Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(<italic style="font-style: italic">ε</italic>-caprolactone) Side Chains

Houluo Cong; Sen Xu; Sixun Zheng

doi:10.1007/s10118-017-2001-y

Your Location：

Home >

Browse articles >

Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains

Papers | Updated：2021-02-18

- Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains
- Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains
- 高分子科学（英文版） 2017年35卷第12期页码：1572-1586
- Affiliations：
  
  Department of Polymer Science and Engineering and the State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
- Author bio：
  
  Sixun Zheng (郑思珣), E-mail:szheng@sjtu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51133003);the National Natural Science Foundation of China(21274091);the National Natural Science Foundation of China(21774078);the Shanghai Synchrotron Radiation Facility under the projects(10sr0260);the Shanghai Synchrotron Radiation Facility under the projects(10sr0126)
- DOI：10.1007/s10118-017-2001-y
  中图分类号：
- 收稿：2017-05-16，
  
  修回：2017-06-25，
  
  录用：2017-06-28，
  
  纸质出版：2017-12-05
- Accepted：
Scan QR Code
Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains[J]. 高分子科学（英文版）, 2017,35(12):1572-1586. DOI: 10.1007/s10118-017-2001-y.

Houluo Cong, Sen Xu, Sixun Zheng. Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1572-1586. DOI: 10.1007/s10118-017-2001-y.
Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains[J]. 高分子科学（英文版）, 2017,35(12):1572-1586. DOI: 10.1007/s10118-017-2001-y. DOI：

Houluo Cong, Sen Xu, Sixun Zheng. Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1572-1586. DOI: 10.1007/s10118-017-2001-y. DOI：

摘要

Abstract

A series of mixed

random cylindrical brush copolymers bearing polystyrene (PS) and poly(

-caprolactone) (PCL) side chains were synthesized

via

the combination of ring-opening polymerization (ROP) and atom transfer radical polymerization (ATRP). These novel cylindrical brush copolymers have been characterized by means of nuclear magnetic resonance (NMR) spectroscopy

gel permeation chromatography (GPC) and differential scanning calorimetry (DSC). It was found that the mikto-armed cylindrical brush copolymers were microphase-separated in bulks and that the morphologies were dependent on the mass ratios of PS to PCL side chains. One of the cylindrical brush copolymers was employed to incorporate into epoxy thermoset to investigate effect of the mikto-armed cylindrical brush architecture on the reaction-induced microphase separation behavior. Depending on the concentration of the cylindrical brush in epoxy

the thermosets can display the morphologies with the spherical

worm-like and lamellar PS microdomains dispersing in continuous thermosetting matrices.

关键词

Keywords

references

S.S. Sheiko , B.S. Sumerlin , K. Matyjaszewski . Prog. Polym. Sci. , 2008 . 33 ( 7 ): 759 DOI: 10.1016/j.progpolymsci.2008.05.001 http://doi.org/10.1016/j.progpolymsci.2008.05.001 .

H.I. Lee , J. Pietrasik , S.S. Sheiko , K. Matyjaszewski . Prog. Polym. Sci. , 2010 . 35 ( 1 ): 24 http://www.sciencedirect.com/science/article/pii/S0079670009001087 http://www.sciencedirect.com/science/article/pii/S0079670009001087 , .

J. Rzayev . ACS Macro Lett. , 2012 . 1 ( 9 ): 1146 DOI: 10.1021/mz300402x http://doi.org/10.1021/mz300402x .

I. Park , D. Shirvanyants , A. Nese , K. Matyjaszewski , M. Rubinstein , S.S. Sheiko . J. Am. Chem. Soc. , 2010 . 132 ( 35 ): 12487 DOI: 10.1021/ja105897b http://doi.org/10.1021/ja105897b .

K. Huang , J. Rzayev . J. Am. Chem. Soc. , 2009 . 131 ( 19 ): 6880 DOI: 10.1021/ja901936g http://doi.org/10.1021/ja901936g .

K. Huang , D.P. Canterbury , Rzayev . J. Macromolecules , 2010 . 43 ( 16 ): 6632 DOI: 10.1021/ma100971w http://doi.org/10.1021/ma100971w .

