Crystallization Kinetics and the Fine Morphological Evolution of Poly(ethylene oxide)/Ionic Liquid Mixtures

Wen-ze Li; Yan-hua Niu; Chen-ting Zhou; Huan Luo; Guang-xian Li

doi:10.1007/s10118-017-1997-3

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Crystallization Kinetics and the Fine Morphological Evolution of Poly(ethylene oxide)/Ionic Liquid Mixtures

Papers | Updated：2021-02-18

- Crystallization Kinetics and the Fine Morphological Evolution of Poly(ethylene oxide)/Ionic Liquid Mixtures
- Crystallization Kinetics and the Fine Morphological Evolution of Poly(ethylene oxide)/Ionic Liquid Mixtures
- Chinese Journal of Polymer Science 2017年35卷第11期页码：1402-1414
- Affiliations：
  
  College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering of China, Sichuan University, Chengdu 610065, China
- Author bio：
  
  Yan-hua Niu (牛艳华), E-mail: yhniu@scu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51573115);the National Natural Science Foundation of China(51421061)
- DOI：10.1007/s10118-017-1997-3
  中图分类号：
- 收稿：2017-03-06，
  
  修回：2017-5-27，
  
  录用：2017-6-16，
  
  纸质出版：2017-11-05
- Accepted：
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Wen-ze Li, Yan-hua Niu, Chen-ting Zhou, 等. Crystallization Kinetics and the Fine Morphological Evolution of Poly(ethylene oxide)/Ionic Liquid Mixtures[J]. Chinese Journal of Polymer Science, 2017,35(11):1402-1414.

Wen-ze Li, Yan-hua Niu, Chen-ting Zhou, et al. Crystallization Kinetics and the Fine Morphological Evolution of Poly(ethylene oxide)/Ionic Liquid Mixtures[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1402-1414.
Wen-ze Li, Yan-hua Niu, Chen-ting Zhou, 等. Crystallization Kinetics and the Fine Morphological Evolution of Poly(ethylene oxide)/Ionic Liquid Mixtures[J]. Chinese Journal of Polymer Science, 2017,35(11):1402-1414. DOI： 10.1007/s10118-017-1997-3.

Wen-ze Li, Yan-hua Niu, Chen-ting Zhou, et al. Crystallization Kinetics and the Fine Morphological Evolution of Poly(ethylene oxide)/Ionic Liquid Mixtures[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1402-1414. DOI： 10.1007/s10118-017-1997-3.

摘要

Abstract

The overall crystallization kinetics and spherulite morphologies of miscible poly(ethylene oxide) (PEO)/1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM] [PF

]) mixtures were studied by differential scanning calorimetry (DSC)

polarized optical microscopy (POM) and rheological measurements. The finer crystal structures were further detected by wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS). Crystallization of PEO is largely suppressed by[BMIM]

[PF

] addition especially at higher ionic liquid (IL) concentrations above 20 wt%. Both the overall crystallization rate and the spherulite growth decrease with the increase of IL content and crystallization temperature; however

the crystallization mechanism keeps unchanged as evidenced by the similar Avrami exponent

and WAXD results. The addition of[BMIM] [PF

] could induce more nuclei to some extent

but the induction time of crystallization is evidently prolonged

and a linear to non-linear transition of the spherulite growth (

∝

1/2

) can be observed. At higher IL concentration

the spherulite texture changes apparently from particular serrated to branch surface due to the diffusion-controlled growth and the dilution effect

which also as a main factor contributes to the increasing trend of the long period of crystals.

关键词

Keywords

references

M. Armand , J.M. Tarascon . Nature , 2008 . 451 652 DOI: 10.1038/451652a http://doi.org/10.1038/451652a .

Jr. D.T. Hallinan , N.P. Balsara . Annu. Rev. Mater. Res. , 2013 . 43 503 DOI: 10.1146/annurev-matsci-071312-121705 http://doi.org/10.1146/annurev-matsci-071312-121705 .

C.N. Sun , T.A. Zawodzinski , W.E. Tenhaeff , F. Ren , J.K. Keum , S. Bi , D. Li , S.K. Ahn , K. Hong , A.J. Rondinone . Phys. Chem. Chem. Phys. , 2015 . 17 8266 DOI: 10.1039/C4CP05583G http://doi.org/10.1039/C4CP05583G .

