A Facile Method for Dye and Heavy Metal Elimination by pH Sensitive Acid Activated Montmorillonite/Polyethersulfone Nanocomposite Membrane

Mehdi Mahmoudian; Peyman Gozali Balkanloo; Ehsan Nozad

doi:10.1007/s10118-018-2004-3

Your Location：

Home >

Browse articles >

A Facile Method for Dye and Heavy Metal Elimination by pH Sensitive Acid Activated Montmorillonite/Polyethersulfone Nanocomposite Membrane

PAPERS | Updated：2021-02-18

- A Facile Method for Dye and Heavy Metal Elimination by pH Sensitive Acid Activated Montmorillonite/Polyethersulfone Nanocomposite Membrane
- A Facile Method for Dye and Heavy Metal Elimination by pH Sensitive Acid Activated Montmorillonite/Polyethersulfone Nanocomposite Membrane
- Chinese Journal of Polymer Science 2018年36卷第1期页码：49-57
- Affiliations：
  
  Nanotechnology Research Institute, Urmia University, Urmia, Iran
- Author bio：
  
  Mehdi Mahmoudian, m.mahmoudian@urmia.ac.ir
- Funds：
- DOI：10.1007/s10118-018-2004-3
  中图分类号：
- 收稿：2017-05-29，
  
  修回：2017-7-3，
  
  录用：2017-7-3，
  
  网络首发：2017-11-16，
  
  纸质出版：2018-01-05
- Accepted：
Scan QR Code
Mehdi Mahmoudian, Peyman Gozali Balkanloo, Ehsan Nozad. A Facile Method for Dye and Heavy Metal Elimination by pH Sensitive Acid Activated Montmorillonite/Polyethersulfone Nanocomposite Membrane[J]. Chinese Journal of Polymer Science, 2018,36(1):49-57.

Mehdi Mahmoudian, Peyman Gozali Balkanloo, Ehsan Nozad. A Facile Method for Dye and Heavy Metal Elimination by pH Sensitive Acid Activated Montmorillonite/Polyethersulfone Nanocomposite Membrane[J]. Chinese Journal of Polymer Science, 2018, 36(1): 49-57.
Mehdi Mahmoudian, Peyman Gozali Balkanloo, Ehsan Nozad. A Facile Method for Dye and Heavy Metal Elimination by pH Sensitive Acid Activated Montmorillonite/Polyethersulfone Nanocomposite Membrane[J]. Chinese Journal of Polymer Science, 2018,36(1):49-57. DOI： 10.1007/s10118-018-2004-3.

Mehdi Mahmoudian, Peyman Gozali Balkanloo, Ehsan Nozad. A Facile Method for Dye and Heavy Metal Elimination by pH Sensitive Acid Activated Montmorillonite/Polyethersulfone Nanocomposite Membrane[J]. Chinese Journal of Polymer Science, 2018, 36(1): 49-57. DOI： 10.1007/s10118-018-2004-3.

摘要

Abstract

Modified clay/polyethersulfone (PES) mixed matrix membranes (MMMs) were prepared by acid activated montmorillonite (AA-MMT) with different concentrations and used to eliminate dyes and remove heavy metals from aqueous solution. The morphology and physiochemical properties of prepared clay nanoparticles and MMMs were characterized using X-ray diffraction (XRD)

Fourier transform infrared (FTIR) spectroscopy

scanning electron microscopy (SEM)

enegy dispersive X-ray (EDX) spectroscopy

Brunauer-Emmett-Teller (BET) analysis

atomic force microscopy (AFM)

contact angle measurement and fouling studies. The filtration study showed that removal of dyes and heavy metals was strongly dependent on pH so that dyes with positive and negative charges showed different separation efficiency in acidic and alkaline conditions. The modified membranes possessed better heavy metal removal in acidic and alkaline pHs. When the rejection of heavy metals was measured in an alkaline environment

it was observed that the rejection had a great increase compared to the neutral values for Zn

and Ni

ions

while rejection of Cu

and Cd

did not undergo significant changes. So it can be concluded that modified membranes show good selectivity for elimination of Zn

and Ni

ions with respect to other cations.

关键词

Keywords

references

C. Mbareck , Q. T. Nguyen , O. T. Alaoui , D. Barillier . Elaboration, characterization and application of polysulfone and polyacrylic acid blends as ultrafiltration membranes for removal of some heavy metals from wate . J. Hazard. Mater. , 2009 . 171 ( 1 ): 93 - 101 . http://www.sciencedirect.com/science/article/pii/S0304389409008796 http://www.sciencedirect.com/science/article/pii/S0304389409008796 , .