M. Zhang , A.H.E. Müller . J. Polym. Sci., Part A:Polym. Chem. , 2005 . 43 ( 16 ): 3461 DOI: 10.1002/(ISSN)1099-0518 http://doi.org/10.1002/(ISSN)1099-0518 .

Z. Li , J. Ma , N.S. Lee , K.L. Wooley . J. Am. Chem. Soc. , 2011 . 133 ( 5 ): 1228 DOI: 10.1021/ja109191z http://doi.org/10.1021/ja109191z .

G. Sun , S. Cho , C. Clark , S.V. Verkhoturov , M.J. Eller , A. Li , A. Pavía-Jiménez , E.A. Schweikert , J.W. Thackeray , P. Trefonas , K.L. Wooley . J. Am. Chem. Soc. , 2013 . 135 ( 11 ): 4203 DOI: 10.1021/ja3126382 http://doi.org/10.1021/ja3126382 .

C. Cheng , E. Khoshdel , K.L. Wooley . Macromolecules , 2007 . 40 ( 7 ): 2289 DOI: 10.1021/ma0627525 http://doi.org/10.1021/ma0627525 .

Z. Li , J. Ma , C. Cheng , K. Zhang , K.L. Wooley . Macromolecules , 2010 . 43 ( 3 ): 1182 DOI: 10.1021/ma902513n http://doi.org/10.1021/ma902513n .

J.A. Johnson , Y. Lu , A.O. Burts , Y.H. Lim , M.G. Finn , J.T. Koberstein , N.J. Turro , D.A. Tirrell , R.H. Grubbs . J. Am. Chem. Soc. , 2011 . 133 ( 3 ): 559 DOI: 10.1021/ja108441d http://doi.org/10.1021/ja108441d .

M. Hu , Y. Xia , G.B. McKenna , J.A. Kornfield , R.H. Grubbs . Macromolecules , 2011 . 44 ( 17 ): 6935 DOI: 10.1021/ma2009673 http://doi.org/10.1021/ma2009673 .

Y. Xia , B.D. Olsen , J.A. Kornfield , R.H. Grubbs . J. Am. Chem. Soc. , 2009 . 131 ( 51 ): 18525 DOI: 10.1021/ja908379q http://doi.org/10.1021/ja908379q .

C. Cheng , E. Khoshdel , K.L. Wooley . Nano Lett. , 2006 . 6 ( 8 ): 1741 DOI: 10.1021/nl0611900 http://doi.org/10.1021/nl0611900 .

W. Gu , J. Huh , S. Hong , B.R. Sveinbjornsson , C. Park , R.H. Grubbs , T.P. Russell . ACS Nano , 2013 . 7 ( 3 ): 2551 DOI: 10.1021/nn305867d http://doi.org/10.1021/nn305867d .

C. Cheng , K. Qi , E. Khoshdel , K.L. Wooley . J. Am. Chem. Soc. , 2006 . 128 ( 21 ): 6808 DOI: 10.1021/ja061892r http://doi.org/10.1021/ja061892r .

J. Bolton , T.S. Bailey , J. Rzayev . Nano Lett. , 2011 . 11 ( 3 ): 998 DOI: 10.1021/nl103747m http://doi.org/10.1021/nl103747m .

C. Li , N. Gunari , K. Fischer , A. Janshoff , M. Schmidt . Angew. Chem. , 2004 . 43 ( 9 ): 1101 DOI: 10.1002/(ISSN)1521-3773 http://doi.org/10.1002/(ISSN)1521-3773 .

R. Djalali , S. Li , M. Schmidt . Macromolecules , 2002 . 35 ( 11 ): 4282 DOI: 10.1021/ma0113733 http://doi.org/10.1021/ma0113733 .

M. Zhang , M. Drechsler , A.H.E. Müller . Chem. Mater. , 2004 . 16 ( 3 ): 537 DOI: 10.1021/cm034760v http://doi.org/10.1021/cm034760v .

M. Zhang , C. Estournès , W. Bietsch , A.H.E. Müller . Adv. Funct. Mater. , 2004 . 14 ( 9 ): 871 DOI: 10.1002/(ISSN)1616-3028 http://doi.org/10.1002/(ISSN)1616-3028 .

