a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
b.Beijing Institute of Aerospace Testing Technology, Beijing 100074, China
c.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
d.Department of Chemical and Materials Engineering, National Chin-Yi University of Technology, Taichung 41170, China
e.Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032, China
E-mail flqing@dhu.edu.cn (F.L.Q.)
收稿:2017-05-18,
修回:2017-7-15,
录用:2017-7-15,
网络首发:2017-11-02,
纸质出版:2018-01-05
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Zeng-He Liu, Ji-Qing Huang, Li-Jie Sun, 等. PPC-based Reactive Hot Melt Polyurethane Adhesive (RHMPA) -Efficient Glues for Multiple Types of Substrates[J]. Chinese Journal of Polymer Science, 2018,36(1):58-64.
Zeng-He Liu, Ji-Qing Huang, Li-Jie Sun, et al. PPC-based Reactive Hot Melt Polyurethane Adhesive (RHMPA) -Efficient Glues for Multiple Types of Substrates[J]. Chinese Journal of Polymer Science, 2018, 36(1): 58-64.
Zeng-He Liu, Ji-Qing Huang, Li-Jie Sun, 等. PPC-based Reactive Hot Melt Polyurethane Adhesive (RHMPA) -Efficient Glues for Multiple Types of Substrates[J]. Chinese Journal of Polymer Science, 2018,36(1):58-64. DOI: 10.1007/s10118-018-2011-4.
Zeng-He Liu, Ji-Qing Huang, Li-Jie Sun, et al. PPC-based Reactive Hot Melt Polyurethane Adhesive (RHMPA) -Efficient Glues for Multiple Types of Substrates[J]. Chinese Journal of Polymer Science, 2018, 36(1): 58-64. DOI: 10.1007/s10118-018-2011-4.
Tens of billion metric tons of anthropogenic CO
2
discharged from the burning of fossil fuels lead to an enormous environmental and resource burden. It is charming to transform CO
2
to desirable
economical chemicals and materials. Poly(propylene carbonate) (PPC) is an emerging CO
2
-based material. Herein
we report the design
synthesis and characterization of the reactive hot melt polyurethane adhesive (RHMPA) based on PPC polyol. The resultant RHMPAs exhibit good adhesion properties to multiple substrates including plastics (PC
PMMA
ABS) and metals (aluminium
steel)
which is comparable to or even better than conventional RHMPAs prepared from petro-based polyol. Furthermore
the PPC-based RHMPAs have tunable mechanical properties
and are thermally stable in the typical working range of bonding process (up to 270℃). The study is expected to expand the applications of PPC and provide a new type of CO
2
-based renewable and eco-friendly materials.
The International Energy Outlook 2016 (IEO2016), U. S. Energy Information Administration (EIA), 2016, http://www.eia.gov/forecasts/ieo/ http://www.eia.gov/forecasts/ieo/ .
S. Kumar , M. Y. Wani , C. T. Arranja , J. de A.e Silva , B. Avula , A. J. F. N. Sobral . Porphyrins as nanoreactors in the carbon dioxide capture and conversion:a review . J. Mater. Chem. A , 2015 . 3 19615 - 19637 . DOI: 10.1039/C5TA05082K http://doi.org/10.1039/C5TA05082K .
X. B. Lu , D. J. Darensbourg . Cobalt catalysts for the coupling of CO 2 and epoxides to provide polycarbonates and cyclic carbonates . Chem. Soc. Rev. , 2012 . 41 1462 - 1484 . DOI: 10.1039/C1CS15142H http://doi.org/10.1039/C1CS15142H .
M. R. Kember , A. Buchard , C. K. Williams . Catalysts for CO 2 /epoxide copolymerisation . Chem. Commun. , 2011 . 47 141 - 163 . DOI: 10.1039/C0CC02207A http://doi.org/10.1039/C0CC02207A .
G. Q. Chen , M. K. Patel . Plastics derived from biological sources:present and future:a technical and environmental review . Chem. Rev. , 2012 . 112 2082 - 2099 . DOI: 10.1021/cr200162d http://doi.org/10.1021/cr200162d .
G. Trott , P. K. Saini , C. K. Williams . Catalysts for CO 2 /epoxide ring-opening copolymerization . Philos. Trans. A Math. Phys. Eng. Sci. , 2016 . 374 DOI: 10.1098/rsta.2015.0085 http://doi.org/10.1098/rsta.2015.0085 .