S. Bi , C.N. Sun , T.A. Zawodzinski , F. Ren , J.K. Keum , S.K. Ahn , D. Li , J. Chen . J. Polym. Sci., Part B:Polym. Phys. , 2015 . 53 1450 DOI: 10.1002/polb.23793 http://doi.org/10.1002/polb.23793 .

D. Fenton , J. Parker , P. Wright . Polymer , 1973 . 14 589 http://www.sciencedirect.com/science/article/pii/0032386173901468 http://www.sciencedirect.com/science/article/pii/0032386173901468 , .

C. Berthier , W. Gorecki , M. Minier , M.B. Armand , J.M. Chabagno . Solid State Ionics , 1983 . 11 91 DOI: 10.1016/0167-2738(83)90068-1 http://doi.org/10.1016/0167-2738(83)90068-1 .

S.K. Fullerton-Shirey , J.K. Maranas . Macromolecules , 2009 . 42 2142 DOI: 10.1021/ma802502u http://doi.org/10.1021/ma802502u .

S. Cheng , D.M. Smith , C.Y. Li . Macromolecules , 2014 . 47 3978 DOI: 10.1021/ma500734q http://doi.org/10.1021/ma500734q .

M. Gopinadhan , P.W. Majewski , C.O. Osuji . Macromolecules , 2010 . 43 3286 DOI: 10.1021/ma9026349 http://doi.org/10.1021/ma9026349 .

R.J. Yue , Y.H. Niu , Z.G. Wang , J.F. Douglas , X.Q. Zhu , E.Q. Chen . Polymer , 2009 . 50 1288 DOI: 10.1016/j.polymer.2009.01.022 http://doi.org/10.1016/j.polymer.2009.01.022 .

W.S. Young , T.H. EppsⅢ . Macromolecules , 2009 . 42 2672 DOI: 10.1021/ma802799p http://doi.org/10.1021/ma802799p .

L.M. Wu , M. Lisowski , S. Talibuddin , J. Runt . Macromolecules , 1999 . 32 1576 DOI: 10.1021/ma981169o http://doi.org/10.1021/ma981169o .

S. Talibuddin , L. Wu , J. Runt , J.S. Lin . Macromolecules , 1996 . 29 7527 DOI: 10.1021/ma960508f http://doi.org/10.1021/ma960508f .

J.L. Lutkenhaus , K.D. Hrabak , K. McEnnis , P.T. Hammond . J. Am. Chem. Soc. , 2005 . 127 17228 DOI: 10.1021/ja053472s http://doi.org/10.1021/ja053472s .

Y.S. Ye , J. Rick , B.J. Hwang . J. Mater. Chem. A , 2013 . 1 2719 DOI: 10.1039/C2TA00126H http://doi.org/10.1039/C2TA00126H .

D. Zhou , R. Zhou , C.X. Chen , W.A. Yee , J.H. Kong , G.Q. Ding , X.H. Lu . J. Phys. Chem. B , 2013 . 117 7783 DOI: 10.1021/jp4021678 http://doi.org/10.1021/jp4021678 .

S. Mallakpour , Z. Rafiee . J. Polym. Environ. , 2011 . 19 485 DOI: 10.1007/s10924-011-0291-7 http://doi.org/10.1007/s10924-011-0291-7 .

W.L. Hough , M. Smiglak , H. Rodríguez , R.P. Swatloski , S.K. Spear , D.T. Daly , J. Pernak , J.E. Grisel , R.D. Carliss , M.D. Soutullo , J.H. Davis , R.D. Rogers . New J. Chem. , 2007 . 31 1429 DOI: 10.1039/b706677p http://doi.org/10.1039/b706677p .

A. Lewandowski , A. Świderska-Mocek . J. Power Sources , 2009 . 194 601 DOI: 10.1016/j.jpowsour.2009.06.089 http://doi.org/10.1016/j.jpowsour.2009.06.089 .

R.F. de Souza , J.C. Padilha , R.S. Gonçalves , J. Dupont . Electrochem. Commun. , 2003 . 5 728 DOI: 10.1016/S1388-2481(03)00173-5 http://doi.org/10.1016/S1388-2481(03)00173-5 .