C. Tang , B. Dufour , T. Kowalewski , K. Matyjaszewski . Macromolecules , 2007 . 40 ( 17 ): 6199 DOI: 10.1021/ma070892o http://doi.org/10.1021/ma070892o .

Z. Li , K. Zhang , J. Ma , C. Cheng , K.L. Wooley . J. Polym. Sci., Part A:Polym. Chem. , 2009 . 47 ( 1 ): 2257 http://europepmc.org/abstract/med/20161348 http://europepmc.org/abstract/med/20161348 , .

S. Jha , S. Dutta , N.B. Bowden . Macromolecules , 2004 . 37 ( 12 ): 4365 DOI: 10.1021/ma049647k http://doi.org/10.1021/ma049647k .

Y. Xia , J.A. Kornfield , R.H. Grubbs . Macromolecules , 2009 . 42 ( 11 ): 3761 DOI: 10.1021/ma900280c http://doi.org/10.1021/ma900280c .

H. Gao , K. Matyjaszewski . J. Am. Chem. Soc. , 2007 . 129 ( 20 ): 6633 DOI: 10.1021/ja0711617 http://doi.org/10.1021/ja0711617 .

S.H. Lahasky , W.K. Serem , L. Guo , J.C. Garno , D. Zhang . Macromolecules , 2011 . 44 ( 23 ): 9063 DOI: 10.1021/ma201948u http://doi.org/10.1021/ma201948u .

J. Sun , J. Hu , G. Liu , D. Xiao , G. He , R. Lu . J. Polym. Sci., Part A:Polym. Chem. , 2011 . 49 ( 5 ): 1282 DOI: 10.1002/pola.v49.5 http://doi.org/10.1002/pola.v49.5 .

H. Lee , W. Jakubowski , K. Matyjaszewski , A. Yu , S.S. Sheiko . Macromolecules , 2006 . 39 ( 15 ): 4983 DOI: 10.1021/ma0604688 http://doi.org/10.1021/ma0604688 .

A. Nese , Y. Li , S. Averick , Y. Kwak , D. Konkolewicz , S.S. Sheiko , K. Matyjaszewski . ACS Macro Lett. , 2012 . 1 ( 1 ): 227 DOI: 10.1021/mz200134n http://doi.org/10.1021/mz200134n .

J. Bolton , J. Rzayev . ACS Macro Lett. , 2012 . 1 ( 1 ): 15 DOI: 10.1021/mz200003j http://doi.org/10.1021/mz200003j .

D. Zehm , A. Laschewsky , H. Liang , J.P Rabe . Macromolecules , 2011 . 44 ( 24 ): 9635 DOI: 10.1021/ma2015613 http://doi.org/10.1021/ma2015613 .

M. Zhang , T. Breiner , H. Mori , A.H.E. Müller . Polymer , 2003 . 44 ( 5 ): 1449 DOI: 10.1016/S0032-3861(02)00774-7 http://doi.org/10.1016/S0032-3861(02)00774-7 .

H.G. Boerner , K. Beers , K. Matyjaszewski . Macromolecules , 2001 . 34 ( 13 ): 4375 DOI: 10.1021/ma010001r http://doi.org/10.1021/ma010001r .

H. Cong , L. Li , S. Zheng . Polymer , 2015 . 79 99 DOI: 10.1016/j.polymer.2015.10.014 http://doi.org/10.1016/j.polymer.2015.10.014 .

H. Shinoda , K. Matyjaszewski . Macromol. Rapid Commun. , 2001 . 22 ( 14 ): 1176 DOI: 10.1002/1521-3927(20011001)22:14<1176::AID-MARC1176>3.0.CO;2-J http://doi.org/10.1002/1521-3927(20011001)22:14<1176::AID-MARC1176>3.0.CO;2-J .

S.K. Kim , D.G. Kim , A. Lee , H.S. Sohn , J.J. Wie , N.A. Nguyen , M.E. Mackay , J.C. Lee . Macromolecules , 2012 . 45 ( 23 ): 9347 DOI: 10.1021/ma301404q http://doi.org/10.1021/ma301404q .