J. Langanke , A. Wolf , J. Hofmann , K. Böhm , M. A. Subhani , T. E. Müller , W. Leitner , C. Gürtler . Carbon dioxide (CO 2 ) as sustainable feedstock for polyurethane production . Green Chem. , 2014 . 16 1865 - 1870 . DOI: 10.1039/C3GC41788C http://doi.org/10.1039/C3GC41788C .
W. Zhang , L. Lu , Y. Cheng , N. Xu , L. Pan , Q. Lin , Y. Wang . Clean and rapid synthesis of double metal cyanide complexes using mechanochemistry . Green Chem. , 2011 . 13 2701 - 2703 . DOI: 10.1039/c1gc15557a http://doi.org/10.1039/c1gc15557a .
Y. Z. Meng , W. Wan , M. Xiao , A. S. Hay . Synthesis of metallophthalocyanine end-capped polymers and their catalytic activity for the copolymerization of CO 2 and propylene oxide . Green Chem. , 2004 . 6 249 - 253 . DOI: 10.1039/b400624k http://doi.org/10.1039/b400624k .
X. B. Lu , L. Shi , Y. M. Wang , R. Zhang , Y. J. Zhang , X. J. Peng , Z. C. Zhang , B. Li . Design of highly active binary catalyst systems for CO 2 /epoxide copolymerization:polymer selectivity, enantioselectivity, and stereochemistry control . J. Am. Chem. Soc. , 2006 . 128 1664 - 1674 . DOI: 10.1021/ja056383o http://doi.org/10.1021/ja056383o .
J. Wang , H. Zhang , Y. Miao , L. Qiao , X. Wang , F. Wang . Waterborne polyurethanes from CO 2 based polyols with comprehensive hydrolysis/oxidation resistance . Green Chem. , 2016 . 18 524 - 530 . DOI: 10.1039/C5GC01373A http://doi.org/10.1039/C5GC01373A .
N. von der Assen , A. Bardow . Life cycle assessment of polyols for polyurethane production using CO 2 as feedstock:insights from an industrial case study . Green Chem. , 2014 . 16 3272 - 3280 . DOI: 10.1039/C4GC00513A http://doi.org/10.1039/C4GC00513A .
S. Inoue , H. Koinuma , T. Tsuruta . Copolymerization of carbon dioxide and epoxide . J. Polym. Sci. B , 1969 . 7 287 - 292 . DOI: 10.1002/pol.1969.110070408 http://doi.org/10.1002/pol.1969.110070408 .
D. J. Darensbourg , S. J. Wilson . What's new with CO 2 ? Recent advances in its copolymerization with oxiranes . Green Chem. , 2012 . 14 2665 - 2671 . DOI: 10.1039/c2gc35928f http://doi.org/10.1039/c2gc35928f .
X. L. Lu , F. G. Du , X. C. Ge , M. Xiao , Y. Z. Meng . Biodegradability and thermal stability of poly(propylene carbonate)/starch composites . J. Biomed. Mater. Res. A , 2006 . 77 653 - 658 . http://new.med.wanfangdata.com.cn/Paper/Detail?id=PeriodicalPaper_JJ024711511 http://new.med.wanfangdata.com.cn/Paper/Detail?id=PeriodicalPaper_JJ024711511 , .
Allen, S. D., 2012, U. S. Pat., 8, 748, 555.
X. Zhong , F. Dehghani . Fabrication of biomimetic poly(propylene carbonate) scaffolds by using carbon dioxide as a solvent, monomer and foaming agent . Green Chem. , 2012 . 14 2523 - 2533 . DOI: 10.1039/c2gc35608b http://doi.org/10.1039/c2gc35608b .
G. Kim , M. Ree , H. Kim , I. J. Kim , J. R. Kim , J. I. Lee . Biological affinity and biodegradability of poly(propylene carbonate) prepared from copolymerization of carbon dioxide with propylene oxide . Macromol. Res. , 2008 . 16 473 - 480 . DOI: 10.1007/BF03218547 http://doi.org/10.1007/BF03218547 .
Jiang, C., Zheng, H. D., Zhang, M. ; Zhu, Y. W., 2015, CN Pat., 104, 693, 773.
Y. Chen , Z. Liu , S. Han , J. Han , D. Jiang . Poly(propylene carbonate) polyurethane self-polishing coating for marine antifouling application . J. Appl. Polym. Sci. , 2016 . 133 DOI: 10.1002/app.43667 http://doi.org/10.1002/app.43667 .
