Enhanced Crystallization Rate of Biodegradable Poly(<italic style="font-style: italic">ε</italic>-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent

Kang-jing Zhang; Zhao-bin Qiu

doi:10.1007/s10118-017-1993-7

Your Location：

Home >

Browse articles >

Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent

Papers | Updated：2021-02-18

- Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent
- Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent
- 高分子科学（英文版） 2017年35卷第12期页码：1517-1523
- Affiliations：
  
  State Key Laboratory of Chemical Resource Engineering, Ministry of Education Key Laboratory of Carbon Fiber and Functional Polymers, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  Zhao-bin Qiu (邱兆斌), E-mail:qiuzb@mail.buct.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(51373020);the National Natural Science Foundation of China(51573016);the National Natural Science Foundation of China(51521062)
- DOI：10.1007/s10118-017-1993-7
  中图分类号：
- 收稿：2017-05-09，
  
  修回：2017-06-09，
  
  录用：2017-06-13，
  
  纸质出版：2017-12
- Accepted：
Scan QR Code
Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent[J]. 高分子科学（英文版）, 2017,35(12):1517-1523. DOI: 10.1007/s10118-017-1993-7.

Kang-jing Zhang, Zhao-bin Qiu. Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1517-1523. DOI: 10.1007/s10118-017-1993-7.
Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent[J]. 高分子科学（英文版）, 2017,35(12):1517-1523. DOI: 10.1007/s10118-017-1993-7. DOI：

Kang-jing Zhang, Zhao-bin Qiu. Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1517-1523. DOI: 10.1007/s10118-017-1993-7. DOI：

摘要

Abstract

The influence of cyanuric acid (CA) as an efficient nucleating agent on the crystallization behavior and morphology of biodegradable poly(

-caprolactone) (PCL) was extensively studied in this work with several techniques for the first time. The nonisothermal melt crystallization behavior and overall isothermal melt crystallization rate of PCL were significantly enhanced by only a small amount of CA. The addition of CA apparently improved the nonisothermal melt crystallization peak temperature

overall isothermal melt crystallization rate

and nucleation density of PCL spherulites

but did not modify the crystallization mechanism and crystal structure of PCL

indicating that CA was an efficient nucleating agent for the crystallization of PCL. The possible nucleation mechanism of CA on the crystallization of PCL was also discussed on the basis of their crystal structures.

关键词

Keywords

references

M. Woodruff , D. Hutmacher . Prog. Polym. Sci. , 2010 . 35 1217 DOI: 10.1016/j.progpolymsci.2010.04.002 http://doi.org/10.1016/j.progpolymsci.2010.04.002 .

G. Eastmond . Adv. Polym. Sci. , 1999 . 149 59 DOI: 10.1007/3-540-48838-3 http://doi.org/10.1007/3-540-48838-3 .

Z. Qiu , M. Komura , T. Ikehara , T. Nishi . Polymer , 2003 . 44 7749 DOI: 10.1016/j.polymer.2003.10.013 http://doi.org/10.1016/j.polymer.2003.10.013 .

Z. Qiu , W. Yang , T. Ikehara , T. Nishi . Polymer , 2005 . 46 11814 DOI: 10.1016/j.polymer.2005.10.058 http://doi.org/10.1016/j.polymer.2005.10.058 .

D. Wu , Y. Zhang , M. Zhang , W. Yu . Biomacromolecules , 2009 . 10 417 DOI: 10.1021/bm801183f http://doi.org/10.1021/bm801183f .

Y. Ni , S. Zheng . J. Polym. Sci., Part B:Polym. Phys. , 2007 . 45 2201 DOI: 10.1002/(ISSN)1099-0488 http://doi.org/10.1002/(ISSN)1099-0488 .

K. Chrissafis , G. Antoniadis , K. Paraskevopoulos , A. Vassiliou , D. Bikiaris . Compos. Sci. Technol. , 2007 . 67 2165 DOI: 10.1016/j.compscitech.2006.10.027 http://doi.org/10.1016/j.compscitech.2006.10.027 .