P. Wang , S.M. Zakeeruddin , I. Exnar , M. Grätzel . Chem. Commun. , 2002 . 24 2972 .

H.N. Lee , T.P. Lodge . J. Phys. Chem. Lett. , 2010 . 1 1962 DOI: 10.1021/jz100617t http://doi.org/10.1021/jz100617t .

R. Tsuda , K. Kodama , T. Ueki , H. Kokubo , S. Imabayashi , M. Watanabe . Chem. Commun. , 2008 . 40 4939 http://www.ncbi.nlm.nih.gov/pubmed/18931745 http://www.ncbi.nlm.nih.gov/pubmed/18931745 , .

Z.L. Xiao , R.G. Larson , Y.L. Chen , C.T. Zhou , Y.H. Niu , G.X. Li . Soft Matter , 2016 . 12 7613 DOI: 10.1039/C6SM01220E http://doi.org/10.1039/C6SM01220E .

F.Y. Liu , Y.X. Lv , J.J. Liu , Z.C. Yan , B.Q. Zhang , J. Zhang , J.S. He , C.Y. Liu . Macromolecules , 2016 . 49 6106 DOI: 10.1021/acs.macromol.6b01171 http://doi.org/10.1021/acs.macromol.6b01171 .

S.K. Chaurasia , R.K. Singh , S. Chandra . Solid State Ionics , 2014 . 262 790 DOI: 10.1016/j.ssi.2013.09.048 http://doi.org/10.1016/j.ssi.2013.09.048 .

S.K. Chaurasia , S. Kataria , A.K. Gupta , Y.L. Verma , V.K. Singh , A.K. Tripathi , A.L. Saroj , R.K. Singh . RSC Adv. , 2015 . 5 8263 DOI: 10.1039/C4RA12951B http://doi.org/10.1039/C4RA12951B .

S.K. Chaurasia , R.K. Singh , S. Chandra . CrystEngComm , 2013 . 15 6022 DOI: 10.1039/c3ce40576a http://doi.org/10.1039/c3ce40576a .

Y.X. Bai , G.L. Wu , Q. Zhang , C.F. Zhang , J. Gu , Y.P. Sun . J. Appl. Polym. Sci. , 2015 . DOI: 10.1002/app.42137 http://doi.org/10.1002/app.42137 .

Y.T. Shieh , G.L. Liu , K.C. Hwang , C.C. Chen . Polymer , 2005 . 46 10945 DOI: 10.1016/j.polymer.2005.09.022 http://doi.org/10.1016/j.polymer.2005.09.022 .

Z. Bartczak , E. Martuscelli . Macromol. Chem. Phys. , 1987 . 188 445 DOI: 10.1002/macp.1987.021880220 http://doi.org/10.1002/macp.1987.021880220 .

N. Rakkapao , V. Vao-soongnern , Y. Masubuchi , H. Watanabe . Polymer , 2011 . 52 2618 DOI: 10.1016/j.polymer.2011.03.044 http://doi.org/10.1016/j.polymer.2011.03.044 .

M. Avrami . J. Chem. Phys. , 1939 . 7 1103 DOI: 10.1063/1.1750380 http://doi.org/10.1063/1.1750380 .

Y.K. Godovsky , G.L. Slonimsky . J. Polym. Sci., Part B:Polym. Phys. , 1974 . 12 1053 DOI: 10.1002/pol.1974.180120603 http://doi.org/10.1002/pol.1974.180120603 .

Z.B. Qiu , C.Z. Yan , J.M. Lu , W.T. Yang . Macromolecules , 2007 . 40 5047 DOI: 10.1021/ma070255y http://doi.org/10.1021/ma070255y .

N.V. Pogodina , H.H. Winter . Macromolecules , 1998 . 31 8164 DOI: 10.1021/ma980134l http://doi.org/10.1021/ma980134l .

Y.H. Niu , L. Yang , H. Wang , Z.G. Wang . Macromolecules , 2009 . 42 7623 DOI: 10.1021/ma901543c http://doi.org/10.1021/ma901543c .

A. Kelarakis , S.M. Mai , C. Booth , A.J. Ryan . Polymer , 2005 . 46 2739 DOI: 10.1016/j.polymer.2005.01.068 http://doi.org/10.1016/j.polymer.2005.01.068 .

