Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions

Wei Zhao; Jia Qiao; Tian-Li Ning; Xi-Kui Liu

doi:10.1007/s10118-018-2010-5

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Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions

Rapid Communications | Updated：2021-02-18

- Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions
- Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions
- Chinese Journal of Polymer Science 2018年36卷第1期页码：1-7
- Affiliations：
  
  1.College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  Xi-Kui Liu, E-mail xkliu@scu.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2010-5
  中图分类号：
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Wei Zhao, Jia Qiao, Tian-Li Ning, 等. Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions[J]. Chinese Journal of Polymer Science, 2018,36(1):1-7.

Wei Zhao, Jia Qiao, Tian-Li Ning, et al. Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions[J]. Chinese Journal of Polymer Science, 2018,36(1):1-7.
Wei Zhao, Jia Qiao, Tian-Li Ning, 等. Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions[J]. Chinese Journal of Polymer Science, 2018,36(1):1-7. DOI： 10.1007/s10118-018-2010-5.

Wei Zhao, Jia Qiao, Tian-Li Ning, et al. Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions[J]. Chinese Journal of Polymer Science, 2018,36(1):1-7. DOI： 10.1007/s10118-018-2010-5.

摘要

Abstract

A novel scale-up ambient pressure synthetic strategy for the preparation of imine-based covalent organic frameworks (COFs) was proposed through dynamic imine exchange reaction mechanism. The obtained COFs exhibited good crystallinity and much higher porosity comparable to their solvothermally synthesized counterparts. Moreover, under ambient pressure, the COF nanofibers could readily grow on the surface of polyimide films, and the resulted nanocomposite film showed an interesting colorimetric acid-responsive behavior.

关键词

Keywords

Covalent organic frameworks (COFs)Dynamic imine exchangeAmbient pressure synthesis

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Morphology Engineering for Covalent Organic Frameworks (COFs) by Surfactant Mediation and Acid Adjustment

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