M. Peter-Varbanets , C. Zurbrügg , C. Swartz , W. Pronk . Decentralized systems for potable water and the potential of membrane technology . Water Res. , 2009 . 43 ( 2 ): 245 - 265 . DOI: 10.1016/j.watres.2008.10.030 http://doi.org/10.1016/j.watres.2008.10.030 .

S. K. Sikdar , D. Grosse , I. Rogut . Membrane technologies for remediating contaminated soils:a critical review . J. Membr. Sci. , 1998 . 151 ( 1 ): 75 - 85 . DOI: 10.1016/S0376-7388(98)00189-6 http://doi.org/10.1016/S0376-7388(98)00189-6 .

Y. Sato , M. Kang , T. Kamei , Y. Magara . Performance of nanofiltration for arsenic removal . Water Res. , 2002 . 36 ( 13 ): 3371 - 3377 . DOI: 10.1016/S0043-1354(02)00037-4 http://doi.org/10.1016/S0043-1354(02)00037-4 .

J. Yin , B. Deng . Polymer-matrix nanocomposite membranes for water treatment . J. Membr. Sci. , 2015 . 479 256 - 275 . DOI: 10.1016/j.memsci.2014.11.019 http://doi.org/10.1016/j.memsci.2014.11.019 .

K. S. Novoselov , A. K. Geim , S. V. Morozov , D. Jiang , Y. Zhang , S. V. Dubonos , I. V. Grigorieva , A. A. Firsov . Electric field effect in atomically thin carbon films . Science , 2004 . 306 ( 5696 ): 666 - 669 . DOI: 10.1126/science.1102896 http://doi.org/10.1126/science.1102896 .

F. Ran , S. Nie , W. Zhao , J. Li , B. Su , S. Sun , C. Zhao . Biocompatibility of modified polyethersulfone membranes by blending an amphiphilic triblock co-polymer of poly(vinyl pyrrolidone)- b -poly(methyl methacrylate)- b -poly(vinyl pyrrolidone) . Acta Bio. , 2011 . 7 ( 9 ): 3370 - 3381 . DOI: 10.1016/j.actbio.2011.05.026 http://doi.org/10.1016/j.actbio.2011.05.026 .

D. Li , M. B. Mueller , S. Gilje , R. B. Kaner , G. G. Wallace . Processable aqueous dispersions of graphene nanosheets . Nat. Nanotechnol. , 2008 . 3 101 - 105 . DOI: 10.1038/nnano.2007.451 http://doi.org/10.1038/nnano.2007.451 .

W. Zhao , J. Huang , B. Fang , S. Nie , N. Yi , B. Su , H. Li , C. Zhao . Modification of polyethersulfone membrane by blending semi-interpenetrating network polymeric nanoparticles . J. Membr. Sci. , 2011 . 369 ( 1 ): 258 - 266 . https://www.sciencedirect.com/science/article/pii/S0376738810009348 https://www.sciencedirect.com/science/article/pii/S0376738810009348 , .

L. Duan , Q. Zhao , J. Liu , Y. Zhang . Antibacterial behavior of halloysite nanotubes decorated with copper nanoparticles in a novel mixed matrix membrane for water purification . Environ. Sci.:Water Res. Technol. , 2015 . 1 ( 6 ): 874 - 881 . DOI: 10.1039/C5EW00140D http://doi.org/10.1039/C5EW00140D .

Q. Zhao , J. Hou , J. Shen , J. Liu , Y. Zhang . Long-lasting antibacterial behavior of a novel mixed matrix water purification membrane . J. Mater. Chem. A , 2015 . 3 ( 36 ): 18696 - 18705 . DOI: 10.1039/C5TA06013C http://doi.org/10.1039/C5TA06013C .

Q. Zhao , C. Liu , J. Liu , Y. Zhang . Development of a novel polyethersulfone ultrafiltration membrane with antibacterial activity and high flux containing halloysite nanotubes loaded with lysozyme . RSC Adv. , 2015 . 5 ( 48 ): 38646 - 38653 . DOI: 10.1039/C5RA05062F http://doi.org/10.1039/C5RA05062F .