Y.P. Khanna . Macromolecules , 1993 . 26 3639 DOI: 10.1021/ma00066a024 http://doi.org/10.1021/ma00066a024 .

C.Y. Liu , J. Zhang , J.S. He , G.H. Hu . Polymer , 2003 . 44 7529 DOI: 10.1016/j.polymer.2003.09.013 http://doi.org/10.1016/j.polymer.2003.09.013 .

F. Chambon , Z.S. Petrovic , W.J. MacKnight , H.H. Winter . Macromolecules , 1986 . 19 2146 DOI: 10.1021/ma00162a007 http://doi.org/10.1021/ma00162a007 .

K. Boutahar , C. Carrot , J. Guillet . Macromolecules , 1998 . 31 1921 DOI: 10.1021/ma9710592 http://doi.org/10.1021/ma9710592 .

Q.F. Yi , X.J. Wen , J.Y. Dong , C.C. Han . Polymer , 2008 . 49 5053 DOI: 10.1016/j.polymer.2008.09.037 http://doi.org/10.1016/j.polymer.2008.09.037 .

S.C. Zhao , Z. Cai , Z. Xin . Polymer , 2008 . 49 2745 DOI: 10.1016/j.polymer.2008.04.012 http://doi.org/10.1016/j.polymer.2008.04.012 .

J. Mondal , E. Choi , A. Yethiraj . Macromolecules , 2013 . 47 438 http://pubs.acs.org/doi/abs/10.1021/ma4016714 http://pubs.acs.org/doi/abs/10.1021/ma4016714 , .

H.D. Keith , F.J. Padden . J. Appl. Phys. , 1964 . 35 1270 DOI: 10.1063/1.1713606 http://doi.org/10.1063/1.1713606 .

U.S. Kestur , L.S. Taylor . CrystEngComm , 2010 . 12 2390 DOI: 10.1039/c001905d http://doi.org/10.1039/c001905d .

C.H. Lee . Polymer , 1998 . 39 5197 DOI: 10.1016/S0032-3861(97)10112-4 http://doi.org/10.1016/S0032-3861(97)10112-4 .

F.C. Frank . Proc. R. Soc. London , 1950 . A201 586 .

H.D. Keith , F.J. Padden . J. Appl. Phys. , 1963 . 34 2409 DOI: 10.1063/1.1702757 http://doi.org/10.1063/1.1702757 .

H.D. Keith , F.J. Padden . J. Appl. Phys. , 1964 . 35 1286 DOI: 10.1063/1.1713607 http://doi.org/10.1063/1.1713607 .

M. Pulst , M.H. Samiullah , U. Baumeister , M. Prehm , J. Balko , T. Thurn-Albrecht , K. Busse , Y. Golitsyn , D. Reichert , J. Kressler . Macromolecules , 2016 . 49 6609 DOI: 10.1021/acs.macromol.6b01107 http://doi.org/10.1021/acs.macromol.6b01107 .

C.Y. Lai , A. Hiltner , E. Baer , L.T. Korley . ACS Appl. Mater. Interfaces , 2012 . 4 2218 DOI: 10.1021/am300240r http://doi.org/10.1021/am300240r .

W.C. Shi , J. Yang , Y. Zhang , J. Luo , Y.R. Liang , C.C. Han . Macromolecules , 2012 . 45 941 DOI: 10.1021/ma202046c http://doi.org/10.1021/ma202046c .

H.L. Chen , H.H. Liu , J. Lin . Macromolecules , 2000 . 33 4856 DOI: 10.1021/ma991504o http://doi.org/10.1021/ma991504o .

H.J. Chiu , H.L. Chen , T.L. Lin , J. Lin . Macromolecules , 1999 . 32 4969 DOI: 10.1021/ma990304+ http://doi.org/10.1021/ma990304+ .

R. Verma , H. Marand , B. Hsiao . Macromolecules , 1996 . 29 7767 DOI: 10.1021/ma951727o http://doi.org/10.1021/ma951727o .

M. Imai , K. Kaji , T. Kanaya . Macromolecules , 1994 . 27 7103 DOI: 10.1021/ma00102a016 http://doi.org/10.1021/ma00102a016 .

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