Jiang, W., Cui, X. H. ; Cui, J., 2016, CN Pat., 105, 802, 330.
M. Taherimehr , P. P. Pescarmona . Green polycarbonates prepared by the copolymerization of CO 2 with epoxides . J. Appl. Polym. Sci. , 2014 . 131 DOI: 10.1002/app.41141 http://doi.org/10.1002/app.41141 .
P. Waites . Moisture-curing reactive polyurethane hot-melt adhesives . Pigm. Resin Technol. , 1997 . 26 300 - 303 . DOI: 10.1108/03699429710177690 http://doi.org/10.1108/03699429710177690 .
Q. Tang , J. He , R. Yang , Q. Ai . Study of the synthesis and bonding properties of reactive hot-melt polyurethane adhesive . J. Appl. Polym. Sci. , 2013 . 128 2152 - 2161 . http://onlinelibrary.wiley.com/doi/10.1002/app.38415/full http://onlinelibrary.wiley.com/doi/10.1002/app.38415/full , .
T. K. Kim , B. K. Kim , Y. S. Kim , Y. L. Cho , S. Y. Lee , Y. B. Cho , J. H. Kim , H. M. Jeong . The properties of reactive hot melt polyurethane adhesives modified with novel thermoplastic polyurethanes . J. Appl. Polym. Sci. , 2009 . 114 1169 - 1175 . DOI: 10.1002/app.v114:2 http://doi.org/10.1002/app.v114:2 .
J. S. Jung , J. H. Kim , M. S. Kim , H. M. Jeong , Y. S. Kim , T. K. Kim , J. M. Hwang , S. Y. Lee , Y. L. Cho . Properties of reactive hot melt polyurethane adhesives with acrylic polymer or macromonomer modifications . J. Appl. Polym. Sci. , 2008 . 109 1757 - 1763 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .
Y. J. Cui , L. Hong , X. L. Wang , X. Z. Tang . Evaluation of the cure kinetics of isocyanate reactive hot-melt adhesives with differential scanning calorimetry . J. Appl. Polym. Sci. , 2003 . 89 2708 - 2713 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .
J. Comyn , F. Brady , R. A. Dust , M. Graham , A. Haward . Mechanism of moisture-cure of isocyanate reactive hot melt adhesives . Int. J. Adhes. Adhes. , 1998 . 18 51 - 60 . DOI: 10.1016/S0143-7496(98)80004-3 http://doi.org/10.1016/S0143-7496(98)80004-3 .
Y. J. Cui , D. H. Chen , X. L. Wang , X. Z. Tang . Crystalline structure in isocyanate reactive hot melt adhesives . Int. J. Adhes. Adhes. , 2002 . 22 317 - 322 . DOI: 10.1016/S0143-7496(02)00010-6 http://doi.org/10.1016/S0143-7496(02)00010-6 .
Y. B. Cho , H. M. Jeong , B. K. Kim . Reactive hot melt polyurethane adhesives modified by acrylic copolymer nanocomposites . Macromol. Res. , 2009 . 17 879 - 885 . DOI: 10.1007/BF03218630 http://doi.org/10.1007/BF03218630 .
T. K. Kim , B. K. Kim , Y. S. Kim , Y. L. Cho , S. Y. Lee , Y. B. Cho , H. M. Jeong . The Properties of reactive hot melt polyurethane adhesives:effects of molecular weight and reactive organoclay . Polym-Plast Technol , 2009 . 48 932 - 938 . DOI: 10.1080/03602550902995034 http://doi.org/10.1080/03602550902995034 .
Y. Xu , Z. Petrovic , S. Das , G. L. Wilkes . Morphology and properties of thermoplastic polyurethanes with dangling chains in ricinoleate-based soft segments . Polymer , 2008 . 49 4248 - 4258 . DOI: 10.1016/j.polymer.2008.07.027 http://doi.org/10.1016/j.polymer.2008.07.027 .
A. Kultys , M. Rogulska , H. Głuchowska . The effect of soft-segment structure on the properties of novel thermoplastic polyurethane elastomers based on an unconventional chain extender . Polym. Int. , 2011 . 60 652 - 659 . DOI: 10.1002/pi.v60.4 http://doi.org/10.1002/pi.v60.4 .
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