C. Y. Liang , P. Uchytil , R. Petrychkovych , Y. C. Lai , K. Friess , M. Sipek , M. M. Reddya , S. Y. Suen . A comparison on gas separation between PES (polyethersulfone)/MMT (Na-montmorillonite) and PES/TiO 2 mixed matrix membranes . Sep. Purif. Technol. , 2012 . 92 57 - 63 . DOI: 10.1016/j.seppur.2012.03.016 http://doi.org/10.1016/j.seppur.2012.03.016 .

P. Daraei , S. S. Madaeni , E. Salehi , N. Ghaemic , H. Sadeghi Gharid , M. A. Khadivif , E. Rostami . Novel thin film composite membrane fabricated by mixed matrix nanoclay/chitosan on PVDF microfiltration support:preparation, characterization and performance in dye removal . J. Membr. Sci. , 2013 . 436 97 - 108 . DOI: 10.1016/j.memsci.2013.02.031 http://doi.org/10.1016/j.memsci.2013.02.031 .

A. K. Zulhairun , A. F. Ismail , T. Matsuura , M. S. Abdullah , A. Mustafa . Asymmetric mixed matrix membrane incorporating organically modified clay particle for gas separation . Chem. Eng. J. , 2014 . 241 495 - 503 . DOI: 10.1016/j.cej.2013.10.042 http://doi.org/10.1016/j.cej.2013.10.042 .

L. Zatta , L. P. Ramos , F. Wypych . Acid-activated montmorillonites as heterogeneous catalysts for the esterification of lauric acid acid with methanol . Appl. Clay Sci. , 2013 . 80 236 - 244 . https://www.sciencedirect.com/science/article/pii/S0169131713001221 https://www.sciencedirect.com/science/article/pii/S0169131713001221 , .

H. Babaki , A. Salem , A. Jafarizad . Kinetic model for the isothermal activation of bentonite by sulfuric acid . Mater. Chem. Phys. , 2008 . 108 ( 2 ): 263 - 268 . http://www.sciencedirect.com/science/article/pii/S0254058407005986 http://www.sciencedirect.com/science/article/pii/S0254058407005986 , .

T. H. Wang , T. Y. Liu , D. C. Wu , M. H. Li , J. R. Chen , S. P. Teng . Performance of phosphoric acid activated montmorillonite as buffer materials for radioactive waste repository . J. Hazard. Mater. , 2010 . 173 ( 1 ): 335 - 342 . https://www.sciencedirect.com/science/article/pii/S0304389409013843 https://www.sciencedirect.com/science/article/pii/S0304389409013843 , .

K. G. Bhattacharyya , S. S. M. Gupta . Influence of acid activation on adsorption of Ni(Ⅱ) and Cu(Ⅱ) on kaolinite and montmorillonite:kinetic and thermodynamic study . Chem. Eng. J. , 2008 . 136 ( 1 ): 1 - 13 . DOI: 10.1016/j.cej.2007.03.005 http://doi.org/10.1016/j.cej.2007.03.005 .

X. Guo , Y. Yao , G. Yin , Y. Kang , Y. Luo , L. Zhuo . Preparation of decolorizing ceramsites for printing and dyeing wastewater with acid and base treated clay . Appl. Clay Sci. , 2008 . 40 ( 1 ): 20 - 26 . https://www.sciencedirect.com/science/article/pii/S0169131707001330 https://www.sciencedirect.com/science/article/pii/S0169131707001330 , .

S. K. Bharadwaj , P. K. Boruah , P. K. Gogoi . Phosphoric acid modified montmorillonite clay:a new heterogeneous catalyst for nitration of arenes . Catal. Commun. , 2014 . 57 124 - 128 . DOI: 10.1016/j.catcom.2014.08.019 http://doi.org/10.1016/j.catcom.2014.08.019 .

M. Kumar , Z. Gholamvand , A. Morrissey , K. Nolan , M. Ulbricht , J. Lawler . Preparation and characterization of low fouling novel hybrid ultrafiltration membranes based on the blends of GO-TiO 2 nanocomposite and polysulfone for humic acid removal . J. Membr. Sci. , 2016 . 506 38 - 49 . DOI: 10.1016/j.memsci.2016.02.005 http://doi.org/10.1016/j.memsci.2016.02.005 .

Y. Ma , F. Shi , Z. Wang , M. Wu , J. Ma , C. Gao . Preparation and characterization of PSf/clay nanocomposite membranes with PEG 400 as a pore forming additive . Desalination , 2012 . 286 131 - 137 . DOI: 10.1016/j.desal.2011.10.040 http://doi.org/10.1016/j.desal.2011.10.040 .

