta Polymerica Sinica , 2015 . ( 8 ): 927 - 932 . https://www.researchgate.net/publication/283439522_Preparation_of... https://www.researchgate.net/publication/283439522_Preparation_of... , .

W. Deng , H. C. Guo , W. N. Zhang , C. Y. Kan . Fabrication and morphology control of hollow polymer particles by altering core particle size . Colloid Polym. Sci. , 2014 . 292 ( 10 ): 2687 - 2694 . DOI: 10.1007/s00396-014-3323-8 http://doi.org/10.1007/s00396-014-3323-8 .

G. W. Ceska . The effect of carboxylic monomers on surfactant-free emulsion copolymerization . J. Appl. Polym. Sci. , 1974 . 18 ( 2 ): 427 - 437 . DOI: 10.1002/app.1974.070180210 http://doi.org/10.1002/app.1974.070180210 .

W. Deng , M. Y. Wang , G. Chen , C. Y. Kan . Morphological evolution of multistage polymer particles in the alkali post-treatment . Eur. Polym. J. , 2010 . 46 ( 6 ): 1210 - 1215 . DOI: 10.1016/j.eurpolymj.2010.03.009 http://doi.org/10.1016/j.eurpolymj.2010.03.009 .

C. M. Cardinal , L. F. Francis , L. E. Scriven . Drying and collapse of hollow latex . J. Coat. Technol. Res , 2008 . 6 ( 4 ): 457 - 469 . https://link.springer.com/article/10.1007/s11998-009-9167-3 https://link.springer.com/article/10.1007/s11998-009-9167-3 , .

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