M.Y. Zaremski , D.I. Kalugin , V.B. Golubev . Polym. Sci. Ser. A , 2009 . 51 103 DOI: 10.1134/S0965545X09010088 http://doi.org/10.1134/S0965545X09010088 .

L. A. Wood . J. Polym. Sci., Part A:Polym. Chem. , 1958 . 28 ( 117 ): 319 http://onlinelibrary.wiley.com/doi/10.1002/pol.1958.1202811707/full http://onlinelibrary.wiley.com/doi/10.1002/pol.1958.1202811707/full , .

M.J. Brekner , H.A. Schneider , H.J. Cantow . Polymer , 1988 . 29 ( 1 ): 78 DOI: 10.1016/0032-3861(88)90203-0 http://doi.org/10.1016/0032-3861(88)90203-0 .

C. de Rosa , C. Park , E.L. Thomas , B. Lotz . Nature , 2000 . 405 ( 6785 ): 433 DOI: 10.1038/35013018 http://doi.org/10.1038/35013018 .

L. Zhu , B.R. Mimnaugh , Q. Ge , R P. Quirk , S.Z.D. Cheng , E.L. Thomas , B. Lotz , B.S. Hsiao , F. Yeh , L. Liu . Polymer , 2001 . 42 ( 21 ): 9121 DOI: 10.1016/S0032-3861(01)00394-9 http://doi.org/10.1016/S0032-3861(01)00394-9 .

Y.L. Loo , R.A. Register , A.J. Ryan . Macromolecules , 2002 . 35 ( 6 ): 2365 DOI: 10.1021/ma011824j http://doi.org/10.1021/ma011824j .

R.V. Castillo , A.J. Müller , M. Lin , H. Chen , U.S. Jeng , M.A. Hillmyer . Macromolecules , 2008 . 41 ( 16 ): 6154 DOI: 10.1021/ma800859y http://doi.org/10.1021/ma800859y .

H. Tanaka , T. Nishi . Phys. Rev. Lett. , 1985 . 55 ( 10 ): 1102 DOI: 10.1103/PhysRevLett.55.1102 http://doi.org/10.1103/PhysRevLett.55.1102 .

Y. Li , M. Stein , B. Jungnickel . J. Colloid Polym. Sci. , 1991 . 269 ( 8 ): 772 DOI: 10.1007/BF00657443 http://doi.org/10.1007/BF00657443 .

R.M. Briber , F. Khoury . Polymer , 1987 . 28 ( 1 ): 38 DOI: 10.1016/0032-3861(87)90316-8 http://doi.org/10.1016/0032-3861(87)90316-8 .

F. Meng , S. Zheng , H. Li , Q. Liang , T. Liu . Macromolecules , 2006 . 39 ( 15 ): 5072 DOI: 10.1021/ma060004+ http://doi.org/10.1021/ma060004+ .

D.E. Kline . J. Polym. Sci., Part A:Polym. Chem. , 1960 . 47 ( 1 ): 237 http://onlinelibrary.wiley.com/doi/10.1002/pol.1960.1204714921/full http://onlinelibrary.wiley.com/doi/10.1002/pol.1960.1204714921/full , .

L.M. Robeson . Polym. Eng. Sci. , 1969 . 9 ( 4 ): 277 DOI: 10.1002/(ISSN)1548-2634 http://doi.org/10.1002/(ISSN)1548-2634 .

浏览量

316

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Core Structure Modulation of 2D Nanosheets by Selective Crystallization-driven Self-assembly of Polyhedral Oligomeric Silsesquioxane-containing Block Copolymers

Phase Equilibrium Analysis of Ternary Systems Based on an Epoxy Oligomer, Polysulfone, and Tetraethoxysilane

Thermoplastic Liquid Crystal Elastomers Based on ABA-type Triblock Copolymers

Hydrophobicity Regulated Coacervate Droplet Size and the Thermal Protection Against Denaturation of Enzyme

Tunable Circularly Polarized Luminescence of Helical Poly(phenylacetylene)s via Side-chain-to-Backbone Förster Resonance Energy Transfer

Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains

Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains

DOI：10.1007/s10118-017-2001-y

摘要

Abstract

关键词

Keywords

references