N. Abdullah , R. J. Gohari , N. Yusof , A. F. Ismaila , J. Juhanaa , W. J. Laua , T. Matsuura . Polysulfone/hydrous ferric oxide ultrafiltration mixed matrix membrane:preparation, characterization and its adsorptive removal of lead(Ⅱ) from aqueous solution . Chem. Eng. J. , 2016 . 289 28 - 37 . DOI: 10.1016/j.cej.2015.12.081 http://doi.org/10.1016/j.cej.2015.12.081 .

C. Barth , M. C. Gonçalves , A. T. N. Pires , J. Roeder , B. A. Wolf . Asymmetric polysulfone and polyethersulfone membranes:effects of thermodynamic conditions during formation on their performance . J. Membr. Sci. , 2000 . 169 ( 2 ): 287 - 299 . DOI: 10.1016/S0376-7388(99)00344-0 http://doi.org/10.1016/S0376-7388(99)00344-0 .

S. Zinadini , V. Vatanpour , A. A. Zinatizadeh , M. Rahimi , Z. Rahimi , M. Kian . Preparation and characterization of antifouling graphene oxide/polyethersulfone ultrafiltration membrane:application in MBR for dairy wastewater treatment . J. Water Pro. Eng. , 2015 . 7 280 - 294 . DOI: 10.1016/j.jwpe.2015.07.005 http://doi.org/10.1016/j.jwpe.2015.07.005 .

R. Ding , R. Zhang , Y. Li , J. Wang , B. Shi , H. Mao , J. Dang , J. Liu . Graphene oxide-embedded nanocomposite membrane for solvent resistant nanofiltration with enhanced rejection ability . Chem. Eng. Sci. , 2015 . 138 227 - 238 . DOI: 10.1016/j.ces.2015.08.019 http://doi.org/10.1016/j.ces.2015.08.019 .

M. Liu , S. Yu , Z. Yong , C. Cao . Study on the thin-film composite nanofiltration membrane for the removal of sulfate from concentrated salt aqueous:preparation and performance . J. Membr. Sci. , 2008 . 310 ( 1 ): 289 - 295 . http://www.sciencedirect.com/science/article/pii/S0376738807008009 http://www.sciencedirect.com/science/article/pii/S0376738807008009 , .

G.N. B. Baroña , J. Lim , B. Jung . High performance thin film composite polyamide reverse osmosis membrane prepared via m-phenylenediamine and 2, 2'-benzidinedisulfonic acid . Desalination , 2012 . 291 69 - 77 . DOI: 10.1016/j.desal.2012.02.001 http://doi.org/10.1016/j.desal.2012.02.001 .

Y. C. Chiang , Y. Z. Hsub , R. C. Ruaan , C. J. Chuang , K. L. Tung . Nanofiltration membranes synthesized from hyperbranched polyethyleneimine . J. Membr. Sci. , 2009 . 326 ( 1 ): 19 - 26 . DOI: 10.1016/j.memsci.2008.09.021 http://doi.org/10.1016/j.memsci.2008.09.021 .

C. A. Crock , A. R. Rogensues , W. Shan , V. V. Tarabara . Polymer nanocomposites with graphene-based hierarchical fillers as materials for multifunctional water treatment membranes . Water. Res. , 2013 . 47 ( 12 ): 3984 - 3996 . DOI: 10.1016/j.watres.2012.10.057 http://doi.org/10.1016/j.watres.2012.10.057 .

B. M. Ganesh , A. M. Isloor , A. F. Ismail . Enhanced hydrophilicity and salt rejection study of graphene oxide-polysulfone mixed matrix membrane . Desalination , 2013 . 313 199 - 207 . DOI: 10.1016/j.desal.2012.11.037 http://doi.org/10.1016/j.desal.2012.11.037 .

Y. S. Al-Degs , M. I. El-Barghouthi , A. H. El-Sheikh , G. M. Walker . Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon . Dyes Pigments , 2008 . 77 ( 1 ): 16 - 23 . DOI: 10.1016/j.dyepig.2007.03.001 http://doi.org/10.1016/j.dyepig.2007.03.001 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Tunable Circularly Polarized Luminescence of Helical Poly(phenylacetylene)s via Side-chain-to-Backbone Förster Resonance Energy Transfer

Molecular Segregation and Melt Memory in Dilute Polycaprolactone with Reduced Entanglements

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

Advances in Polymer-based Circularly Polarized Luminescent Materials