H. Zeng , C. Gao , D. Yan . Adv. Funct. Mater. , 2006 . 16 812 DOI: 10.1002/(ISSN)1616-3028 http://doi.org/10.1002/(ISSN)1616-3028 .

Z. Qiu , H. Wang , C. Xu . J. Nanosci. Nanotechnol. , 2011 . 11 7884 DOI: 10.1166/jnn.2011.4714 http://doi.org/10.1166/jnn.2011.4714 .

E. Chen , T. Wu . Polym. Degrad. Stab. , 2007 . 92 1009 DOI: 10.1016/j.polymdegradstab.2007.02.019 http://doi.org/10.1016/j.polymdegradstab.2007.02.019 .

H. Pan , Z. Qiu . J. Biobased Mater. Bioenergy , 2014 . 8 273 DOI: 10.1166/jbmb.2014.1426 http://doi.org/10.1166/jbmb.2014.1426 .

H. Lei , W. Kai , Z. Liang , Y. Inoue . J. Polym. Sci., Part B:Polym. Phys. , 2010 . 48 294 DOI: 10.1002/polb.v48:3 http://doi.org/10.1002/polb.v48:3 .

J. Zhang , Z. Qiu . Ind. Eng. Chem. Res. , 2011 . 50 13885 DOI: 10.1021/ie202132m http://doi.org/10.1021/ie202132m .

H. Pan , J. Yu , Z. Qiu . Polym. Eng. Sci. , 2011 . 51 2159 DOI: 10.1002/pen.v51.11 http://doi.org/10.1002/pen.v51.11 .

W. Guan , Z. Qiu . Ind. Eng. Chem. Res. , 2012 . 51 3203 DOI: 10.1021/ie202802d http://doi.org/10.1021/ie202802d .

Y. Wang , M. Rodriguez-Perez , R. Reis , J. Mano . Macromol. Mater. Eng. , 2005 . 290 792 DOI: 10.1002/(ISSN)1439-2054 http://doi.org/10.1002/(ISSN)1439-2054 .

P. Pan , G. Shan , Y. Bao , Z. Weng . J. Appl. Polym. Sci. , 2013 . 129 1374 DOI: 10.1002/app.38825 http://doi.org/10.1002/app.38825 .

J. Yang , Y. Chen , S. Qin , J. Liu , C. Bi , R. Liang , T. Dong , X. Feng . Ind. Eng. Chem. Res. , 2015 . 54 8048 DOI: 10.1021/acs.iecr.5b02150 http://doi.org/10.1021/acs.iecr.5b02150 .

M. Weng , Z Qiu . Thermochimi. Acta , 2014 . 577 41 DOI: 10.1016/j.tca.2013.12.011 http://doi.org/10.1016/j.tca.2013.12.011 .

M. Avrami . J. Chem. Phys. , 1940 . 8 212 DOI: 10.1063/1.1750631 http://doi.org/10.1063/1.1750631 .

M. Avrami . J. Chem. Phys. , 1941 . 9 177 DOI: 10.1063/1.1750872 http://doi.org/10.1063/1.1750872 .

B. Wunderlich . Macromolecular physics, Vol. 2:Crystal nucleation, growth, annealing , : New York Academic Press , 1976 .

G. Verschoor , E. Keulen . Acta Cryst. , 1971 . B27 - 134 . http://onlinelibrary.wiley.com/doi/10.1107/S0567740871001791/citedby http://onlinelibrary.wiley.com/doi/10.1107/S0567740871001791/citedby , .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane

Effects of Different Nucleating Agents, Annealing and Pre-stretching Process on the Crystallinity and Mechanical Properties of Poly(butylene carbonate)

Study on the Differences in Crystallization Behavior of Poly(lactic acid) (PLA) Induced by Amide-based and Hydrazide-based Nucleating Agents

Pyrimidoisoindigo-based Polymers for Ambipolar Charge Transport

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent

Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent

DOI：10.1007/s10118-017-1993-7

摘要

Abstract

关键词

Keywords

references